• Title/Summary/Keyword: Aqueous system

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Evaluation of Ice Adhesion in an Aqueous Solution with Functional Materials by Stirring Power (교반동력에 의한 기능성 물질 함유 수용액의 빙부착 평가)

  • Seung, Hyun;Baek, Jong-Hyun;Hong, Hee-Ki;Kang, Chae-Dong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.8
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    • pp.720-727
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    • 2004
  • In the process of ice-slurry making, the phenomenon of ice adhesion influences extremely to ice making system. In this study, the effect on the ice adhesion by thermal storage material with additives is investigated quantitatively. Various solutions of 300 g in a stainless vessel were frozen under stirring. Through the experiment the ice adhesion between cooling wall and ice-slurry was compared with each other by measuring the stirring power. From the experiment, the stirring power in EG, SCA solution was smaller than those in the solution containing functional materials, such as poly-vinyl-alcohol or kitchen detergent.

Preparation of NR/MG Latex Blend Films and its Mechanical Properties (NR/MG Latex 블랜드필름의 제조 및 그의 기계적특성)

  • Kim, K.S.;Park, J.H.;Eum, J.S.;Kim, S.J.
    • Elastomers and Composites
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    • v.29 no.1
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    • pp.9-17
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    • 1994
  • Methylmetharylate grafted latex(MGL) was prepared by emulsion graft copolymerization of methyl methacrylate onto natural rubber latex(NRL) by using t-butyl hydroperoxide and tetraethylene pentamine in an aqueous medium. Blending of MGL and NRL with different mixing ratio carried out and viscosity and particle size distribution of blend latex were determined. It was found that the optimum condition of mature time, vulcanizing temperature and time for preparation of blend latex films were investigated. latex films prepared by dipping process were meaured. As the reuslt, blend latex(NR-d-MG) films obtained from two-dipping system were more excellent than NR and MG film obtained from one-dipping system.

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The Conduction Properties of Epoxy Resin Composition According to the Content Change of Spherical Hollow Type Silver (중공형 구형 은입자의 함량변화에 따른 에폭시 수지조성물의 전도특성 연구)

  • Kim, Whan Gun;Lim, Ryun Woo
    • Journal of the Semiconductor & Display Technology
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    • v.11 no.2
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    • pp.23-26
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    • 2012
  • The monodispersed polystyrene spheres were prepared by emulsion polymerization in aqueous alcohol system. They coated with silver by reduction of silver ion percolated on the surface of them. The spherical hollow type silver has been prepared by dissolving polystyrene with toluene. Epoxy resin compositions with spherical hollow type silver were manufactured, which were composed of a bisphenol F type epoxy resin (RE-304S), amine type hardener (Kayahard AA), and 1-benzyl 2-methyl imidazole (1B2MI) as catalyst. The electrical conductivity with silver content ratio were investigated after cure, the percolation threshold weight ratio for conductance in this epoxy resin system was obtained above the 70 wt% of silver.

Degradation of 2,3-dichlorophenol by a Photo-Fenton Process with Continuous Pump-Feeding of Hydrogen Peroxide (동력펌프주입식 광펜톤시스템에 의한 2,3-디염화페놀 분해특성 연구)

  • Kim, Il-Kyu
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.84-90
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    • 2014
  • The degradation of 2,3-dichlorophenol(2,3-diCP) by various advanced oxidation systems with continuous feeding of hydrogen peroxide including the ultraviolet/hydrogen peroxide, the Fenton and the photo-Fenton process has been conducted. The highest removal efficiency for 2,3-diCP in the aqueous phase was obtained by the photo-Fenton process among the advanced oxidation systems. In the photo-Fenton process, The removal efficiency of 2,3-diCP decreased with increasing pH in the range of 3 to 6, and it decreased with increasing initial concentration. As the intermediates of 2,3-diCP by photo-fenton reaction, 3,4-chlorocatechol and 2,3-dichlorohydroquinone were detected, thus the degradation pathways were proposed.

Thermodynamic Properties of the Solute Transfer from the Aqueous Acetonitrile Mobile Phase to the Stationary Phase Monitored by HPLC

  • Jeong, Won Jo;Kim, Ji Yeon;Gu, Yun Mo
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.105-109
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    • 2000
  • High-performance liquid chromatography is suitable for getting thermodynamic information about solute-solvent interactions. We used a squalane impregnated $C_{18}$ phase as a presumably bulk-like stationary phase to secure a simple partition mechanism for solute retention in reversed phase liquid chromatographic system. We measured retention data of some selected solutes (benzene, toluene, ethylbenzene, propylbenzene, butylbenzene, phenol, benzylalcohol, phenethylalcohol, benzylacetone, acetophenone, benzonitrile, benzylcyanide) at 25, 30, 35, 40, 45, and 50 $^{\circ}C$ in 30/70, 40/60, 50/50, 60/40 and 70/30 (v/v%) acetonitrile/water eluents. The van't Hoff plots were nicely linear, thus we calculated dependable thermodynamic values such as enthalpies and entropies of solute transfer from the mobile phase to the stationary phase based on more than four retention measurements on different days (or weeks). We found that the cavity formation effect was the major factor in solute distribution between the mobile and stationary phases in the system studied here. Our data were com-pared with some relevant literature data.

