고흡수성 중합물질의 자연발화에 대한 실험적 연구 (Experimental Study on Autoignition of Superabsorbent Polymers)
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- 한국재난정보학회 논문집
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- 제19권2호
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- pp.280-291
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- 2023
연구목적: 생활의 편의를 위한 고흡수성 중합물질의 생산 및 저장 사업장에서 발화사고가 발생하고 있어 이에 대한 실질적인 예방대책 수립을 위한 기초자료의 확보를 위해 실험적인 연구를 하였다. 연구방법: 시료용기(가로 20cm×세로 20cm) 폭을 각각 3cm, 5cm, 7cm, 14cm의 크기로 입방체 형상으로 하여 무한평판에 접근하도록 하였고, 300mesh의 스테인리스 망으로 전면과 뒷면을 일차원 방향으로 열이 전달되게 하였다. 이 시료용기를 온도제어장치 프로그램을 미리 설정하여 소정의 온도로 가열되도록 한항온조 중심에 위치시키고 중심온도가 설정온도보다 20℃이상 상승하였을 때를 「발화」로, 시료의 중심온도가 설정온도의 근사치에 유지되었을 경우를 「비발화」로 판정하였다. 연구결과: 자연발화한계온도는 시료용기 폭이 3cm일 경우 217.5℃, 5cm일 경우 212.5℃, 7cm일 경우 202.5℃, 그리고 14cm일 경우에는 187.5℃로 산출되었다. 최고온도에 도달하는 발화유도시간은 3cm일 경우 약 34시간, 5cm일 경우 약 76시간, 7cm일 경우 약 143시간, 그리고 14cm일 경우 약 318시간으로 나타났다. 결론: ① 용기의 크기가 증가할수록 자연발화온도는 낮아지고, 최고온도에 도달되는 발화유도시간은 길어지는 것으로 나타났다. ② 겉보기활성화에너지는 44.92 [kcal/mol]을 구하였으며, 상관도는 96.93%이었다.
고속 수중운동체 능동 탐지는 수중 무기 방어 시스템에 중요한 기술로, 정확한 표적 탐지와 거리 및 속도 추정이 필수적이다. 빔 형성 각도마다 신호를 순차적으로 송신해야 하지만 펄스 분할 송신 방법은 거리 추정의 모호성이 발생한다. 이를 보완하기 위해 다중 주파수 기반 방법이 제안되었지만 대역폭을 분할할 경우 시간-대역폭 곱에서 손실이 발생한다. 이러한 문제를 해결하기 위해, 본 연구에서는 대역폭을 분할하지 않아도 부펄스 간의 상관관계를 낮게 설계할 수 있는 일반화된 사인파 주파수 변조(Generalized Sinusoidal Frequency Modulation, GSFM)를 사용한 능동 고속 탐지 기법을 제안한다. 제안한 방법은 펄스 길이를 최소화시킨 GSFM을 사용함으로써 표적의 거리와 속도를 빠르게 갱신할 수 있다. 제안한 방법의 성능을 검증하기 위해 잔향이 존재하는 모의 환경을 구축하였다. 모의 실험 결과 0.05 s의 선형 주파수 변조 펄스는 한정적인 주파수 대역으로 인해 추정 거리 대비 평균적으로 50 %의 거리 추정 오차와 103 %의 속도 추정오차가 발생하였다. 이에 반해, GSFM은 같은 길이의 펄스를 사용하더라도 추정 거리 대비 거리 추정 오차와 속도 추정 오차가 각각 10 %와 14 %로 표적을 비교적 정확하고 빠르게 추적할 수 있었다. 게다가, GSFM은 방위별로 직교성이 높은 부펄스를 송신하여 표적의 대략적인 방위까지 알 수 있었다.
In Korea, Korea Proven Bulls (KPN) program has been well-developed. Breeding and evaluation of cows are also an essential factor to increase earnings and genetic gain. This study aimed to evaluate the accuracy of cow breeding value by using three methods (pedigree index [PI], pedigree-based best linear unbiased prediction [PBLUP], and genomic-BLUP [GBLUP]). The reference population (n = 16,971) was used to estimate breeding values for 481 females as a test population. The accuracy of GBLUP was 0.63, 0.66, 0.62 and 0.63 for carcass weight (CWT), eye muscle area (EMA), back-fat thickness (BFT), and marbling score (MS), respectively. As for the PBLUP method, accuracy of prediction was 0.43 for CWT, 0.45 for EMA, 0.43 for MS, and 0.44 for BFT. Accuracy of PI method was the lowest (0.28 to 0.29 for carcass traits). The increase by approximate 20% in accuracy of GBLUP method than other methods could be because genomic information may explain Mendelian sampling error that pedigree information cannot detect. Bias can cause reducing accuracy of estimated breeding value (EBV) for selected animals. Regression coefficient between true breeding value (TBV) and GBLUP EBV, PBLUP EBV, and PI EBV were 0.78, 0.625, and 0.35, respectively for CWT. This showed that genomic EBV (GEBV) is less biased than PBLUP and PI EBV in this study. In addition, number of effective chromosome segments (Me) statistic that indicates the independent loci is one of the important factors affecting the accuracy of BLUP. The correlation between Me and the accuracy of GBLUP is related to the genetic relationship between reference and test population. The correlations between Me and accuracy were -0.74 in CWT, -0.75 in EMA, -0.73 in MS, and -0.75 in BF, which were strongly negative. These results proved that the estimation of genetic ability using genomic data is the most effective, and the smaller the Me, the higher the accuracy of EBV.
