• Title/Summary/Keyword: Antimony

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A Study on Hazardous Heavy Metal Contents of Lip Cosmetics (립메이크업 제품의 유해 중금속 함량 조사연구)

  • Choi, Chae Man;Kim, Su Un;Park, Ae Suk;Kim, Ji-Young;Kim, Yun Hee;Lee, Myung Sook;Kim, Uk Hee;Hwang, In Sook
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.2
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    • pp.147-155
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    • 2022
  • From March to August 2021, a total of 66 lip makeup products were collected from Seoul to measure the contents of lead, arsenic, cadmium, antimony, and nickel, and compared by product type (lip gloss, lip balm and lip tint), production area (domestic and imported), and user (for adults and children). The average metal contents were as follows; 0.284 ㎍/g for lead, 0.020 ㎍/g for arsenic, 0.003 ㎍/g for cadmium, 0.004 ㎍/g for antimony and 0.415 ㎍/g for nickel. The results of lip cosmetics were below the recommended maximums in regulations on safety standards for cosmetics of Ministry of Food and Drug Safety.

Monitoring of Quality Characteristics and Harmful Substances in Commercial Handmade Soap (유통 수제비누의 품질특성 및 유해물질 모니터링)

  • Yeon Ji Kim;In Sook Lee;Su Ae Kim;Koth Bong Woo Ri Kim;Ho Cheol Yun;Pyeung Tae Gu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.3
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    • pp.213-223
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    • 2023
  • A total of 81 handmade soaps on sale on the market were collected from January to November 2022. To compare quality characteristics, all ingredients were referred to, and the pH, dry reduction, heavy metals (lead, arsenic, cadmium, antimony, and mercury), and contents of free alkali were measured. All soaps had a slightly alkaline pH of 7.9 to 11.2, average drying loss was 17.6%, and free alkali was hardly detected. The average values of all heavy metals were 0.104 ㎍/g for lead, 0.035 ㎍/g for arsenic, 0.002 ㎍/g for cadmium, 0.048 ㎍/g for antimony, and 0.0003 ㎍/g for mercury. The results of handmade soap were below the recommended in regulations on safety standards for cosmetics of Ministry of Food and Drug Safety.

A Simple and Quick Chemical Synthesis of Nanostructured Bi2Te3, Sb2Te3, and BixSb2-xTe3

  • Kim, Hee-Jin;Lee, Ki-Jung;Kim, Sung-Jin;Han, Mi-Kyung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1123-1127
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    • 2010
  • We report a simple and quick route for the preparation of high-quality, nearly monodisperse $Bi_2Te_3$, $Sb_2Te_3$, and $Bi_xSb_{2-x}-Te_3$ nanocrystallites. The reactions of bismuth acetate or antimony acetate with Te in oleic acid result in pure phase of $Bi_2Te_3$ or $Sb_2Te_3$ nanoparticles, respectively. Also, ternary $Bi_xSb_{2-x}Te_3$ nanoparticles were successfully synthesized using the same method. The size and morphology of the nanoparticles were controlled by varying the stabilizing agents. The as-prepared nanoparticles are characterized by X-ray diffraction, scanning electron microscope, and high-resolution transmission electron microscope using an energy dispersive spectroscopy.

M-Zn (M = Sb, V, and Nb) Substituted Strontium Hexaferrites with Enhanced Saturation Magnetization for Permanent Magnet Applications

  • Sapoletova, Nina;Kushnir, Sergey;Ahn, Kyunghan;An, Sung Yong;Choi, Moonhee;Kim, Jae Yeong;Choi, Changhak;Wi, Sungkwon
    • Journal of Magnetics
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    • v.21 no.3
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    • pp.315-321
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    • 2016
  • M-Zn (M = Sb, V, Nb) substituted M-type strontium hexaferrites were prepared by a ceramic method. The phase composition, morphology and magnetic properties were studied by x-ray diffractometry, scanning electron microscopy and vibrating sample magnetometry. Saturation magnetization increases with a substitution up to 75.0 emu/g (2.5 % higher compared to unsubstituted hexaferrite) and then decreases with a further substitution. A coercive field of substituted hexaferrite powders with highest saturation magnetization is more than 3 kOe. Substituted strontium hexaferrite powders prepared in this work are a rare example of high $M_S$ compositions without doping rare-earth elements and would be a promising candidate for a permanent magnet application.

