• Journal of the Korean Geotechnical Society
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• v.15 no.2
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• pp.153-164
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• 1999

The solubilization of BTEX was evaluated in aqueous surfactant solutions with and without several additives. Anionic surfactant(Sodium Dodecyl Sulfate, SDS) and nonionic surfactants (NEODOL(equation omitted)25-3 and $SOFTANOL\circledR-90$ were used as test surfactants. The effects of surfactant HLB(Hydrophile-Lipophile Balance) Number and hydrocarbon molar volume and polarity of BTEX on the MSR(Molar Solubilization Ratio), micelle-water partition coefficient of BTEX, and CMC(C,itical Micelle Concentration) were investigated. Optimizing treatment conditions applicable to enhanced solubilization was also studied by manupulating salinity or electrolyte control with additives of ethyl alcohol, hydrotrope, and electrolyte solution. The most effective surfactant for solubilization was found $SOFTANOL\circledR-90$, since HLB number of 13.6 is similar to those values of BTEX ranging between 11.4 and 12.2, which was also proved experimentally. Ethyl alchohol of 3% was the most effective additives in reducing CMC and improving solubilization among the conditions using SDS, NEODOL(equation omitted)25-3, and $SOFTANOL\circledR-90$ with three additives. The partitioning of BTEX between surfactant micelles and aqueous solutions was characterized by a mole fraction micelle-phase/aqueous phase partion coefficient, $K_m$. Values of log $K_m$. for BTEX compounds in surfactant solutions of this study range from 2.95 to 3.76(100mM SDS) and 2.95 to 3.49(117mM $SOFTANOL\circledR-90$. Log $K_m$ appears to be a linear function of log $K_{ow}$ for SDS and $SOFTANOL\circledR-90$. A knowledge of partitioning of BTEX in aqueous surfactant system can be a prerequisite for the understanding of the behavior of hydrophobic organic compounds in soil-water systems in which surfactants play a role in remediation of contaminated soil and facilitated transport.

• Journal of Bio-Environment Control
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• v.20 no.4
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• pp.352-356
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• 2011

It is true that the industrial development has usually been accompanied with urbanization or centralization of population that has inevitably led to high-rise buildings and densely built-up living area in the cities. While it is badly needed to acquire as much green land within the city limits as possible to compensate for reduced space for recreational purpose in parallel with increasingly urbanized area, the living conditions of plants have become seriously devastated due to shortage of sun light walled-off by high-rise buildings and contaminated environment and air. The shade that is generated by high-rise and compact buildings hinders growth of plants, which makes it urgent to develop native ground cover plant that is strongly viable in the shade. For this purpose, Ligularia stenocephala, best known as greens for Ssam (rice and condiments wrapped in leaves) was cultivated under the 30%, 50%, and 80% shadings and observed to see if there would be any changes in soil conditions, growth of plants and chlorophyll contents depending on the shading rate. The leaf number was 10.8 pieces under the 50% shading and 8.4 under the 30%-shading, 7.7 pieces more than that cultivated under lighting. The leaf width turned out to be excellent from cultivation under the 50%- shading, an evidence indicating its possibility of being cultivated as native ground cover plant in the shade. The live weight of the plants cultivated under the shading increased to 31.63 g, 43.39 g and 19.40 g, respectively, compared to 90.43 g of those in the untreated control plot. The increase in growth of roots was particularly significant with 48.48 g in comparison to 12.33 g under 30% shading cultivation. The chlorophyll synthesis amounted to 46.2 under the 50% shading, showing an increase compared to 41.9 under lighting. The chlorophyll synthesis rather shrank under other shading conditions. The cultivation of Ligularia stenocephala under the 50% shading showed the best condition in growth as native ground cover plant.

