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UO22+ Ion-Selective Membrane Electrode Based on a Naphthol-Derivative Schiff's Base 2,2'-[1,2-Ethandiyl bis(nitriloethylidene)]bis(1-naphthalene)

  • Shamsipur, Mojtaba;Saeidi, Mahboubeh;Yari, Abdullah;Yaganeh-Faal, Ali;Mashhadizadeh, Mohammad Hossein;Azimi, Gholamhasan;Naeimi, Hossein;Sharghi, Hashem
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.629-633
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    • 2004
  • A new PVC membrane electrode for $UO_2^{2+}$ ion based on 2,2'-[1,2-ethanediyl bis (nitriloethylidene)]bis(1-naphthalene) as a suitable ionophore was prepared. The electrode exhibites a Nernstian response for $UO_2^{2+}$ ion over a wide concentration range ($1.0{\times}10^{-1}-1.0{\times}10^{-7}$M) with a slope of 28.5 ${\pm}$ 0.8 mV/decade. The limit of detection is $7.0{\times}10^{-8}$M. The electrode has a response time of < 20 s and a useful working pH range of 3-4. The proposed membrane sensor shows good discriminating abilities towards $UO_2^{2+}$ ion with regard to several alkali, alkaline earth transition and heavy metal ions. It was successfully used to the recovery of uranyl ion from, tap water and, as an indicator electrode, in potentiometric titration of $UO_2^{2+}$ ion with Piroxycam.

Improving cyclic behavior of multi-level pipe damper using infill or slit diaphragm inside inner pipe

  • Zahrai, Seyed Mehdi;Cheraghi, Abdullah
    • Structural Engineering and Mechanics
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    • v.64 no.2
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    • pp.195-204
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    • 2017
  • Analytical and experimental studies of the innovative pipe in pipe damper have been recently investigated by the authors. In this paper, by adding lead or zinc infill or slit diaphragm inside the inner pipe, it is tried to increase the equivalent viscous damping ratio improving the cyclic performance of the recently proposed multi-level control system. The damper consists of three main parts including the outer pipe, inner pipe and added complementary damping part. At first plastic deformations of the external pipe, then the internal pipe and particularly the added core and friction between them make the excellent multi-level damper act as an improved energy dissipation system. Several kinds of added lead or zinc infill and also different shapes of slit diaphragms are modeled inside the inner pipe and their effectiveness on hysteresis curves are investigated with nonlinear static analyses using finite element method by ABAQUS software. Results show that adding lead infill has no major effect on the damper stiffness while zinc infill and slit diaphragm increase damper stiffness sharply up to more than 10 times depending on the plate thickness and pipe diameter. Besides, metal infill increases the viscous damping ratio of dual damper ranging 6-9%. In addition, obtained hysteresis curves show that the multi-level control system as expected can reliably dissipate energy in different imposed energy levels.

Intensity measure-based probabilistic seismic evaluation and vulnerability assessment of ageing bridges

  • Yazdani, Mahdi;Jahangiri, Vahid
    • Earthquakes and Structures
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    • v.19 no.5
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    • pp.379-393
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    • 2020
  • The purpose of this study is to first evaluate the seismic behavior of ageing arch bridges by using the Intensity Measure - based demand and DCFD format, which is referred to as the fragility-hazard format. Then, an investigation is performed for their seismic vulnerability. Analytical models are created for bridges concerning different features and these models are subjected to Incremental Dynamic Analysis (IDA) analysis using a set of 22 earthquake records. The hazard curve and results of IDA analysis are employed to evaluate the return period of exceeding the limit states in the IM-based probabilistic performance-based context. Subsequently, the fragility-hazard format is used to assess factored demand, factored capacity, and the ratio of the factored demand to the factored capacity of the models with respect to different performance objectives. Finally, the vulnerability curves are obtained for the investigated bridges in terms of the loss ratio. The results revealed that decreasing the span length of the unreinforced arch bridges leads to the increase in the return period of exceeding various limit states and factored capacity and decrease in the displacement demand, the probability of failure, the factored demand, as well as the factored demand to factored capacity ratios, loss ratio, and seismic vulnerability. Finally, it is derived that the probability of the need for rehabilitation increases by an increase in the span length of the models.