Tribological properties of the brake friction materials without environmentally regulated ingredients (친환경 규제 원료를 제거한 마찰재의 마찰 특성에 관한 연구)

  • Lim, Se-Eun;Lee, Wan-Gyu;Shin, Min-Wook;Jang, Ho
    • Tribology and Lubricants
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    • v.26 no.4
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    • pp.246-253
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    • 2010
  • Friction characteristics of the brake friction materials without environmentally regulated ingredients were examined to find their role in the brake performance. Five friction materials were produced based on a nearcommercial formulation by changing the relative amount of potentially hazardous ingredients to health and environment, such as $Sb_2S_3$, potassium titanate, and brass fiber. Tribological properties of the friction materials were obtained using a scale dynamometer and Krauss type tribometer. Results showed that the excluded three ingredients played important synergetic effects on tribological properties in terms of fade resistance, wear resistance and friction effectiveness. In particular, brass fibers played important roles in the friction stability by providing excellent thermal diffusivity at the friction interface. Potassium titanate whiskers showed excellent fade resistance and wear resistance compared to the substituted barite. Antimony trisulfide, on the other hand, showed little effect on the high temperature fade resistance and wear resistance, while it increased friction effectiveness at moderate temperatures. The friction materials without the three ingredients showed severe fade, indicating antisynergy effects.

A Novel KOH Wet Etching Technique for Ultrafine Nanostructure Formation (초정밀 나노구조물 형성을 위한 새로운 KOH 습식각 기술)

  • Kang, Chan-Min;Park, Jung-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.2
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    • pp.156-161
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    • 2011
  • The present study introduces a novel wet etching technique for nanostructure fabrications which usually requires low surface roughness. Using the current method, acquired profiles were smooth even in the nanoscale, which cannot be easily achieved with conventional wet or dry etching methods. As one of the most popular single crystal silicon etchant, potassium hydroxide (KOH) solution was used as a base solvent and two additives, antimony trioxide (Sb2O3) and ethyl alcohol were employed in. Four experimental parameters, concentrations of KOH, Sb2O3, and ethyl alcohol and temperature were optimized at 60 wt.%, 0.003 wt.%, 10 v/v%, and $23^{\circ}C$, respectively. Effects of additives in KOH solution were investigated on the profiles in both (110) and (111) planes of single crystal silicon wafer. The preliminary results show that additives play a critical role to decrease etch rate significantly down to ~2 nm/min resulting in smooth side wall profiles on (111) plane and enhanced surface roughness.

Characteristics of SCR-Catalytic with de-NOx System in Thermal Power plants (화력발전소 NOx 제거를 위한 SCR 촉매 특성)

  • Ko, Seung-Jae;Kim, Ji-Hyun;Kim, Mi-Joung;Cho, Yeon-Bae;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.3
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    • pp.451-460
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    • 2013
  • NOx from the thermal power plants are NO and $NO_2$. This work investigated the chemical/physical characteristics and SCR efficiency of newly prepared catalysts including tungsten ($WO_3$), molybdenum ($MoO_3$) and antimony ($SbO_3$) based on vanadia($V_2O_5$) over titania($TiO_2$). As a result of the examination, the surface area of the catalysts promoted with additional metals was larger and the de-NOx efficiency also was enhanced with temperature. The most efficient catalytst was $V_2O_5/TiO_2-WO_3$(10%) at $200^{\circ}C$. Such a high efficiency could contribute to reduce the ammonia slip.

