• Title/Summary/Keyword: Arrhenius

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A study on ignition delays of sprays using a shock tube (충격파관을 이용한 분무연료의 착화지연에 관한 연구)

  • 정진도;류정인;수곡행부
    • Journal of the korean Society of Automotive Engineers
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    • v.11 no.6
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    • pp.48-56
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    • 1989
  • A shock tube technique was developed in which a freely falling droplets column produced by an ultrasonic atomizer was ignited behind reflected shock. In the present study, the effects of turbulent mixing on the ignition delay of a cetane was decided, also, ignition process was investigated. For the purpose of disturbance of droplets column and mixing, authors installed turbulent lattice in shock tube. Usually, the ignition delay is so called Arrhenius plot which found break point in the Arrhenius plot on the high temperature side. The rate of misfiring increased rapidly below 1080K, but ignition took place from 838k and luminous flame was seen to spread over the whole section by turbulent lattice. Length, from end plate to turbulent lattice, was varied with 60,40,20mm. Also, ignition process was detected by Photo transistor. As a result, it was found that physical factors changed ignition delay greatly and turbulent mixing had a considerable effects in the ignition process.

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Coupled Analysis of Structure and Surface Ablation in Solid Rocket Nozzle (삭마반응을 고려한 고체 추진기관 노즐 조립체의 열반응 및 구조해석)

  • Kim, Yun-Chul;Doh, Young-Dae;Hahm, Hee-Cheol;Moon, Soon-Il
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.565-569
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    • 2011
  • A two-dimensional thermal response and ablation analysis code for predicting charring material ablation and shape change on solid rocket nozzle is presented. For closing the problem of thermo-structural analysis, Arrhenius' equation and Zvyagin's ablation model are used. The moving boundary problem are solved by remeshing-rezoning method. For simulation of complicated thermal protection systems, this method is integrated with a three-dimensional finite-element thermal and structure analysis code.

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Oxidation Study on the Fabrication of Fe-36Ni Oxide Powder from Its Scrap

  • Yun, Jung Yeul;Park, Man Ho;Yang, Sangsun;Lee, Dong-Won;Wang, Jei-Pil
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.48-52
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    • 2013
  • A study of oxidation kinetic of Fe-36Ni alloy has been investigated using thermogravimetric apparatus (TGA) in an attempt to define the basic mechanism over a range of temperature of 400 to $1000^{\circ}C$ and finally to fabricate its powder. The oxidation rate was increased with increasing temperature and oxidation behavior of the alloy followed a parabolic rate law at elevated temperature. Temperature dependence of the reaction rate was determined with Arrhenius-type equation and activation energy was calculated to be 106.49 kJ/mol. Based on the kinetic data and micro-structure examination, oxidation mechanism was revealed that iron ions and electrons might migrate outward along grain boundaries and oxygen anion diffused inward through a spinel structure, $(Ni,Fe)_3O_4$.

An Accelerated Life Test of LED Lights for Aviation Taxiway (항공유도로등화용 LED 광원의 가속수명시험)

  • Min, Kyong-Chan;Yun, Yang-Gi;Kim, Myung-Soo
    • Journal of Applied Reliability
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    • v.11 no.2
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    • pp.127-140
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    • 2011
  • This paper presents an accelerated life test of aviation taxiway lights installed in the airport to help safe navigation of airplanes at night or in bad weather. Recently halogen lamps of taxiway lights are replaced by LED ones and their reliability needs yet to be verified. Thus, effective test conditions are designed reflecting the failure modes and mechanisms from the previous studies on LED, which include the accelerated degradation process. The test is performed under the temperature $70^{\circ}C$ and $90^{\circ}C$ for two types of LED lights, taxiway center line lights(TCLL) and taxiway edge lights (TEDL). The failure time data were analyzed using lognormal distribution and Arrhenius model to find the life-stress relationship, acceleration factor and life characteristics under the normal condition temperature $30^{\circ}C$.

Accelerated Lifetime Data Analysis Using Quantile Regression (분위수 회귀를 이용한 가속수명시험 자료 분석)

  • Roh, Chee-Youn;Kim, Hee-Jeong;Na, Myung-Hwan
    • The Korean Journal of Applied Statistics
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    • v.21 no.4
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    • pp.631-638
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    • 2008
  • Accelerated Lifetime Test is a method of estimation of lifetime quality characteristics under operation condition with the accelerated lifetime data obtained under accelerated stress. In this paper we propose estimation method with accelerated lifetime data using quantile regression. We apply the method to real data with Arrhenius and Inverse power model.