COFINITENESS OF GENERAL LOCAL COHOMOLOGY MODULES FOR SMALL DIMENSIONS

  • Aghapournahr, Moharram;Bahmanpour, Kamal
    • Bulletin of the Korean Mathematical Society
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    • v.53 no.5
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    • pp.1341-1352
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    • 2016
  • Let R be a commutative Noetherian ring, ${\Phi}$ a system of ideals of R and $I{\in}{\Phi}$. In this paper among other things we prove that if M is finitely generated and $t{\in}\mathbb{N}$ such that the R-module $H^i_{\Phi}(M)$ is $FD_{{\leq}1}$ (or weakly Laskerian) for all i < t, then $H^i_{\Phi}(M)$ is ${\Phi}$-cofinite for all i < t and for any $FD_{{\leq}0}$ (or minimax) submodule N of $H^t_{\Phi}(M)$, the R-modules $Hom_R(R/I,H^t_{\Phi}(M)/N)$ and $Ext^1_R(R/I,H^t_{\Phi}(M)/N)$ are finitely generated. Also it is shown that if cd I = 1 or $dimM/IM{\leq}1$ (e.g., $dim\;R/I{\leq}1$) for all $I{\in}{\Phi}$, then the local cohomology module $H^i_{\Phi}(M)$ is ${\Phi}$-cofinite for all $i{\geq}0$. These generalize the main results of Aghapournahr and Bahmanpour [2], Bahmanpour and Naghipour [6, 7]. Also we study cominimaxness and weakly cofiniteness of local cohomology modules with respect to a system of ideals.

Effect of Different Budding Methods and Times on Grafting Success of Walnut

  • Nosrati, Zia;Khadivi-Khub, Abdollah
    • Horticultural Science & Technology
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    • v.32 no.6
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    • pp.788-793
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    • 2014
  • Vegetative propagation of walnut is difficult compared with that of other fruit and nut species. The present study assessed three methods of grafting (patch, shield, and chip) at various periods of walnut growth and with different timings of grafting in walnut. Early May was the best time for grafting, at which time the highest success rate was obtained by the patch method (96%), followed by chip-budding (75%), while shield-grafting showed the lowest efficiency (10%). Patch-grafting was also successful (75-80%) in early August and moderately successful in mid-June (51-55%), while the shield and chip methods had no success during these two times (0.00%). Patch-grafting was more efficient and also induced better callus formation and scion growth than the other two methods. The genotypes used did not affect grafting efficiency. The best results were obtained by patch-budding in both tested genotypes. The present findings show the potential value of patch-grafting in early May as a propagation method for walnut for establishment of guidelines for propagation.

Kinetic Study of the Electrooxidation of Mefenamic Acid and Indomethacin Catalysed on Cobalt Hydroxide Modified Glassy Carbon Electrode

  • Saghatforoush, Lotfali.;Hasanzadeh, Mohammad.;Karim-Nezhad, Ghasem.;Ershad, Sohrab.;Shadjou, Nasrin.;Khalilzadeh, Balal.;Hajjizadeh, Maryam.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1341-1348
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    • 2009
  • Electrocatalytic oxidation of two anti-inflammatory drugs (Mefenamic acid and Indomethacin) was investigated on a cobalt hydroxide modified glassy carbon (CHM-GC) electrode in alkaline solution. The process of oxidation and its kinetics were established by using cyclic voltammetry and chronoamperometry techniques as well as steady state polarization measurements. Voltammetric studies indicated that in the presence of under study drugs, the anodic peak current of low-valence cobalt species increased, followed by a decrease in the corresponding cathodic current. This result indicates that the drugs were oxidized via cobalt hydroxide species immobilized on the electrode surface via an E$\acute{C}$ mechanism. A mechanism based on the electrochemical generation of Co (IV) active sites and their subsequent consumption by the drugs in question was also investigated. The constants rate of the catalytic oxidation of the drugs and the electron-transfer coefficients reported.

Flexural ductility of reinforced HSC beams strengthened with CFRP sheets

  • Hashemi, Seyed Hamid;Maghsoudi, Ali Akbar;Rahgozar, Reza
    • Structural Engineering and Mechanics
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    • v.30 no.4
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    • pp.403-426
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    • 2008
  • Externally bonding fiber reinforced polymer (FRP) sheets with an epoxy resin is an effective technique for strengthening and repairing reinforced concrete (RC) beams under flexural loads. Their resistance to electro-chemical corrosion, high strength-to-weight ratio, larger creep strain, fatigue resistance, and nonmagnetic and nonmetallic properties make carbon fiber reinforced polymer (CFRP) composites a viable alternative to bonding of steel plates in repair and rehabilitation of RC structures. The objective of this investigation is to study the effectiveness of CFRP sheets on ductility and flexural strength of reinforced high strength concrete (HSC) beams. This objective is achieved by conducting the following tasks: (1) flexural four-point testing of reinforced HSC beams strengthened with different amounts of cross-ply of CFRP sheets with different amount of tensile reinforcement up to failure; (2) calculating the effect of different layouts of CFRP sheets on the flexural strength; (3) Evaluating the failure modes; (4) developing an analytical procedure based on compatibility of deformations and equilibrium of forces to calculate the flexural strength of reinforced HSC beams strengthened with CFRP composites; and (5) comparing the analytical calculations with experimental results.