Influence of Bismuth and Antimony Additions on the Structures and Casting Properties of Lead-free Cu-Zn-Sn Bronze Castings (무연 Cu-Zn-Sn 청동의 조직과 주조성에 미치는 Bi 및 Sb 첨가의 영향)

  • Park, Heung-Il;Park, Sung-Ik;Kim, Sung-Gyu
    • Journal of Korea Foundry Society
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    • v.32 no.2
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    • pp.91-97
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    • 2012
  • The effects of Bi and Sb additions on the microstructures and casting properties in lead-free Cu-Zn-Sn broze were investigated. (1) When only Bi was added to the bronze, Bi was precipitated on the ${\delta}$ phase of ${\alpha}$ dendrite cell boundary. When Bi and Sb were added together, Bi was precipitated on the ${\delta}_A$ which was the Sb-rich area in the ${\delta}$ phase. (2) The addition of Sb accelerated the formation of ${\delta}$ phase, and when Sb, Bi and Pb were added, Bi and Pb were precipitated as mixed solution in the ${\delta}_A$ phase. (3) The combined addition of Sb and Bi resulted in the suppression of shrinkage due to the complementary effects of the mass feeding of ${\alpha}$-dendrite cluster covered with ${\delta}$ phase and sealing of micro-shrinkage in the ${\delta}$ phase by solidification expansion of Bi.

Plasmid-Mediated Arsenical and Antimonial Resistance Determinants (ars) of Pseudomonas sp. KM20

  • Yoon, Kyung-Pyo
    • Journal of Microbiology and Biotechnology
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    • v.12 no.1
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    • pp.31-38
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    • 2002
  • Bacteria have evolved various types of resistance mechanism to toxic heavy metals, such as arsenic and antimony. An arsenical and antimonial resistant bacterium was isolated from a shallow creek draining a coal-mining area near Taebaek City, in Kangwon-Do, Korea. The isolated bacterium was identified and named as Pseudomonas sp. KM20 after biochemical and physiological studies were conducted. A plasmid was identified and its function was studied. Original cells harboring the plasmid were able to grow in the presence of 15 mM sodium arsenite, while the plasmid-cured (plasmidless) strain was sensitive to as little as 0.5 mM sodium arsenate. These results indicated that the plasmid of Pseudomonas sp. KM20 does indeed encode the arsenic resistance determinant. In growth experiments, prior exposure to 0.1 mM arsenate allowed immediate growth when they were challenged with 5 mM arsenate, 5 mM arsenite, or 0.1 mM antimonite. These results suggested that the arsenate, arsenite, and antimonite resistance determinants of Pseudomonas sp. KM20 plasmid were indeed inducible. When induced, plasmid-bearing resistance cells showed a decreased accumulation $of\;73^As$ and showed an enhanced efflux $of\;^73As$. These results suggested that plasmid encoded a transport system that extruded the toxic metalloids, resulting in the lowering of the intracellular concentration of toxic oxyanion. In a Southern blot study, hybridization with an E. coli R773 arsA-specific probe strongly suggested the absence of an arsA cistron in the plasmid-associated arsenical and antimonial resistance determinant of Pseudomonas sp. KM20.

The Applications of Sol-Gel Derived Tin Oxide Thin Films

  • Park, Sung-Soon;John D. Mackenzie
    • The Korean Journal of Ceramics
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    • v.2 no.1
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    • pp.1-10
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    • 1996
  • Transparent conducting $SnO_2$-based thin films have been coated on float substrates such as fused quartz, and ceramic fiber cloths such as the Nexel and E-glass cloth from tin alkoxides by the sol-gel technique. Also, thin films of alternating layers of $SnO_2$ and $SiO_2$ have been fabricated by dip coating. The sheet resistance and average visible transmittance of the films were investigated in the aspect of the applications as transparent electrodes such as liquid crystal displays, photo-detectors and solar cells. The Nextel and E-glass cloths coated with antimony-doped tin oxide (ATO) had sheet resistance of as low as $20 \;ohm/{\Box}$ and $120ohm/\;{\Box}$, respectively. The promotion effects of additives as $La_2O_3$ and Pt on the ethanol gas sensing properties of the films were investigated in the aspects of the applications as an alcohol sensor and a breath alcohol checker. Possible evidence of quantum well effects in the oxide multilayers of $SnO_2$ and $SiO_2$ was investigated.

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