• Journal of the Mineralogical Society of Korea
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• v.23 no.3
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• pp.267-272
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• 2010

High pressure x-ray diffraction patterns of ${\alpha}$-cristobalite gallium phosphate ($GaPO_4$) were acquired up to 8.9 GPa at room temperature using Mao-Bell type diamond anvil cell with high flux synchrotron radiation. Starting orthorhombic phase (phase-I) shows the splitting of peak which is possibly resulted from the pressure induced orientation disorder of the framework structure of tetrahedra. This is designated as phase-I'. This phase transforms to the orthorhombic high pressure phase-III between 2 and 3 GPa. Present phase transition sequence is not in accord with the recent high pressure X-ray diffraction results performed on the same starting sample (Ming et al., 2007). X-ray pattern of the unloaded sample to ambient pressure shows that the structure retains that of the high pressure phase prior to decompression.

• Transactions of the Korean Society of Mechanical Engineers
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• v.11 no.3
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• pp.454-464
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• 1987

The objective of this research is to analyze and evaluate the dynamic flow curve of metals under impact loading at both high strain rate (.epsilon.=1/h dh/dt > 10$\^$3/m/s/m) and large strain (.epsilon.=In h/h$\_$0/ > 1.0). A test method for dynamic compression of metal disc is described. The velocity of the striker face and the force on the anvil are measured during the impact period. From these primitive data the axial stress, strain, and strain rate of the disc are obtained. The Strain rate is determined by the striker velocity divided by the specimen height. This gives a slightly increasing strain rate over most of the deformation period. Strain rates of 100 to 10,000 per second are achieved. Attainable final strains are 150%. A discussion of several problem areas is presented. The friction on the specimen surfaces, the determination of the frictional coefficient, the influence of the specimen geometry (h$\_$0//d$\_$0/ ratio) on the friction effect, the lock-up condition for a given configuration, the friction correction factor, and the evaluation of several lubricants are given. The flow function(stress verus strain) is dependent on the material condition(e.g., prior cold work), specimen geometry, strain rate, and temperature.

• Geotechnical Engineering
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• v.13 no.1
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• pp.169-182
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• 1997

It is known that some amount of loss in impact energy takes place due to some limitations and problems during the performance of the field SPT. Actual energy level tractsferred to the rod should be measured to correct the SPT-N values tested in the field In this paper, the ratio of energy transferred to the rod through the anvil to impact energy is measured by using sharpy impact test equipment and also analysed by using GRL-WEAP This result is certified and compared with that of field SPT As the results of this study, the average rod energy ratio of the R-P hammer and the Trip hammer is calculated at 0.726 and 0.728 respectively, but it is suggested that 0.72 should be used. By using the hammer energy ratio 64.2% and 75.0% obtained from field measurement, the average energy ratio of the SPT for the R-P hammer is calculated at 46.7% and 54.5% for the Trip hammer.

• Economic and Environmental Geology
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• v.49 no.1
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• pp.23-30
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• 2016

Powder samples of natural lawsonite (Ca-lawsonite, $CaAl_2Si_2O_7(OH)_2{\cdot}H_2O$) was studied structurally up to 8 GPa at room temperature using monochromatic synchrotron X-ray powder diffraction and a diamond anvil cell (DAC) with a methanol : ethanol : water (16 : 3 : 1 by volume) mixture solution as a penetrating pressure transmitting medium (PTM). Upon pressure increase, lawsonite does not show any apparent pressure induced expansion (PIE) or phase transition. Pressure-volume data were fitted to a second-order Birch-Murnaghan equation of state using a fixed pressure derivative of 4 leading to a bulk modulus ($B_0$) of 146(6) GPa. This compression is further characterized to be isotropic with calculated linear compressibilities of ${\beta}^a=0.0022GPa^{-1}$, ${\beta}^b=0.0024GPa^{-1}$, and ${\beta}^c=0.0020GPa^{-1}$.

• Journal of the Mineralogical Society of Korea
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• v.31 no.4
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• pp.277-285
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• 2018

Azurite ($Cu_3(CO_3)_2(OH)_2$) was compressed up to 21.52 GPa for its behaviors at ambient temperature. High pressure experiment was performed using the symmetrical diamond anvil cell employed in the angle dispersive X-ray diffraction method. Pressure was determined by ruby fluorescence calibration method. No phase transitions were observed within the present pressure limit and bulk modulus was determined to be 54.4 GPa when ${K_0}^{\prime}$ is fixed to be 4. Applying the normalized pressure-strain analysis, reliability of the azurite compression pattern was checked.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.19 no.4
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• pp.459-467
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• 2021

In the majority of countries, the upper limit of buffer temperature in a repository is set to below 100℃ due to the possible illitization. This smectite-to-illite transformation is expected to be detrimental to the swelling functions of the buffer. However, if the upper limit is increased while preventing illitization, the disposal density and cost-effectiveness for the repository will dramatically increase. Thus, understanding the characteristics and creating a database related to the buffer under the elevated temperature conditions is crucial. In this study, a strategy to investigate the bentonite found in Korea under the elevated temperatures from a mineral transformation and radionuclides retardation perspective was proposed. Certain long-term hydrothermal reactions generated the bentonite samples that were utilized for the investigation of their mineral transformation and radionuclide retardation characteristics. The bentonite samples are expected to be studied using in-situ synchrotron-based X-Ray Diffraction (XRD) technique to determine the smectite-to-illite transformation. Simultaneously, the 'high-temperature and high-pressure mineral alteration measurement system' based on the Diamond Anvil Cell (DAC) will control and provide the elevated temperature and pressure conditions during the measurements. The kinetic models, including the Huang and Cuadros model, are expected to predict the time and manner in which the illitization will become detrimental to the performance and safety of the repository. The sorption reactions planned for the bentonite samples to evaluate the effects on retardation will provide the information required to expand the current knowledge of repository optimization.

