• Title/Summary/Keyword: Antimony

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Dehydrogenation of Ethylbenzene with Carbon Dioxide as Soft Oxidant over Supported Vanadium-Antimony Oxide Catalyst

  • Hong, Do-Young;Vislovskiy, Vladislav P.;Park, Sang-Eon;Park, Min-Seok;Yoo, Jin-S.;Chang, Jong-San
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1743-1748
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    • 2005
  • This work presents that carbon dioxide, which is a main contributor to the global warming effect, could be utilized as a selective oxidant in the oxidative dehydrogenation of ethylbenzene. The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen or carbon dioxide as diluent or oxidant. Among them, the addition of carbon dioxide gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable activity. Carbon dioxide could play a beneficial role of a selective oxidant in the improvement of the catalytic behavior through the oxidative pathway.

The Study on Surface of Devices Using Fractal. (프랙탈을 이용한 소자 표면의 고찰)

  • Hong, Kyung-Jin;Kim, Chang-Won;Cho, Jae-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.47-51
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    • 2001
  • The structural properties of varistors surface studied by fractal phenomenon were investigated to verify the relations of electrical characteristics. The SEM photograph of varistors surface were changed by binary code and the grain shape of that were analyzed by fractal dimension. The void of varistors surface was found by fractal program. The relation between grain density and electrical properties depend on fractal dimension. The grain size in varistors surface was decreased by increasing of oxide antimony addition. The grain size of devices by oxide antimony addition were from 5 to $10[{\mu}m]$. The fractal dimension and electrical properties of varistors surface was related to between grain boundary and grain density. The grain size was decreased by increasing of fractal dimensions.

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The Electrical Characteristics of Varistor. (바리스터의 전기적 특성)

  • Hong, Kyung-Jin;Jang, Dong-Hwan;Cho, Jae-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.52-56
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    • 2001
  • The Breakdown electric field of ZnO semiconductor devices in voltage-current characteristics was increased by increasing of additive materials. The specimen that has not additive materials was not formed spinel structure. The critical voltage that has not spinel structure was 235[V]. When the additive materials has 0.5 and 2[mol%], the Breakdown electric field was 840 and 758[V] in each additive materials. The Breakdown electric field of varistors as a factor of voltage and current was increased by addition of oxide antimony. The varistors that has oxide antimony was linearly increased in low electric field.

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Effect of Treatments with Flame-retardant on Flame-resistance and Tensile Strength of Paper (난연 처리가 종이의 난연성 및 인장강도에 미치는 영향)

  • Song, Han-Kyu;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.61-67
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    • 2006
  • The effect of several inorganic flame-retardants such as ammonium phosphate, ammonium sulfate, aluminum hydroxide and antimony trioxide on the flame-retardant property and tensile strength of paper has been investigated. Flame-retardants were used preferably as a dry powdered mixture and added to the furnish. Both dipping and coating treatments were employed to apply flame-retardants to paper Flame-retardant paper was manufactured by treatment of $5{\sim}30%$ flame-retardants by weight of the paper on a dry weight. Paper's flame-retardant property and tensile strength were examined by comparison of char length and tensile index. As dosages of flame-retardant chemicals increased, flame-retardant property was improved but tensile index was decreased.

Application of Novel BSF Metal and Laser Annealing to Silicon Heterojunction Solar Cell

  • Bong, Seong-Jae;Kim, Seon-Bo;An, Si-Hyeon;Park, Hyeong-Sik;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.491.2-491.2
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    • 2014
  • Generally, silicon heterojunction solar cell has intrinsic and n-type of hydrogenated amorphous silicon (a-Si:H) as passivation layer and BSF layer. In this study, antimony, novel material, deposited on back side of the heterojunction solar cell as passivation and BSF layer to substitute the a-Si:H and the characteristics of the solar cell such electrical properties and optical properties were analyzed. And SIMS analysis was carried out to obtain the depth profile of the BSF layer which was deposited by laser annealing process.

