• Title/Summary/Keyword: Aqueous binder

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Surface Potential Behavior of Nano $CeO_2$ Particles in Aqueous Media (수계분산매체에서 나노 $CeO_2$ 입자의 계면전위 거동)

  • 이태원;백운규;최성철;이상훈;임형섭;김철진
    • Journal of the Korean Ceramic Society
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    • v.37 no.7
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    • pp.721-725
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    • 2000
  • In this study, the dispersion stability of nano-sized CeO2 particles, synthesized by hydrothermal method in aqueous was evaluated from observing the surface potential behavior of CeO2 particle synthesized by solid state reaction. The isoelectric point(IEP) of nano-sized CeO2 synthesized by hydrothermal synthesis was found to be pH 9 contrary to the isoelectric point of micro-sized CeO2 synthesized by solid state reaction at pH 6.7. IEP was shifted to pH 2.0 as the addition of D-3019 from 0.1 to 1.0 wt%. The surface potential of CeO2 particles synthesized by hydrothermal synthesis was reduced as the addition of B-1001 used as a binder without change of IEP because the absorption of B-1001 polymer on the CeO2 particles shifted the shear plane of CeO2 particles outward away from the surface. This surface potential behavior was well correlated with the dispersion stability of slurry.

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터 의 개발)

  • 오길훈;김한주;최원경;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Rheology of Slurries and Effects of Polymer Volume Ratio in Aqueous PZT Tape Casting

  • Yoon, Seok-Jin;Shin, Hyo-Soon;Lee, Dong-Kyun;Kang, Chong-Yun;Park, Ji-Won;Kim, Hyun-Jai
    • The Korean Journal of Ceramics
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    • v.7 no.1
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    • pp.16-19
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    • 2001
  • For the fast dry of the aqueous tape, the process which water was reaplaced by organic solvent was proposed. Socalled, it was the solvent washing dry. Three organic solvents (methanol, ethanol and acetone) were selected for the washing solvent. The weight loss of the washed tapes was measured to evaluate the dry rate of the tapes and dried tapes were examined the generation of the cracks with the variations of the organic solvent and the washing time. Methanol, ethanol and acetone were available organic solvents for this method. The tapes washed in methanol, ethanol and acetone were dried rapidly for twenty minutes. After thirty minutes, the weight losses were not found any more, The solvent of the lower surface tension can decreases the crack of dried tape. If solvent substitutes water completely, though it was fast dried, crack can be eliminated.

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Adsorption Characteristics of Activated Carbon Blocks for Water Purifier Varying Binder Particle Sizes (바인더 입자크기에 따른 정수용 활성탄 블록의 흡착 특성)

  • Kang, Kwang Cheol;Ju, Jin-Hee
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.668-671
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    • 2013
  • This paper describes activated carbon block filters prepared by extrusion for water purifier. The specific surface area of the activated carbon blocks affecting the properties of a polymer binder were investigated. Polyethylene (PE) particles were used as a binder polymer and the effect of particle sizes on changes in the specific surface area of activated carbon blocks in addition to the adsorption properties of chloride anion in the aqueous solution were investigated. The sizes and shapes of PE particles were measured using SEM. The specific surface area of activated carbon was $1186m^2/g$. The specific surface area of PE binder was $444m^2/g$ and $940m^2/g$ with the particle sizes of $200{\mu}m$ and $20{\mu}m$, respectively. In order to verify the performance of the filter, chlorine adsorption experiments were conducted.

Factors Influencing Instant Properties of Agglomerated Food (조립화된 분말식품의 인스탄트성질에 영향을 미치는 인자)

  • Park, Hyun-Jin;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.18 no.1
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    • pp.48-54
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    • 1986
  • Influencing factors on the instant properties of agglomerated parched barley powder prepared by fluidized bed agglomerator were investigated. Instant effect was measured by the determination of wettability, sinkability, dispersibility and solubility of agglomerated particles. Instant effect of agglomerated particle was influenced by sorts of binding materials, concentration of aqueous binder solution and agglomerated particle diameter. The binding materials for agglomerated process were water and aqueous solution of glucose, maltose and gelatin. Instant effect of agglomerated particles increased as the concentration of aqueous sugar solution increased. However, the effect of aqueous solution of gelatin on instant effect was inversely proportional to the concentration. The size of agglomerated particle had an outstanding effect on instant properties and the diameter of agglomerated particle ranging from 0.1 mm - 0.3 mm showed the excellent instant effect.

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Fabrication of Transparent Dielectric Green Sheet for Plasma Display Panel (PDP 투명유전체 형성용 Green Sheet 제조)

  • Heo, Sung-Cheol;Park, Duck-Kyun;Oh, Young-Jei
    • Journal of the Korean Ceramic Society
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    • v.41 no.4
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    • pp.277-283
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    • 2004
  • To fabricate green sheet of transparent dielectric for PDP front panel, dispersion of transparent dielectric slurry, density, and mechanical properties of green sheets have been investigated as a function of amount and composition of organic additives. Measurements of sedimentation and viscosity were employed to determine a proper dispersant and its amount for a well dispersed transparent dielectric powders in non-aqueous system. Green sheets, having various ratios of transparent dielectric powders to transparent dielectric powders+ binder+plasticizer and binder to binder+plasticizer, were fabricated. All the tape casting slurries showed shear thinning effect, that is, the apparent viscosity decreased with the increase of shear rate. It was found that the amount and composition of organic additives were main variables to affect densities and mechanical properties of transparent dielectric green sheets for PDP.