• Journal of Food Hygiene and Safety
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• v.34 no.6
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• pp.526-533
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• 2019

The purpose of this study was to investigate hazardous microorganisms in mixed baby leafy vegetables and various baby leafy vegetables used as raw materials for fresh-cut produce in spring and summer. To estimate microbial loads, a total of 298 samples including 181 samples of mixed baby leafy vegetables purchased in a Korean market and 117 samples of various baby leafy vegetables from distribution companies were collected. Fecal indicators (coliform and Escherichia coli) as well as food-borne pathogens (E. coli O157:H7, Salmonella spp., Staphylococcus aureus) were enumerated. As a result, the mixed baby leafy vegetable samples showed significantly higher (P<0.05) coliform bacteria numbers in summer (5.59±1.18 log CFU/g) compared to spring (3.60±2.53 log CFU/g). E. coli was detected in 1.3% (1/79) and 42.2% (43/102) of samples collected in spring and summer, respectively. Only one sample collected from a market in spring was contaminated with S. aureus. In the experiment with baby leafy vegetables, the number of coliforms detected in baby leafy vegetables cultivated in soil in spring was 1.15±1.95 log CFU/g, and that in summer was 4.09±2.52 log CFU/g. However, the number of coliforms recovered from baby leafy vegetables cultivated in media was above 5.0 log CFU/g regardless of season. Occurrences of E. coli were 44.4% (12/27) and 19.0% (4/21) for baby leafy vegetables cultivated in soil and media, respectively. However, E. coli O157:H7 and Salmonella spp. were not detected. These results are in relation to microbial loads on mixed baby leafy vegetables associated with raw materials. Therefore, it is necessary to develop and implement hygienic practices at baby leafy vegetable farms to enhance the safety of fresh produce.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.68-76
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• 2002

In this study, we have investigated the geochemical behavior and fate of heavy metals in acid rock drainage (ARD). The ARD was collected from the area of the former Dongrae pyrophyllite mine. The Dongrae Creek waters were strongly acidic (pH : 2.3~4.2) and contained high concentrations of $SO_4$, Al, Fe, Mn, Pb, Cu, Zn, and Cd, due to the influence of ARD generated from weathering of pyrite-rich pyrophyllite ores. However, the water quality gradually improved as the water flows downstream. In view of the change of mole fractions of dissolved Fe, Al and Mn, the generated ARD was initially both Fe- and AA-ich but progressively evolved to more Al-rich toward the confluence with the uncontaminated Suyoung River. As the AR3 (pH 2.3) mixed with the uncontaminated waters (pH 6.5), the pH increased up to 4.2, which caused precipitation of $SO_4$-rich Fe hydroxysulfate as a red-colored, massive ferricrete precipitate throughout the Dongrae Creek. Accompanying the precipitation of ferricrete, the Dongrae Creek water progressively changed to more Al-rich toward downstream sites. At the mouth of the Dongrae Creek, it (pH 3.4) mixed with the Suyoung River (pH 6.9), where pH increased to 5.7, causing precipitation of Al hydroxysulfate (white precipitates). Neutralization of the ARD-contaminated waters in the laboratory caused the successive formation of Fe precipitates at pH<3.5 and Al precipitates at higher pH (4~6). Manganese compounds were precipitated at pH>6. The removal of trace metals was dependent on the precipitation of these compounds, which acted as sorbents. The pHs for 50% sorption ($pH_{50}$) in Fe-rich and Al-rich waters were respectively 3.2 and 4.5 for Pb, 4.5 and 5.8 for Cu, 5.2 and 7.4 for Cd, and 5.8 and 7.0 for Zn. This indicates that the trace metals were sorbed preferentially with increasing pH in the general order of Pb, Cu, Cd, and Zn and that the sorption of trace metals in Al-rich water occurred at higher pH than those in Fe-rich water. The results of this study demonstrated that the partitioning of trace metals in ARD is not only a function of pH, but also depends on the chemical composition of the water.

• Korean journal of applied entomology
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• v.44 no.2
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• pp.97-108
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• 2005

Samples of water, soil, and sediment were taken from 10 streams near Andong, Korea in May 2004. To assess the degree of environmental pollution of each stream, chemical pollutants such as total notrogen (T-N), total phosphorus (T-P), chemical oxygen demand (COD), heavy metals, organophosphorus pesticides, organochlorine pesticides, and dioxin-like PCB congeners were analyzed by standard process tests or U.S. EPA methods. In addition, biomarkers originated from insect immune systems of beet armyworm, Spodoptera exigua, were used to analysis of the environmental samples. Except Waya-chun stream showing T-N content of 9.12 mg/L, most streams were contaminated with relatively low levels of overall pollutants in terms of T-N, T-P, and COD, compared to their acceptable environmental levels designated by the Ministry of Environment. Contents of Pb and Cd in samples of each stream were much lower than environmentally permissible levels. However, several times higherconcentrations of Pb and Cd were found in locations at Mi-chun, Kilan-chun, and Hyunha-chun streams, in comparison with other streams. Diazinon, parathion, and phenthoate compounds among organophosphorus pesticides were detected as concentrations of 0.19, 0.40, and $1.13\;{\mu}g/g$, respectively, from soil sample collected in the vicinity of Mi-chun stream. On the other hand, 16 organochlorine pesticides and 12 dioxin-like PCB congeners, known as endocrine disrupting chemicals, selected in this study were not found above the limit of detection. Biomarker analyses using insect immune responses indicated that Waya-chun stream was suspected as exposure to environmental pollutants. Limitation and compensation of both environmental analysis techniques are discussed.