Minimization of Asymmetry Potential in ETH 129-Based Calcium-Selective Membrane Electrodes

  • 박성배;정사라;차근식;김해동
    • Bulletin of the Korean Chemical Society
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    • v.16 no.11
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    • pp.1033-1037
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    • 1995
  • PVC-based calcium-selective electrodes doped with ETH 129 usually suffer from a shift in the standard potential when they are in contact with protein-containing solutions (e.g. blood serum) after being calibrated with aqueous standards. The shift is due to the development of asymmetry potential in inherently symmetric PVC membranes through the contamination of outer membrane surface by proteins in the biological samples. Membranes prepared with polyurethane showed much reduced shifts in terms of standard potential. This study was performed with a flow-injection system following a protocol designed to observe minor shifts in baseline potential. Other electrochemical properties of the system, including selectivity and response slope, were similar to those obtained with regular PVC-based ones. PVC-based calcium selective membrane electrodes, doped with commonly used ETH 1001, were also tested to compare their electrochemical performances.

A Novel Ocular Delivery System for Phenylephrine Hydrochloride

  • Durrani, A.M.;Jamshaid, M.;Kellaway, I.W.
    • Archives of Pharmacal Research
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    • v.19 no.5
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    • pp.386-389
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    • 1996
  • The in vivo behaviour of phenylephrine hydrochloride in different vehicles like gels of Carbopol $907^circledR$, Carbopol $934P^circledR$ and latex system of cellulose acetate hydrogen phthalate(CAHP) was evaluated by measuring the reduction in intraocular pressure and the mydriatic activity. The parameters that haave been utilised to assess the performance of the formulations were the area under the curve (AUC), the maximum mydriasis $(I_{max})$, ethe time of maximum response $(T_{max})$ and the duration of activity (D). The influence of viscosity and mucoadhesion on the bioavailability parameters has also been investigated. Carbopol 934P and CAHP formulations showed prolonged duration of action and greater AUC compared to Carbopol 907 aqueous solution(P<0.05).

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Development of Asymmetric Resolution System for the Production of Chiral Styrene Oxide by Microbial Epoxide Hydrolase (미생물 유래의 Epoxide Hydrolase를 이용한 Chiral Styrene Oxide 생산용 비대칭 광학분할시스템개발)

  • 이지원;윤여준;이은열
    • Journal of Life Science
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    • v.12 no.5
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    • pp.584-588
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    • 2002
  • Asymmetric enantioselective resolution system using epoxide hydrolase activity of Aspergillus niger LK was developed and operated for the production of optically pure styrene oxide. Two-phase hollow-fiber reactor system was employed for the enhanced solubility of racemic styrene oxide in organic phase and protection of epoxide hydrolase activity in aqueous phase. For the removal of phenyl-1,2-ethandiol, the inhibitor of epoxide hydrolase, cascade hollow-fiber reactor system was also developed. Chiral (S)-styrene oxide (39 mM in dodecane) could be asymmetrically resolved with high enantiopurity (> 99% ee) using these reactor system.

Browning Pattern and Pigment of Glucose/Glycine Model Systems (글루코스-글리신 혼합용액의 갈색화 패턴 및 색소)

  • Nam, Sang-Sook;Lee, Mie-Soon
    • Korean Journal of Food Science and Technology
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    • v.16 no.2
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    • pp.218-222
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    • 1984
  • Browning pattern was developed in aqueous solutions of glucose/glycine mixture under controlled conditions. Browning pattern was definitely influenced by pH of medium and concentration of reactants. Filter paper disks were immersed in diluted solutions of glucose/glycine system and fried in cooking oil. Concentrations of reactants only affected browning pattern of fried filter paper disks and pH effect was obscured at high temperatures. Amorphous brown precipitate was obtained from the lowest pH medium of glucose/glycine system. An attempt was made to characterize the brown pigment produced in the present model system.

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Evaluation of inactivation kinetics on pathogenic microorganisms by free chlorine/UV hybrid disinfection system (전해 염소수/자외선 결합 시스템을 이용한 병원성 미생물의 불활성화 키네틱스 평가)

  • Seo, Young-Seok;Kim, Aerin;Cho, Min
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.5
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    • pp.379-388
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    • 2019
  • Chlorination and UV illumination are being widely applied to inactivate a number of pathogenic microbials in the environment. Here, we evaluated the inactivation efficiency of individual and combined treatments of chlorination and UV under various aqueous conditions. UV dosage was required higher in waste water than in phosphate buffer to achieve the similar disinfecting efficiency. Free chlorine generated by electrolysis of waste water was abundant enough to inactivate microbials. Based on these, hybrid system composed of sequential treatment of electrolysis-mediated chlorination and UV treatment was developed under waste water conditions. Compared to individual treatments, hybrid system inactivated bacteria (i.e., E. coli and S. typhimurium) and viruses (i.e., MS-2 bacteriophage, rotavirus, and norovirus) more efficiently. The hybrid system also mitigated the photo re-pair of UV-driven DNA damages of target bacteria. The combined results suggested the hybrid system would achieve high inactivation efficiency and safety on various pathogenic microbials in wastewater.