2001년부터 2005년까지의 국가지정 석조문화재의 정기조사 이후에 많은 석조문화재가 보수 보존처리 되었지만 아직까지 훼손상태 및 등급에 따른 보존처리 기준이 모호하다. 따라서 이 연구에서는 국가지정 석조문화재의 훼손유형 및 등급에 따른 보수 보존처리의 원인을 통계분석하여 석조문화재의 훼손등급과 보존처리의 상관도를 분석하였다. 이 결과, 석조문화재의 모든 훼손유형에서 3등급이 가장 높게 나타났으며, 이를 등급별로 보면 4등급은 풍화상태가 143건, 5등급은 생물영향이 61건으로 가장 많았다. 2002년부터 2011년까지 실시된 보존처리는 총 211건으로 집계되었다. 보존처리 유형은 표면세정(134건, 26.1%), 수지접합, 강화처리 등이 가장 많이 실시되었다. 석조문화재에 대한 직적접인 처리 이외에도 석조문화재의 보존환경을 안정적으로 유지하기 위해 보호각 설치, 배수로 정비, 주변정비공사 등이 실시되었다. 보존처리율은 전반적으로 훼손등급이 높아질수록 증가하는 것으로 확인되었다. 구성암석에 따라서는 변성암 및 퇴적암이 화성암으로 구성된 석조문화재 보다 상대적으로 높은 것으로 나타났다. 건조시대에 따라서는 삼국시대 석조문화재의 보존처리율이 가장 높게 나타났으며 통일신라시대, 고려시대, 조선시대에 축조된 석조문화재의 보존처리율은 유사한 것으로 확인되었다. 국가지정 석조문화재의 최대훼손등급에 따른 보존처리율 살펴보면, 5등급에서 매우 높은 약 80%정도의 비율을 보이며 2012년에 보존처리된 석조문화재 수를 합하면 보존처리율은 더 높아진다. 이 결과는 향후 국내 석조문화재의 훼손상태에 대한 보존처리 여부를 결정하는데 있어 기초자료로 제공될 수 있을 것이다.
With the development of related technologies, Location-Based Services (LBS) are growing fast and being used in many ways. Past LBS studies have focused on adoption of LBS because of the fact that LBS users have privacy concerns regarding revealing their location information. Meanwhile, the number of LBS users and revenues from LBS are growing rapidly because users can get some benefits by revealing their location information. Little research has been done on how LBS affects consumers' information search behavior in product purchase. The purpose of this paper is examining the effect of LBS information filtering on buyers' uncertainty and their information search behavior. When consumers purchase a product, they try to reduce uncertainty by searching information. Generally, there are two types of uncertainties - knowledge uncertainty and choice uncertainty. Knowledge uncertainty refers to the lack of information on what kinds of alternatives are available in the market and/or their important attributes. Therefore, consumers having knowledge uncertainty will have difficulties in identifying what alternatives exist in the market to fulfil their needs. Choice uncertainty refers to the lack of information about consumers' own preferences and which alternative will fit in their needs. Therefore, consumers with choice uncertainty have difficulties selecting best product among available alternatives.. According to economics of information theory, consumers narrow the scope of information search when knowledge uncertainty is high. It is because consumers' information search cost is high when their knowledge uncertainty is high. If people do not know available alternatives and their attributes, it takes time and cognitive efforts for them to acquire information about available alternatives. Therefore, they will reduce search breadth. For people with high knowledge uncertainty, the information about products and their attributes is new and of high value for them. Therefore, they will conduct searches more in-depth because they have incentive to acquire more information. When people have high choice uncertainty, people tend to search information about more alternatives. It is because increased search breadth will improve their chances to find better alternative for them. On the other hand, since human's cognitive capacity is limited, the increased search breadth (more alternatives) will reduce the depth of information search for each alternative. Consumers with high choice uncertainty will spend less time and effort for each alternative because considering more alternatives will increase their utility. LBS provides users with the capability to screen alternatives based on the distance from them, which reduces information search costs. Therefore, it is expected that LBS will help users consider more alternatives even when they have high knowledge uncertainty. LBS provides distance information, which helps users choose alternatives appropriate for them. Therefore, users will perceive lower choice uncertainty when they use LBS. In order to test the hypotheses, we selected 80 students and assigned them to one of the two experiment groups. One group was asked to use LBS to search surrounding restaurants and the other group was asked to not use LBS to search nearby restaurants. The experimental tasks and measures items were validated in a pilot experiment. The final measurement items are shown in Appendix A. Each subject was asked to read one of the two scenarios - with or without LBS - and use a smartphone application to pick a restaurant. All behaviors on smartphone were recorded using a recording application. Search breadth was measured by the number of restaurants clicked by each subject. Search depths was measured by two metrics - the average number of sub-level pages each