• Journal of the Korean Institute of Traditional Landscape Architecture
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• v.28 no.4
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• pp.85-97
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• 2010

This study analyzed the distribution, structure and environmental condition of the vegetation of the Chionanthus retusus Lindly et Paxton community at the Wansanchielbong in the Jeonju city to offer basic data for sustainable conservation and ecological management system. And the results are as follows; 1. The average pH of soil at the community was pH 5.69 and it was slightly higher than the average of forest soil pH of Korea. But if the degree of pH will be down, it will be needed some more fertilization of Calcium. 2. The total average for contents of organism was 4.98%. And the nitrate - nitrogen content(mg/kg) of A, B, C, D quadrat was 20.29%, 28.87%, 7.65%, and 23.3% respectively. And there were good condition except quadrat C which was contaminated by amount of earth and sand. 3. The flora of the Chionanthus retusus Lindly et Paxton community was listed as 60 taxa; 37 families, 50 genera, 47 species, 10 varieties and 3 forms. The average appearance species of each Quadrat were A sector 30, B sector 26, C sector 19 and D 19 taxa respectively. 4. Surveyed woody plants in the community were as follows : Chionanthus retusus, Zelkova serrata, Quercus variabilis, Cornus walteri, Robinia pseudo-acacia and those were mixed status. And Chionanthus retusus, Zelkova serrata, Robinia pseudo-acacia, Albizzia julibrisin, Cudrania tricuspidata, Symplocos chinensis for. pilosa were mixed in mid layer trees. Herbaceous plants were founded such as Chionanthus retusus, Zelkova serrata, Robinia pseudo-acacia, Grewia parviflora, Rosa multiflora, Trachelospermum asiaticum was dominant with 35~64% in the ground cover, and Commelina communis, Calamagrostis arundinacea, Dryopteris bissetiana, Lilium lancifolium were founded also. 5. The importance values of Chionanthus retusus was 40.2% in the quadrat A1, 50.2% at quadrat A, 50.0% B1, 45.2% B2, 22.4% C1, 73.6% C2, 33.2% D1 and the total average of I.V. was 44.9%. 6. The average height of surveyed Chionanthus retusus was 5.7m and the average DBH was 12.4cm. The number of trees higher than 2m were 107 and the number of trees lower than 2m were 63. The total numbers of Chionanthus retusus were 170. 7. The age of surveyed Chionanthus retusus were analyzed 42 thru 87 years old and that of Zelkova serrata were 42, Quercus variabilis were 60, Quercus aliena were 48, Robinia pseudo-acacia were 40. 8. The number of trees with DBH 40 through 50cm were 6, and that of 30~39cm were 3, and that of 20~29cm were 16, so the total number that was over 20cm was 25. And there were 70 trees under 10cm of DBH and 63 seedlings. It will be very important data to conserve the habitat that the structure and environmental condition of the Chionanthus retusus Lindly et Paxton community at the Wansanchielbong was stable, and sustainable monitoring will be needed. Now that community is nurse forest of Jeonju City but more positive preservation plan will be needed and assigning monument of city or province also be necessary.

