Journal of the Mineralogical Society of Korea (한국광물학회지)

The Mineralogical Society of Korea (한국광물학회)
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High Pressure Behavior Study of Azurite

고압 하에서 남동석의 거동에 대한 연구

  • Kim, Young-Ho (Department of Geology and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Choi, Jinwon (Department of Geology and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Choi, Jaeyoung (Department of Geology and Research Institute of Natural Sciences, Gyeongsang National University)
  • 김영호 (경상대학교 지질과학과 및 기초과학연구소) ;
  • 최진원 (경상대학교 지질과학과 및 기초과학연구소) ;
  • 최재영 (경상대학교 지질과학과 및 기초과학연구소)
  • Received : 2018.11.20
  • Accepted : 2018.12.18
  • Published : 2018.12.31
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Abstract

Azurite ($Cu_3(CO_3)_2(OH)_2$) was compressed up to 21.52 GPa for its behaviors at ambient temperature. High pressure experiment was performed using the symmetrical diamond anvil cell employed in the angle dispersive X-ray diffraction method. Pressure was determined by ruby fluorescence calibration method. No phase transitions were observed within the present pressure limit and bulk modulus was determined to be 54.4 GPa when ${K_0}^{\prime}$ is fixed to be 4. Applying the normalized pressure-strain analysis, reliability of the azurite compression pattern was checked.

상온에서 남동석($Cu_3(CO_3)_2(OH)_2$)에 대한 고압 거동 연구를 하였다. 대칭형 다이아몬드 앤빌기기를 이용하여 21.52 GPa까지 압력을 증가시키면서 각분산 X-선 회절법과 방사광을 이용하여 고압회절 데이터를 얻었으며, 시료에 가해준 압력은 루비 형광파의 파장 변화를 측정하여 결정하였다. 본 실험에서 시행한 압력의 범위 내에서 상변이는 관찰되지 않았으며, 정압상태에서 체적탄성률($K_0$)은 ${K_0}^{\prime}$이 4일 때, 54.4 GPa로 계산되었다. 상온상태에서 얻은 남동석의 체적탄성률에 대한 신뢰도를 정규화압력 및 정규화응력변형 분석을 통해 검증하였다.

Keywords

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