Effect of Alternaria solani Exudates on Resistant and Susceptible Potato Cultivars from Two Different pathogen isolates

  • Shahbazi, Hadis;Aminian, Heshmatollah;Sahebani, Navazollah;Halterman, Dennis
    • The Plant Pathology Journal
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    • v.27 no.1
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    • pp.14-19
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    • 2011
  • Early blight of potato, caused by Alternaria solani, is a ubiquitous disease in many countries around the world. Our previous screening of several Iranian potato cultivars found that significant variation in resistance phenotypes exists between two cultivars: resistant 'Diamond' and susceptible 'Granula'. Our previous analysis of five different pathogen isolates also identified varying degrees of aggressiveness regardless of the host cultivar. Here, a bioassay was used to study the role of liquid culture exudates produced in vitro on pathogenicity and elicitation of disease symptomology in seedlings as well as detached leaves. Responses of host genotypes to the exudates of the two A. solani isolates were significantly different. Detached leaves of the resistant cultivar 'Diamond' elicited fewer symptoms to each isolate when compared to the susceptible cultivar 'Granula'. Interestingly, the phytotoxicity effect of the culture filtrate from the more aggressive isolate A was higher than from isolate N suggesting an increased concentration or strength of the toxins produced. Our results are significant because they indicate a correlation between symptoms elicited by A. solani phytotoxins and their aggressiveness on the host.

Mathematical modelling of the stability of carbon nanotube-reinforced panels

  • Sobhani Aragh, B.
    • Steel and Composite Structures
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    • v.24 no.6
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    • pp.727-740
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    • 2017
  • The present paper studies the stability analysis of the continuously graded CNT-Reinforced Composite (CNTRC) panel stiffened by rings and stringers. The Stiffened Panel (SP) subjected to axial and lateral loads is reinforced by agglomerated CNTs smoothly graded through the thickness. A two-parameter Eshelby-Mori-Tanaka (EMT) model is adopted to derive the effective material moduli of the CNTRC. The stability equations of the CNRTC SP are obtained by means of the adjacent equilibrium criterion. Notwithstanding most available literature in which the stiffener effects were smeared out over the respective stiffener spacing, in the present work, the stiffeners are modeled as Euler-Bernoulli beams. The Generalized Differential Quadrature Method (GDQM) is employed to discretize the stability equations. A numerical study is performed to investigate the influences of different types of parameters involved on the critical buckling of the SP reinforced by agglomerated CNTs. The results achieved reveal that continuously distributing of CNTs adjacent to the inner and outer panel's surface results in improving the stiffness of the SP and, as a consequence, inclining the critical buckling load. Furthermore, it has been concluded that the decline rate of buckling load intensity factor owing to the increase of the panel angle is significantly more sensible for the smaller values of panel angle.

Transient thermoelastic analysis of carbon/carbon composite multidisc brake using finite element method

  • Ghashochi-Bargh, Hadi;Goodarzi, Mohammad-Saeed;Karimi, Masoud;Salamat-Talab, Mazaher
    • Advances in aircraft and spacecraft science
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    • v.7 no.2
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    • pp.135-149
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    • 2020
  • In the current paper, a generalization of the results of Zhao et al. (2008) on a new design of C/C composite multidisc brake system is presented. The purpose of this paper is to study the effect of thermal sensitivity of Carbon/Carbon (C/C) composite material on the temperature distributions, deformation, and stress during braking. In this regard, a transient temperature-displacement coupled analysis for C/C composite brake discs with frictional heat generation under simulated operating conditions is performed. An axisymmetric model for brake system is used for the finite element analysis according to the theory of energy transformation and transportation. The transient temperature distributions on the friction surfaces, deformation, and stress are obtained. To check the validity, the results are corroborated with other solutions available in the literature, wherever possible. The current study could be used as a guide in the initial design of a high performance multidisc brake system.