Dielectric and Electrical Properties of Ce,Mn:SBN

  • Kang, Bong-Hoon;Paek, Young-Sop;Rhee, Bum-Ku;Lim, Ki-Soo;Joo, Gi-Tae
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.615-619
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    • 2003
  • Temperature and frequency dependence of dielectric and electrical properties was investigated in cerium and manganese doped Sr$\_$0.6/Ba$\_$0.4/Nb$_2$O$\_$6/(60SBN) ceramic system. Structural deformation of 60SBN by dopants did not appeared. 1350$^{\circ}C$-10 h sintered specimen had higher densification than 1250$^{\circ}C$-10 h sintered one, to which dielectric properties are related. That the feature of dielectric maxima peaks was typical Diffusive Phase Transition (DPT), it was explained by "random-field Ising model". Even though 60SBN has large dielectric loss at high frequency above 100 ㎑, it is desirable for optical applications because of low dielectric loss at low frequency. From Arrhenius plot of temperature, the activation energy was calculated to 0.45-0.49 eV.

A Study on the Evaluation Method for Durability Life of Vehicle,s ECU (자동차 제어기의 내구수명 평가방안 연구)

  • Kim, Byeong-Woo;Choi, Beom-Jin;Cho, Hyun-Duck;Lee, Do-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.2
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    • pp.208-213
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    • 2008
  • In order to assess the reliability of the electronics control unit for vehicles, accelerated life test model and procedure are developed. By using this method, failure mechanism and life distribution are analyzed. The main results are as follows : i) the main failure mechanism is degradation failure that is, junction destruction of a semiconductor resin by high temperature. ii) the life distribution of the electronics control unit for vehicles is fitted well to Weibull life distribution and the accelerated life model of that is fitted well to Arrhenius model. iii) at the result of the life distribution, accelerated life test method is developed, and test time for life assessment will be shortened by 5,000 hours by this test method.

Useful Lifetime Evaluation of Rubber Component for Elevator Cabin (승강기용 방진고무부품 특성 및 사용수명 평가)

  • Woo, Chang-Su;Park, Hyun-Sung
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.576-580
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    • 2008
  • Rubber material properties and useful life evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, the evaluation of characteristics and useful life prediction of rubber component for elevator cabin were experimentally investigated. The material test and accelerated heat-aging test were carried. Rubber material constants were obtained by curve fittings of simple tension, pure shear and bi-axial tension test data. Heat aging test results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the rubber material and component test several useful life prediction equations for rubber component were proposed. Predicted useful life of rubber component for elevator cabin agreed fairly with the experimental lives.

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Electron Transport in Stilbenquinone Derivative-Doped Polymer (Stilbenquinone 유도체가 도핑된 고분자의 전자 수송)

  • Cho, Jong-Rae;Jeong, Jae-Hoon;Moon, Jeong-Oh;Yang, Jong-Hyun;Son, Se-Mo;Kim, Kang-Eun;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.378-381
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    • 2001
  • The electron drift mobility of poly(4,4'-cyclohexylidenediphenyl carbonate) (PC-Z) doped with 3,5-dimethy-3,5-di-t-butylstilbenequinone(MBSQ), 3,5,3,5-tetra-t-butyl stilbenequinone(TBSQ) and 3,5,3,5-tetra-methyl stilbenequinone(TMSQ) was measured by the time-of-flight technique. The electric field and temperature dependences of the electron drift mobility were discussed with Poole-Frenkel, Arrhenius formulations and non-Arrhenius type of temperature dependence. It was assumed that the hopping sites were Gaussian distribution. Mobility and activation energy of MBSQ were increased with increasing dopant. However, mobilities and activation energy of TBSQ and TMSQ were increased and decreased, respectively.

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A Study on the Lifetime Prediction of Device by the Method of Bayesian Estimate (베이지안 추정법에 의한 소자의 수명 예측에 관한 연구)

  • 오종환;오영환
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.8
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    • pp.1446-1452
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    • 1994
  • In this paper, Weibull distribution is applied to the lifetme distribution of a device. The method of Bayesian estimate used to estimate requiring parameter in order to predict lifetime of device using accelerated lifetime test data, namely failure time of device. The method of Bayesian estimate needs prior information in order to estimate parameter. But this paper proposed the method of parameter estimate without prior information. As stress is temperature, Arrhenius model is applied and the method of linear estimate is applied to predict lifetime of device at the state of normal operation.

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