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http://dx.doi.org/10.5012/bkcs.2014.35.6.1605

Entry to Highly Hindered Chiral β-Amino Triazoles Bearing a gem-Diaryl Group by Azide-alkyne Click Chemistry  

Sadu, Venkata Subbaiah (Green Chemistry Division, Korea Research Institute of Chemical Technology)
Roy, Harendra Nath (Green Chemistry Division, Korea Research Institute of Chemical Technology)
Arigala, Pitchaiah (Green Chemistry Division, Korea Research Institute of Chemical Technology)
Hwang, In-Taek (Green Chemistry Division, Korea Research Institute of Chemical Technology)
Lee, Kee-In (Green Chemistry Division, Korea Research Institute of Chemical Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.6, 2014 , pp. 1605-1612 More about this Journal
Abstract
Copper(I)-catalyzed Huisgen cycloaddition of terminal alkynes with unmasked azidoamines derived from amino acids is described. The reported strategy provides a new entry to highly hindered ${\beta}$-amino 1,2,3-triazole derivatives bearing a gem-diaryl group, which are potentially valuable entities as molecular catalysts for asymmetric transformations.
Keywords
Amino triazole; gem-Diaryl group; Azide-alkyne cycloaddition; Amino acid;
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