• Title/Summary/Keyword: Asymmetric Surface

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Study on the Pervaporation Characteristic of Water-alcohol Mixtures through Aromatic Polyetherimide Membranes : I. Pervaporation through Structure Change of Symmetric Dense and Asymmetric Structure Membranes (방향계 폴리에테르이미드막의 물-알콜 혼합액의 투과증발 특성에 관한 연구 : I.구조 변화에 따른 투과증발)

  • Kim, S.G.;Jegal, J.G.;Lee, K.-H.
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.945-953
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    • 1997
  • Aromatic polyetherimide membranes were prepared by dry/wet phase inversion method and investigated regarding the pervaporation characteristic of water-alcohol mixtures by using the permselective property of imide group and the structure modification of skin layer of the membrane. The membrane selectivity increased with the reaction time of surface-modification, to some extent, and the density of top layer tends to increases with increasing the reaction time. In the case of dense membrane, the separation factor was 160 and 2000 for 90wt% ethanol mixture and 90wt% isopropanol solution, respectively, which implies that aromatic polyetherimide has a high permselectivity. The temperature dependence of permeation flux seems to follow an Arrhenius type at the temperature range of ($40^{\circ}C-70^{\circ}C$).

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A Comparison of Lower Limb Muscle Activity Affecting Sit-to-Stand Movement of Stroke Patients (뇌졸중 환자의 앉은 자세에서 일어서기 동작 수행에 영향을 주는 다리 근 활성 비교)

  • Park, In-Seok;Ju, Sung-Kwang
    • PNF and Movement
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    • v.16 no.1
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    • pp.59-66
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    • 2018
  • Purpose: This study aimed (1) to identify asymmetry observed in electromyography (EMG) activity patterns of lower limb muscles between affected and unaffected sides of stroke patients during sit to stand (STS) movement and (2) to identify the muscles of the paretic lower limb that affected STS performance in stroke patients. Methods: This study consisted of 27 patients (15 males and 12 females) with poststroke hemiparesis. The activation of the rectus femoris (RF), tibialis anterior (TA), and gastrocnemius (GCM) of the affected side and unaffected side during STS movement were recorded using surface EMG. In addition, EMG lower limb muscle activation patterns were measured in the all section, pre-thigh off (pre-TO), and post-thigh off (post-TO) section. All measurements were obtained during five repetitions of the STS (FTSTS) movement. An independent t-test was performed to compare the affected side and unaffected side of the lower limb during the STS movement. A stepwise linear regression analysis was conducted to identify the muscles that affected STS performance. Results: Activation of both the RF and TA significantly affected the lower limb during the STS movement (p<0.05). Two muscles showed a difference on the post-TO section. The results of the stepwise multiple regression analysis showed that the RF and TA muscles of the affected lower limb were affected in FTSTS. Conclusion: These results provide a basis for reinforcement training, focusing on the RF and TA muscles of the affected side of stroke patients to improve asymmetric movement and performance in STS movement.

Development and Characterization of Asymmetric Swelling-Induced Wrinkles on Natural Rubber Surface

  • Lee, Gi-Bbeum;Sathi, Shibulal Gopi;Kim, Min Jung;Park, Changsin;Huh, Yang Il;Nah, Changwoon
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.342-349
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    • 2016
  • Characteristics of the swelling-induced wrinkles on the surfaces of natural rubber (NR) film were investigated. The wrinkle structure was generated by swelling of NR film pre-stretched and firmly bonded onto an aluminum substrate in hexane. A novel experimental method was adopted to replicate the swelling-induced wrinkles on the NR film using an epoxy-hardener system. To get insight into the wrinkle parameters; the wrinkle length (L), wrinkle distance (D), wrinkle height (H) and the angle between two consecutive wrinkles (${\theta}$), the cross-sections of the replicas obtained from saturated swollen NR film were examined using an optical microscopy (OM). From the OM images, the wrinkling parameters were measured as a function of the thickness of NR film from 0.42 to 1.76 mm. Also, it was evaluated that the effects of swelling time on the wrinkling parameters. The length (L), distance (D) and height (H) of wrinkles increased as the thickness of the NR film and the swelling time increased. However, the angle between the wrinkles (${\theta}$) showed a sharp decrease up to a swelling time of 200 minutes and slightly decreased afterwards.

