• Title/Summary/Keyword: Aqueous system

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Acceleration Test of Ion Migration for PCB Electronic Reliability Evaluation (PCB 전기적 신뢰성평가를 위한 이온 마이그레이션 가속시험)

  • Lee, D.B.;Kim, J.H.;Kang, S.K.;Chang, S.W.;Lim, J.H.;Ryu, D.S.
    • Journal of Power System Engineering
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    • v.9 no.1
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    • pp.64-69
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    • 2005
  • In evaluation of electronic reliability on the PCB(Print Circuit Borad),electrochemical migration is one of main test objects. The phenomenon of electrochemical migration occurs in the environment of the hight humidity and the hight temperature under bias through a continuous aqueous electrolyte. In this paper, the generating mechanism of electrochemical migration is investigated by using water drop acceleration test under various waters. The waters used in the water drop test are city water, distilled water and ionic water. It found that the generated velocity of electrochemical migration depended on electrolyte quantity which included in the various waters.

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Polarization Characteristics of Thermal Sprayed Coating Layer (용사코팅층의 분극특성)

  • Ahn, S.H.;Kim, S.J.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.8 no.4
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    • pp.38-43
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    • 2004
  • Thermal spraying onto the metal substrate has been widely used as a technique of the surface treatment in the various industrial field. A wide range of thermal spray technologies exist and all rely on the fundamental process of fusing a metal feedstock, atomizing it and transporting it to the surface of a substrate. Specially, these methods have been taken into account as the protection method against the corrosion. In this study, the polarization characteristics were carried out on the thermal sprayed coating layer immersed in various pH of diluted aqueous solutions at $25^{\circ}C$. Aluminum, Zinc, Ni-base alloy, alumina and polyethylene powder were used with sprayed coating materials. From the polarization curves, the electrochemical corrosion potential($E_{corr}$) and the corrosion current density($I_{corr}$) were investigated.

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Removing of Phosphate, Nitrogen and Anion surfactants in the Wastewater using ALC (경량기포콘크리트를 이용한 인과 질소 및 음이온계면활성제 제거)

  • 홍영호
    • Journal of environmental and Sanitary engineering
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    • v.16 no.1
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    • pp.102-107
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    • 2001
  • This research was carried out investigate the removed T-P, T-N and anion surfactants using Autoclaved Lightweight Concrete(ALC) in wastewater treatment system. Effects of pH, TDS on aqueous solution was measured. Specific area which measured by BET was $27.66m^2/g$. The phosphorous, nitrogen and anion surfactants removal efficiencies were examined by using artificial waste water(T-P : 66~73mg/L, T-N : 56~136mg/L and anion surfactants : 10~31mg/L). The results showed that the ALC was effective material as a adsorbent due to the structure and porosity. It was found that anion surfactants removed was 85~95%, phosphate removed was 92% and nitrogen removed was 90% in artificial wastewater. Agitation process was more effective than aeration process in that case of nitrogen removal system using ALC.

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Study on Thermal Neutron Efficiency for Neutron Induced Prompt Gamma-ray Spectrometer Using Various Reflectors (즉발감마선 계측시스템의 반사체를 이용한 열중성자 효율증대 연구)

  • Park, Y.J.;Song, B.C.;Jee, K.Y.
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.426-429
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    • 2003
  • Neutron induced prompt gamma-ray spectroscopy (NIPS) system equipped with a $^{252}Cf$ neutron source and a n-type coaxial HPGe detector was installed for the quantitative analysis of aqueous samples in KAERI, Korea. Since the thermal neutron flux for the $^{252}Cf$ neutron source is relatively low compared to that for the reactor, the use of a thermal neutron reflector in the NIPS system may lead to improved results. The enhancement by using various reflectors was carried out by comparing the Cl peak with or without a cadmium plate between sample and the $^{252}Cf$ source. The use of pyrolitic graphite as a reflector provided a good result.

On Compositional Convection in Near-Eutectic Solidification System Cooled from a Bottom Boundary

  • Hwang, In Gook
    • Korean Chemical Engineering Research
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    • v.55 no.6
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    • pp.868-873
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    • 2017
  • Natural convection is driven by the compositional buoyancy in solidification of a binary melt. The stabilities of convection in a growing mushy layer were analyzed here in the time-dependent solidification system of a near-eutectic melt cooled impulsively from below. The linear stability equations were transformed to self-similar forms by using the depth of the mushy layer as a length scale. In the liquid layer the stability equations are based on the propagation theory and the thermal buoyancy is neglected. The critical Rayleigh number for the mushy layer increases with decreasing the Stefan number and the Prandtl number. The critical conditions for solidification of aqueous ammonium chloride solution are discussed and compared with the results of the previous model for the liquid layer.