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Behavior of Pt, Sb, Te during Crystallizaion of Ore Magma (I) (광화마그마내에서의 백금, 안티모니, 테루리움 거동에 관한 연구(I))

  • 김원사
    • Journal of the Mineralogical Society of Korea
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    • v.9 no.2
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    • pp.93-101
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    • 1996
  • Behavior of platinum group elements during crystallization within ore magma is of interest. In this study platinum is selected and its mineralogical and geochemical behavior in the presence of antimony and tellurium is investigated at 600$^{\circ}C$. High purity Pt, Sb, and Te are used as starting material and silica quartz tubings are as container. Rection products have been examined by use of ore microscope, X-ray diffractometer, electron microprobe analyser and micro-indentation hardness tester. stable phases at 600$^{\circ}C$ are platinum (Pt), Pt5Sb, Pt3Sb, PtSb, stumpflite (PtSb), geversite (PtSb), PtTe, Pt3Te4, Pt2Te3, moncheite (PtTe2), tellurantimony (Sb2Te3), and antimony (Sb). Geversite is the mineral showing the most significant extent of solid solution by up to 27 at% between Sb and Te elements. Isothermal section of 600$^{\circ}C$ is established in this study. It is noted that platinum cannot coexists with stumpflite or geversite under equilibrium condition, and stumpflite composition in equilibrium with geversite may be used as geothermometer.

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Leakage Prevention of Mechanical Seal in a Feed Water Pumpof Power Plant with Oxygen Water Treatment (산소주입 수처리 발전소용 급수펌프 밀봉장치의 누설방지)

  • Shin, Jung-Gook;Moon, Seung-Jae;Yoo, Hoseon
    • Plant Journal
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    • v.7 no.1
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    • pp.56-63
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    • 2011
  • The identifying cause of leakage problems on mechanical seal in a feed water pump of power plant have been difficult because of technical limits of domestic mechanical seal manufacturer and the various conditions of power plants. This paper can get a conclusion through the consideration study and experiment test of mechanical seal characteristics of feed water pump depending on oxygen treatment as follows. The oxygen treatment increase dissolved oxygen and cause a corrosion on the mechanical seal stationary ring composed of antimony as well as leakage problems. For solving leakage problems of seal, to eliminate dissolved oxygen in the cooling water of seal with hydrazine injection can prevent leakage problems of mechanical seal in feed water pump.

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Study on Properties of Antimony-doped Tin Oxide Thin Films Prepared by Sputtering (Sputtering 방법에 의해 제조된 Sb가 도핑된 주석산화물 박막의 특성에 관한 연구)

  • 김층완;김광호;이환수;이혜용
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.735-742
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    • 1996
  • Antimony-doped Tin oxide (ATO) thin films were deposited on soda-lime glass substrates by DC magnetron sputtering technique. Effects of DC power film thickness and post heat-treatment on electrical conductivity of ATO film were investigated. Other properties of ATO film such as optical anti-chemical and wear properties were also reported in this work. The obtained ATO films showed electrical resistivities ranging from 5$\times$10-3 $\Omega$cm to 3$\times$10-3 $\Omega$cm with the average optical transparency above 80% in visible wavelength range and excel-lent anti-chemical properties where the electrical resistivity was not changed even after soaking the films in 1M HCl or 1M NaOH solution for 10 days. These properties were found to be related to the crystallinity of ATO film and the films having higher crystallinity showed better properties.

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ELECTROSPINNING OF ANTIMONY DOPED TIN OXIDE NANOPARTICLE DISPERSION FOR TRANSPARENT AND CONDUCTIVE FILMS

  • YOUNG-SANG CHO;MINHO HAN;SEUNG HEE WOO
    • Archives of Metallurgy and Materials
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    • v.65 no.4
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    • pp.1345-1350
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    • 2020
  • Stable dispersion of antimony-doped tin oxide nano-powder was prepared by wet attrition process by comminuting aggregated ATO nano-powder using the titanate coupling agent as a dispersant to form the chemisorbed layer on the particle surface. The feed solution of the ATO dispersion and PVP was prepared for electro-spun fibers on the glass substrate. The surface resistance of the fibrous ATO film after electrospinning for 30 minutes was in the order of 105 Ω/□, which is sufficient for anti-static coating. The optical transmittance of ATO fibers was confirmed by measuring the visible light transmittance.