Electron Emission and Degradation of the Pb($\textrm{Zr}_{0.5}\textrm{Ti}_{0.5}$)$\textrm{O}_3$Electron Guns with Various Upper Electrode Sizes (Pb($\textrm{Zr}_{0.5}\textrm{Ti}_{0.5}$)$\textrm{O}_3$전자총의 상부 전극 크기에 따른 전자 방출 및 열화)

  • Kim, Yong-Tae;Yun, Gi-Hyeon;Kim, Tae-Hui;Park, Gyeong-Bong
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.1032-1036
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    • 1999
  • The electron emission and degradation of the ferroelectric Pb($\textrm{Zr}_{0.5}\textrm{Ti}_{0.5}$)$\textrm{O}_3$ ceramics by the pulse electric field have been investigated as a function of the upper electrode diameter. Polarization increased with the decrease of the upper electrode diameter due to the increase of the volume fraction participated in the polarization reversal near the electrode edge. Simulation using ANSYS 5.3 for the electric field distribution showed that the electric field increased near the upper electrode edge of the asymmetric electrode structure. The ferroelectric volume near the upper electrode edge which contributed to the increase of the polarization and the emission charge per electrode diameter were independent on the upper electrode diameter. Polarization and dielectric constant were decreased due to the erosion of the upper electrode with repeating the emission cycles, but they were recovered by the electrode regeneration. The degradation of the ferroelectric surface resulted in the increase of the coercive field and dielectric loss.

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Physical Properties and Facies of the Sand Ridge Sediment, South Sea of Korea (남해 Sand ridge 퇴적물의 퇴적상과 물리적 특성)

  • CHON Hee-Jeong;SEO Yong-Kyo;KIM Dae-Choul;KIM Jeng-Chang;KEENE Jock
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.5
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    • pp.609-621
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    • 1998
  • Sand ridges in the South Sea of Korea have been investigated to reveal the surface morphology and vortical variation in sediment physical property. Both field and laboratory methods such as high resolution subbottom profiling, side scan sonar, and physical property and sediment textural study on cored sediments were employed. Asymmetric sand waves are found on the ridge, No prominent difference in the sediment was recorded throughout the ridge area. Sediment sorting is generally poor due to interbedded mud. Average compressional wave velocity is 1753 m/sec for the sand dominated core section, Most of cores show two prominent facies: facies A and B. Facies A is defined as modern mud sediment and B is dominated by relict sand. Facies B is characterized by gravel, sand, and shell fragment, It is suggested that the facies B was developed in transgressive environment by tide and sporadic high energy events.

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A Study on the Permeance Through Polymer Membranes and Selectivity of $CH_4/N_2$ (폴리이미드와 폴리이써설폰 분리막을 이용한 $CH_4/N_2$의 투과선택도 특성)

  • Park, Bo-Ryoung;Kim, Dae-Hoon;Lee, Gang-Woo;Hwang, Taek-Sung;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.498-504
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    • 2011
  • In this research, hollow fiber membranes were used in order to investigate to permeation and selectivity of the $CH_4$ and $N_2$. Polyimide and polyethersulfone hollow fiber membrane were prepared by the dry-wet phase inversion method and the module was manufactured by fabricating fibers after surface coating with silicone elastomer. The scanning electron microscopy (SEM) studies showed that the produced fibers typically had an asymmetric structure. The permeance of $CH_4$ and $N_2$ were increased with pressure and temperature. However, the selectivity was decreased with increasing temperature. The permeances of $CH_4$ and $N_2$ were decreased with increasing the air gap and the effect of post-treatment on membrane showed the increase in permeance up to 3.2~7.0 times.

A Study on Water Uptake Behavior and Properties of Pervaporation PVA Membrane (투과증발 PVA 분리막의 물 흡수 거동 및 물성 연구)

  • 김광제;박인준;김동권;이수복
    • Membrane Journal
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    • v.5 no.2
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    • pp.74-80
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    • 1995
  • Asymmetric poly(vinyl alcohol) (PVA) membranes were prepared by varying the precipitation conditions of the phase inversion technique, and the influences of precipitation conditions on the water uptake of the membrane were investigate. The degree of water uptake of the membrane increased and reached a certain maximum value, as the precipitation time increased. However, it decreded after that. As the precipition temperauure became lower, the degree of water uptake increased more or less. The addition of a nonionic surfactant to the precipitaon solution was effective reducing the precipitation time by lowering the surface tension of the precipitation solution, but ig didn't change the maximum value of its own degree of water uptake. In addition, the relationship between the degree of water uptake and the separation characteristics and mechanical properies of the membrane were investigated. The selectivity factor of the membrane for pervaperation separation decreased, but the permeate flux increased, respectively, with increasing the degree of water uptake. The tensile strength and elongation of the membrane, respectively, increased to a maximum value with increasing the degree of water uptake, and then decreased abtuptly.