Electrochemical Reduction of Nitrate Ion in an Aqueous Solution (수용액에서 질산성 질소의 전기화학적 환원거동)

  • Park, J.K.;Jeon, C.J.;Lee, C.K.
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.246-251
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    • 2003
  • 전기분해법을 이용하여 수용액 중의 질산성 질소의 환원거동에 대한 연구를 통하여 수용액중의 질산 함량을 제어하는 연구를 수행하였다. 촉매전극을 채택한 복극전해조에서 30분의 조업에 질산 100ppm 이하의 저농도 용액은 70%, 300ppm 이상의 고농도의 경우는 90%까지 질소를 용이하게 제거할 수 있었다. 초기 질소농도가 증가하면서 한계전류밀도도 크게 증가하였으며, pH가 감소할수록 환원전류가 증가하였다. 그리고 수용액의 pH는 질소 환원반응기구에 큰 영향을 주는 것으로 판명되었으며, 산성에서는 질소형태로 중성 혹은 염기성에서는 암모니아 형태로 환원되는 것으로 추정된다.

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Biological screening of 100 plant extracts for cosmetic use (1) Antioxidative activity and free radical scavenging activity

  • Kim, Jeong-Ha;Kim, Beom-Jun;Seok, Chung-Hyun;Won, Il;Kim, Jeong-Haeng;Kim, Hyun-Pyo;Heo, Moon-Young
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.2
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    • pp.115-123
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    • 1996
  • Methanolic aqueous extracts of 100 plants were screened for antioxidative activity using Fenton's reagen/ethyl linoeate system and free radical scavenging activity using DPPH free radical generating system. The results suggest that at least six plants including Eugenia caryophyllata, Alpinia offiicinarum, Rhus verniciflua, Curcuma longa, Rheum palmatvm and Evodia officinalis may be the potential sources of antioxidant, But only one plant, Cornus officinalis, may be the potential source of free radical scavenger from natural plants.

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Dissolution properties of Chitin or Chitosan Microsphere Containing p-Aminosalicylic Acid (p-Aminosalicylic acid를 포함하고 있는 Chitin, Chitosan-Microsphere의 용출특성)

  • 임정수;김공수
    • Journal of Biomedical Engineering Research
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    • v.10 no.1
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    • pp.59-66
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    • 1989
  • The Applicability of chitin or chitosan microsphere as means to achieve sustained release of p-aminosalicylic acid(PAS) has been examined. The microsphere of chitin or chitosan containing PAS were prepared by coacervation in acidic aqueous system in range of pH 2.0-4.0. The dissolution test of PAS from polymeric drug system was carried out in vitro test. The dissolution rate of PAS from the microsphere with chitin was significanthly lower than that from the microsphere with chitosan.The dissolution rate of PAS from the microsphere was decreased with increasing of concentration of chitin and chitosan. The sustained release of PAS from the microsphere was more effective at pH 1.2 than pH 6.8.

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A Novel Oxidation Model with Photolysis for Degradation of Trichlorobenzenes (TCBs)

  • Kim, Jae-Hyoun
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.1-13
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    • 1997
  • First- and second-order kinetic oxidation rates of trichlorobenzenes (TCBs) were obtained and compared by a chemical activation system (CAS) which mimics mixed functional oxidase activity. The system consists of EDTA, ferrous sulfate, ascorbic acid, and $H_2O_2$ in potassium phosphdte buffer (monobasic at pH 7.4). The rate of transformation in CAS was enhanced in the presence and absence of catalase in the sequence 1, 2, 3-TCB < 1, 2, 4-TCB < 1, 3, 5-TCB. In general, the rates of degradation were greater in the test media with catalase. The effect of photolysis on the degradation of the TCBs with the CAS were examined. Sensitized photolysis with nitrite, Fenton's reagent, TiO$_2$ and triethylamine (TEA) studied in concert with the CAS demonstrated significant enhancement of the degradation rate of TCBs. Disappearance rates of TCBs in CAS with prior photolysis or prior photosensitization were at least 10-fold higher than the sum of the rate for each single experiment. This study proves that the combination of the CAS and photolysis can be used as a suitable technique for enhancing degradation of TCBs in aqueous systems.

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A new Aqueous Injection Molding Method of Fabricating W-Cu Pseudo-alloy Part (수계 바인더를 이용한 W-Cu 합금의 새로운 사출성형법 연구)

  • Lee Jeong-Keun
    • Journal of Powder Materials
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    • v.13 no.1 s.54
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    • pp.57-61
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    • 2006
  • The present work illustrates the use of water-soluble cupric salts as ingredients of binder for injection molding of $W-10 wt\%$ Cu. Parts produced are dense, homogeneous and have good surface finish, compared to those produced using conventional binder system. This new binder system provides also process-simplification benefit. $CuCl_2\;and\;Cu(NO_3)_2$ with the purity of $98\%$ was selected for this study. Rapid sintering process involving thermal decomposing was successful in densification for 1h. Final density that is about $93\%$ of theoretical value could be obtained, and are distinguishable from conventionally processed W-Cu composites.