• Korean Journal of Veterinary Research
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• v.49 no.3
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• pp.257-263
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• 2009

Bovine mastitis is an important disease causing serious economic loss in dairy production and food poison in public health. Escherichia coli and Staphylococcus aureus are the major causative agents of bovine mastitis. These bacteria were found in milk and environmental condition such as feces, water, soil and so on. Bovine mastitis causative micro-organisms can survive in 1-2 weeks in feces and bed complexes. Low level of percentage of water content (PWC) of feces and bed complexes can reduce the spreading of bovine mastitis incidence from environmental contamination. In this study, we developed the fecal dehydrating system and determined the elimination rates of bovine mastitis causative agent from feces and bed complexes. To develop the fecal dehydrating system, the screw pressurized dehydrating system was used and the maximum rate of dehydrating was reached to 52% PWC using 90% PWC (wet base) of fecal and bed complexes. The elimination rates of the dehydrating system for E. coli and S. aureus were reached at 41.19 $\pm$ 7.84% to 62.55 $\pm$ 8.71% in various percentages of PWC of feces and bed complexes (80, 85 and 90%). These results suggested that the application of fecal dehydrating system would reduce the exposure of dairy cattle to bovine mastitis causing agents contaminated feces and bed complexes, and can be used for environmental bovine mastitis control avoiding misuse or abuse of chemical disinfectants and antibiotics in dairy farm.

• Journal of the Korean GEO-environmental Society
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• v.13 no.1
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• pp.5-13
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• 2012

For the last decade the amount of waste has rapidly been increased in South Korea and many waste landfills have been built according to government guidelines specifying required systems such as landfill liner, leachate collecting facilities, final cover system, etc. This effort has led the recently constructed landfills to be under well managed sanitary condition. In a meanwhile closed waste-landfill sites in the past before the adoption of the government guidelines exits under unsanitary condition. In these cases untreated leachate flew out to the surroundings due to the absence of liner and leachate collecting facilities and caused groundwater and soils to be contaminated. Waste generated odor and gas also brought civil complaints. Because environmental influences bring serious problems nearby sites, it is required to have unsanitary waste-landfills to be appropriately treated and managed. A study to evaluate environmental influence and contamination level of surroundings nearby and on the unsanitary landfills is necessary before the establishment of "Management guide of closed landfill site." This paper presents an environmental evaluation for the closed site, Doil-dong landfill, according to "Closed landfill management regulation" by Ministry of Environment. "D" landfill, located in Pyeongtaek city, has possobility to contaminate surrounding surfacewater and groundwater by leakage of leachate. The in-situ stabilization carried out to build the DMW(deep soil mixing cutoff wall) wall and drainage systems.

• Journal of Applied Biological Chemistry
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• v.61 no.2
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• pp.191-194
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• 2018

Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) are emerging pollutants in agricultural product, and the residual patterns and the uptake potentials were only studied on several crops, not on rice. The residue level and bioconcentration factor (BCF) of PFOA and PFOS were investigated on the low ($1mg\;kg^{-1}$) and the high contaminated soil ($5mg\;kg^{-1}$) groups. The residue levels in brown rice in the low group and in the high group were 0.002-0.004 and $0.008-0.030mg\;kg^{-1}$ of the each perfluorinated compounds (PFCs), and in the rice husk were $0.035-0.074mg\;kg^{-1}$ and $0.125-0.376mg\;kg^{-1}$ of the each PFCs, respectively. Furthermore, the residues in rice straw were the highest level in the all rice parts both in the groups. The PFOA and PFOS were reached to $3.723mg\;kg^{-1}$ and $7.641mg\;kg^{-1}$, respectively, and the BCF (1.474 and 4.700) as well.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.12
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• pp.1285-1291
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• 2005

In this study, we isolated bacteria from petroleum contaminated soil which were near to underground storage tanks(UST). Through the screen test, we selected high efficiency bacterium, KDi19, for biodegradation of diesel. KDi19 was identified as Pseudomonas sp. by 16S rDNA, fatty acid, and morphological physiological characteristics. KDi19 degraded 956.3 mg/L(95.6%) of 1,000 mg/L diesel for 48 hours(incubation condition : temperature; $30^{\circ}C$, cell concentration; 1.0 g/L, pH 7). At low temperature, $20^{\circ}C$, $15^{\circ}C$, $10^{\circ}C$, KDi19 respectively removed 63.9%, 18.5% and 17.0% of 1,000 mg/L diesel for 48 hours(cell concentration 1.0 g/L, pH 7). At low concentration of diesel, 50 mg/L and 100 mg/L, KDi19 degraded 97.9% and 96.2% of diesel for 24 hours(temperature; $30^{\circ}C$, cell concentration: 1.0 g/L, pH 7), respectively.