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Ductile Fracture Predictions of High Strength Steel (EH36) using Linear and Non-Linear Damage Evolution Models (선형 및 비선형 손상 발전 모델을 이용한 고장력강(EH36)의 연성 파단 예측)

  • Park, Sung-Ju;Park, Byoungjae;Choung, Joonmo
    • Journal of Ocean Engineering and Technology
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    • v.31 no.4
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    • pp.288-298
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    • 2017
  • A study of the damage evolution laws for ductile materials was carried out to predict the ductile fracture behavior of a marine structural steel (EH36). We conducted proportional and non-proportional stress tests in the experiments. The existing 3-D fracture strain surface was newly calibrated using two fracture parameters: the average stress triaxiality and average normalized load angle taken from the proportional tests. Linear and non-linear damage evolution models were taken into account in this study. A damage exponent of 3.0 for the non-linear damage model was determined based on a simple optimization technique, for which proportional and non-proportional stress tests were simultaneously used. We verified the validity of the three fracture models: the newly calibrated fracture strain model, linear damage evolution model, and non-linear damage evolution model for the tensile tests of the asymmetric notch specimens. Because the stress evolution pattern for the verification tests remained at mode I in terms of the linear elastic fracture mechanics, the three models did not show significant differences in their fracture initiation predictions.

Properties of GaN Film Grown on AlN/PSS Template by Hydride Vapor Phase Epitaxy (AlN/PSS Template 위에 HVPE로 성장한 GaN 막의 특성)

  • Son, Hoki;Lee, YoungJin;Lee, Mijai;Kim, Jin-Ho;Jeon, Dae-Woo;Hwang, Jonghee;Lee, Hae-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.348-352
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    • 2016
  • In this paper, GaN film was grown on AlN/PSS by hydride vapor phase epitaxy compared with GaN on planar sapphire. Thin AlN layer for buffer layer was deposited on patterned sapphire substrate (PSS) by metal organic chemical vapor deposition. Surface roughness of GaN/AlN on PSS was remarkably decreased from 28.31 to 5.53 nm. Transmittance of GaN/AlN grown on PSS was lower than that of planar sapphire at entire range. XRD spectra of GaN/AlN grown on PSS corresponded the wurzite structure and c-axis oriented. The full width at half maximum (FWHM) values of ${\omega}$-scan X-ray rocking curve (XRC) for GaN/AlN grown on PSS were 196 and 208 arcsec for symmetric (0 0 2) and asymmetric (1 0 2), respectively. FWHM of GaN on AlN/PSS was improved more than 50% because of lateral overgrowth and AlN buffer effect.

Characterization of Alpha-Ga2O3 Template Grown by Halide Vapor Phase Epitaxy (HVPE 방법으로 성장한 Alpha-Ga2O3의 특성 분석)

  • Son, Hoki;Ra, Yong-Ho;Lee, Young-Jin;Lee, Mi-Jai;Kim, Jin-Ho;Hwang, Jonghee;Kim, Sun Woog;Lim, Tae-Young;Jeon, Dae-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.6
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    • pp.357-361
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    • 2018
  • We demonstrated a crack-free ${\alpha}-Ga_2O_3$ on sapphire substrate by horizontal halide vapor phase epitaxy (HVPE). Oxygen-and gallium chloride-synthesized Ga metal and HCl were used as the precursors, and $N_2$ was used as the carrier gas. The HCl flow and growth temperature were controlled in the ranges of 10~30 sccm and $450{\sim}490^{\circ}C$, respectively. The surface of ${\alpha}-Ga_2O_3$ template grown at $470^{\circ}C$ was flat and the root-mean-square (RMS) roughness was ~2 nm. The full width at half maximum (FWHM) values for the symmetric-plane diffractions, were as small as 50 arcsec and those for the asymmetric-plane diffractions were as high as 1,800 arcsec. The crystal quality of ${\alpha}-Ga_2O_3$ on sapphire can be controlled by varying the HCl flow rate and growth temperature.