• Journal of the Mineralogical Society of Korea
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• v.18 no.4 s.46
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• pp.249-257
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• 2005

Garnet is one of the major minerals down to the top of lower mantle approximately 660 km with spinel and pyroxenes. Garnet transforms into perovskite and corundum in the lower mantle, however its sequence is still in controversy. We measured the compressibility of a natural almandine at high-pressure up to 62 CPa using Mao-Bell type diamond anvil cell (DAC) at room temperature. Chemical formula of the specimen is ($Fe_{2.52}Ca_{0.21}Mg_{0.18}Mn_{0.12})Al_{2.23}Si_{2.97}O_{12}$. Results of this compression study are as follows: a : $10.175\;{\AA}$, V : $1251.16\;{\AA}^{3}$, $D_{x}$ : $5.265\;g/cm^{3}$ at 62 GPa; bulk modulus is 156 GPa using Birch-Murnaghan equation of state (EoS) with a fixed $K_{0}\;'$ of 4. This study would be the first time attempt accomplished with the high pressure DAC using synchrotron radiation at the Pohang Light Source (PLS) in Korea.

• Journal of the Mineralogical Society of Korea
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• v.5 no.2
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• pp.72-78
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• 1992

The Earth outer core accomodates moderately considerable amount of lighter elements than pure iron itself. Hydrogen is one of the possible candidates of minor constituents in the outer core. It would be worth while to extend for the pressure effect on the solubility of hydrogen in the metal-hydrides including iron hydride. In view of hydrogen being one of the potential substitutes for petroleum, searching a more efficient way for storing hydrogen in the form of hydrides is of considerable value. For two purposes, $TiH_2$was selected among lot of hydrides for its characteristics under pressure and temperature. There have been two kinds of experiment carried out on $TiH_2$ under different experimental conditions. As one of these attempts, polycrystalline $TiH_2$ was loaded up to 15 GPa stepwise at the constant temperature 500${\circ}$ using a piston-cylinder diamond anvil cell equipped with a miniature furnace of an electric power supply. The X-ra diffraction technique was employed on the quenched samples after the simultaneous high pressure and temperature treatments. During these high pressure-temperature runs, and irreversible phase of $TiH_2$ has been observed at the pressures higher than 11.3 GPa, which would be assigned to the orthorhombic crystal system as one of the new phase(s) of $TiH_2$. Molar volume change on this phase transition is ∼10%.

• Journal of the Korean earth science society
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• v.31 no.7
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• pp.749-761
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• 2010

A relationship between cloud-to-ground lightning and rainfall was investigated by using the two-years (2006-2007) summer lightning data and the automatic weather stations (AWSs) data of the Korea Meteorological Administration. The negative lightning occurred at the core of highly concentrated convection, which is often accompanied with heavy rains. Whereas most positive lightning occurred at the anvil cloud with low density and light rains. The rainfall intensity is strongest when the negative and positive lightning occurred concurrently, and one with lightning is much stronger than that without lightning. A portion of the positive lightning of the total lightning was less than 10% during summer seasons, and the lightning without rains was about 34%. The rain rate was strongly correlated with the negative flash rate, and the correlation coefficients varied between 0.87 and 0.94 according to the co-location radius (5-15 km) of AWSs. Most of the lightning occurred 10 minutes before and/or concurrently occurred with rains. A portion of the convective rainfalls of the total rainfalls was at least 20% when we define the rainfalls with lightning as convective. The convective rainfall was greater during August than in June and July. In general, the portion of convective rainfalls showed a maximum diurnal variation during late afternoon as in the rains and lightning.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.1
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• pp.11-18
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• 2020

High-pressure synchrotron X-ray powder diffraction experiments were performed on natural illite (K_0.65Al₂(Al_0.65Si_3.35)O₁₀(OH)₂) using diamond anvil cell (DAC) under two different pressure transmitting media (PTM), i.e., water and ME41 (methanol:ethanol = 4:1 by volume). When using water as PTM, occasional heating was applied up to about 250℃ while reaching pressure up to 2.7 GPa in order to promote both hydrostatic conditions and intercalation of water molecules into the layer. When using ME41, pressure was reached up to 6.9 GPa at room temperature. Under these conditions, illite did not show any expansion of interlayer distance or phase transitions. Pressure-volume data were used to derive bulk moduli (K₀) of 45(3) GPa under water and 51(3) GPa under ME41 PTM. indicating no difference in compressibility within the analytical error. Linear compressibilities were then calculated to be β^a = 0.0025, β^b = 0.0029, β^c = 0.0144 under ME41 PTM showing the c-axis is ca. six times more compressible than a- and b-axes. These elastic behaviors of illite were compared to muscovite, one of its structural analogues.