subject visited and the average time spent on each restaurant. The hypotheses were tested using SPSS and PLS. The results show that knowledge uncertainty reduces search breadth (H1a). However, there was no significant correlation between knowledge uncertainty and search depth (H1b). Choice uncertainty significantly reduces search depth (H2b), but no significant relationship was found between choice uncertainty and search breadth (H2a). LBS information filtering significantly reduces the buyers' choice uncertainty (H4) and reduces the negative relationship between knowledge uncertainty and search breadth (H3). This research provides some important implications for service providers. Service providers should use different strategies based on their service properties. For those service providers who are not well-known to consumers (high knowledge uncertainty) should encourage their customers to use LBS. This is because LBS would increase buyers' consideration sets when the knowledge uncertainty is high. Therefore, less known services have chances to be included in consumers' consideration sets with LBS. On the other hand, LBS information filtering decrease choice uncertainty and the near service providers are more likely to be selected than without LBS. Hence, service providers should analyze geographically approximate competitors' strength and try to reduce the gap so that they can have chances to be included in the consideration set.
본(本) 연구는 구획경계선(區劃境界線)이 토괴(土壞)의 화학성(化學性)의 공간변이(空間變異)에 미치는 영향을 알기 위하여 10년전 구획정리로 논을 회전환(回轉換)한 맥류연구소 시험원지(試驗園地)중 화동(華東) 미사질 식양토(Fine clayey, mixed, mesic family of Aquic Hapludalfs)를 공시토양으로 하여 필지경계선(筆地境界線)을 횡단(橫斷)하여 토양화학성건(土壤化學性健)을 조사하고 각 측정자료를 고전통계적방법(古典統計的方法)과 지질통계적(地質統計的) 방법(方法)으로 각 측정치의 변이성과 공간변이성(空間變異性)을 해석하였다. 토양화학성은
The wall shear stress in the vicinity of end-to end anastomoses under steady flow conditions was measured using a flush-mounted hot-film anemometer(FMHFA) probe. The experimental measurements were in good agreement with numerical results except in flow with low Reynolds numbers. The wall shear stress increased proximal to the anastomosis in flow from the Penrose tubing (simulating an artery) to the PTFE: graft. In flow from the PTFE graft to the Penrose tubing, low wall shear stress was observed distal to the anastomosis. Abnormal distributions of wall shear stress in the vicinity of the anastomosis, resulting from the compliance mismatch between the graft and the host artery, might be an important factor of ANFH formation and the graft failure. The present study suggests a correlation between regions of the low wall shear stress and the development of anastomotic neointimal fibrous hyperplasia(ANPH) in end-to-end anastomoses. 30523 T00401030523 ^x Air pressure decay(APD) rate and ultrafiltration rate(UFR) tests were performed on new and saline rinsed dialyzers as well as those roused in patients several times. C-DAK 4000 (Cordis Dow) and CF IS-11 (Baxter Travenol) reused dialyzers obtained from the dialysis clinic were used in the present study. The new dialyzers exhibited a relatively flat APD, whereas saline rinsed and reused dialyzers showed considerable amount of decay. C-DAH dialyzers had a larger APD(11.70
The wall shear stress in the vicinity of end-to end anastomoses under steady flow conditions was measured using a flush-mounted hot-film anemometer(FMHFA) probe. The experimental measurements were in good agreement with numerical results except in flow with low Reynolds numbers. The wall shear stress increased proximal to the anastomosis in flow from the Penrose tubing (simulating an artery) to the PTFE: graft. In flow from the PTFE graft to the Penrose tubing, low wall shear stress was observed distal to the anastomosis. Abnormal distributions of wall shear stress in the vicinity of the anastomosis, resulting from the compliance mismatch between the graft and the host artery, might be an important factor of ANFH formation and the graft failure. The present study suggests a correlation between regions of the low wall shear stress and the development of anastomotic neointimal fibrous hyperplasia(ANPH) in end-to-end anastomoses. 30523 T00401030523 ^x Air pressure decay(APD) rate and ultrafiltration rate(UFR) tests were performed on new and saline rinsed dialyzers as well as those roused in patients several times. C-DAK 4000 (Cordis Dow) and CF IS-11 (Baxter Travenol) reused dialyzers obtained from the dialysis clinic were used in the present study. The new dialyzers exhibited a relatively flat APD, whereas saline rinsed and reused dialyzers showed considerable amount of decay. C-DAH dialyzers had a larger APD(11.70