Effect of Mixing Ratio of Amphoteric and Anionic Latices on Print Quality of Coated Papers (라텍스의 혼합비율이 도공지 품질에 미치는 영향)

  • 강태근;박규재;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.72-79
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    • 1999
  • The binder plays important roles in determining the quality of pigment coating. In addition to its primary role of binding the pigment to the base paper, the binder performs several other important functions. The binder, also referred to as the adhesive, is the dominant in the aqueous phase of the formulation. Thus it plays a major role in determining viscosity, rheology, water release, and setting time for the coating. Latices based on styrene-butadiene dominate the market for synthetic paper coating binders. Consumption is high and is expected to increase further due to the present tendeyncy toward high-solids coating. The purpose of this study is understanding the impact of various parameters of latex(i.e. Tg, Particle size) affecting prontabilities and optical properties of the coated papers, as well as providing basic information on the use of amphoteric latex for improving print qualities of coated papers. Recently, amphoteric latices, Which are cationic at low pH's but turn anionic at high pH's have attracted interests of paper scientists and engineers. Therefore we investigated the effect of the Tg(glass transition temperature) and particle size of amphoteric latex on the coating qualities. We also studied the effect of mixing ratios (Amphoteric / Anionic)of latex on the coating qualities. Our results showed that Tg and particle size of amphoteric latex have to be controlled for optimizing coated paper qualities. The formulation consisting of 10 parts of amphoteric latex and 5 parts of anionic latex gave best results in ink receptivity, smoothness, air permeability, opacity and sheet gloss. If the results hold for the industrial paper coatings, the amount of expensive amphoteric latex can be reduced while achieving best available printing quality.

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LTCC Tape Characterization as Organic formulation (유기물 조성에 따른 LTCC 테입 특성 연구)

  • Lim, W.;Kang, B.H.;Yoo, Y.S.;Lee, Y.S.;Cho, H.M.;Lee, W.S.;Kang, N.K.
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2000.11a
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    • pp.89-92
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    • 2000
  • Non-aqueous tape casting of LTCC with PVB binder has been studied in a continuous tape casting machine. The aim of the study was to evaluate this type of system in the different Binder/Plasticizer and solid content compositions. Each four slurry compositions were used in the experiments with varied binder/plasticizer and solid content. All the slurries gave good quality tapes with smooth surfaces without blisters or pinholes. The highest mechanical properties was obtained for the B/P=3.0, powder content 70vol% composition from 52 ${\mu}{\textrm}{m}$ green tapes, a tensile strength of 4.6 MPa and a linear extension of 29.5%

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Effect of Immersion and High Temperature on Shear Strength of Cemented Sand (수침 및 고온이 고결모래의 전단강도에 미치는 영향)

  • Moon, Hong Duk;Hwang, Keum-Bee;Kim, Tae-hun;Park, Sung-Sik
    • Journal of the Korean Geotechnical Society
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    • v.39 no.7
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    • pp.17-30
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    • 2023
  • This study investigates the impact of water immersion and high temperature on the shear strength of cemented sand through direct shear tests. Standard Jumunjin sand was used and cemented with binders, such as ultra-rapid hardening cement and an epoxy aqueous solution. The binder was mixed at concentrations of 4%, 8%, or 12%. Subsequently, cylindrical cemented specimens with a diameter of 64 mm and height of 25 mm were produced using compaction. The curing period was three days, and the specimens were cured under dry air, immersion, and heating conditions. The heating condition involved subjecting the immersed specimens to a microwave oven three times for three minutes to achieve an internal temperature of approximately 90℃. Regardless of the binder type, the cohesion of the cemented sand increased with higher binder content, whereas the internal friction angle exhibited a slight increase or decrease. Compared with ultra-rapid hardening cemented sand, epoxy-cemented sand displayed an average cohesion that was five times higher and an internal friction angle that was 10° higher. Overall, irrespective of binder type, the shear strength decreased during water immersion and increased during heating. Notably, the epoxy-cemented sand exhibited a three-fold increase in cohesion and a more than 20° increase in the internal friction angle during heating.

Tyrosinase-Immobilized Biosensor Based on Ionic Property-Modified MWNTs Prepared by Radiation-Induced Graft Polymerization

  • Ryu, Ha-Na;Choi, Seong-Ho
    • Carbon letters
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    • v.11 no.3
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    • pp.216-223
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    • 2010
  • Two-types of ionically modified multi-walled carbon nanotube (MWNTs) based sensors were developed by radiationinduced graft polymerization using vinyl monomers such as 3-(butyl imidazol)-2-(hydroxyl)propyl methyl methacrylate and 1-[(4-ethenylphenyl)methyl]-3-buthyl-imidazolium chloride with ionic properties, in aqueous solution at room temperature. Subsequently, the tyrosinase-immobilized biosensor was fabricated by a hand-casting of the ionic property-modified MWNTs, tyrosinase, and chitosan solution as a binder onto ITO glass surface. The sensing ranges of the tyrosinase-biosensor for phenol in phosphate buffer solution was in the range of 0.005~0.2 mM. The total phenolic compounds mainly such as caffeine of the tyrosinase-immobilized biosensor for commercial coffee were also determined.