• Title/Summary/Keyword: Anti-Corrosive

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Quinone-Diamine Adduct as a High Performance Resin for Coatings (퀴논-디아민 부가물계 고성능 도료용 수지)

  • Lee, Chi-Giu
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.1
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    • pp.1-10
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    • 1996
  • We have prepared diamine-benzoquinone polymer which was known to excellent water proofing, high adhesion strength and good anti-corrosive effect, and have investigate with the possibility of application as a high performance resin for coatings. First of all, the reactivity of diamine-benzoquinone has been described an example of polymer reaction with research trend. The polymer reaction was divided into the polymerization with several diamine-benzoquinone and urethane group. The synthetic resin was shown a high solubility. In case of polymer containing urethane, water absorption content, water proofing and mechanical properties were controlled with the content, water proofing and mechanical properties were controlled with the content of quinone. It was shown that an use of choice was a possible result for various coatings. Diamine-quinone polymer can be used as a new resin for coatings. In addition, the polymer containing a functional group was shown a useful applicability as a high performance resin.

Anti Corrosive Performance of Al and Zn Coatings Deposited by Plasma Arc Thermal Spray Process in Artificial Ocean Water (인공해양환경에서 플라즈마 아크 용사 공법이 적용된 Al 및 Zn 코팅의 부식 방지 성능 평가)

  • Adnin, Raihana Jannat;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.52-53
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    • 2020
  • The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.

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Characteristics of Fluoride-based Anti-stain Chemicals Made from industrial By-product (I) - Anti-mold Effectiveness, Iron Corrosivity and Hygroscopicity - (산업 부산물을 이용하여 제조한 플루오르화합물계 목재 방미제의 특성 (I) - 목재 방미효력 및 철부식성과 흡습성 -)

  • Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.2
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    • pp.73-81
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    • 2004
  • To develope of the inexpensive anti-stain chemicals, it was conducted to investigate the inhibitory effectiveness of mycelial growth and anti-mold effectiveness against test fungi causing surface mold of wood, iron corrosivity and hygroscopicity of six fluoride-based chemicals made from industrial by- product.Among the six chemicals. RNF-3 and RNF-4 were the most effective with respect to a mycelial growth control and anti-mold effectiveness. For the wood treatment with these chemicals, the optimum concentration was about 2% and there was no difference in the effectiveness of chemicals between wood species. The wood treated with synthesized chemicals showed a relatively high iron corrosion rate for corrosive F component whereas, in the treatment with RNF-3 and RNF-4, there was no difference from the untreated wood when the concentration was less than 2%. The hygroscopic property of wood was not effected by treatment of these chemicals. To prove the feasibility for practical using of RNF-3 and RNF-4 chemicals, it is necessary to test of anti-mold effectiveness in the sawmill by field test.

Evaluation of Half Cell Potential Measurement in Cracked Concrete Exposed to Salt Spraying Test (염해에 노출된 균열부 콘크리트의 반전위 평가)

  • Kim, Ki-Bum;Park, Ki-Tae;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.25 no.6
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    • pp.621-630
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    • 2013
  • Several techniques for steel corrosion detection are proposed and HCP (half cell potential) technique is widely adopted for field investigation. If concrete has cracks on surface, steel corrosion is rapidly accelerated due to additional intrusion of chloride and carbon dioxide ions. This study is for an evaluation of HCP in cracked concrete exposed chloride attack. For this work, RC (reinforced concrete) beams are prepared considering 3 w/c ratios (0.35, 0.55, and 0.70) and several cover depths (10~60 mm) and various crack widths of 0.0~1.0 mm are induced. For 35 days, SST (salt spraying test) is performed for corrosion acceleration, and HCP and corrosion length of rebar are evaluated. With increasing crack width, w/c ratios, and decreasing cover depth, HCP measurements increase. HCP evaluation technique is proposed considering the effects of w/c ratios, crack width, and cover depth. Furthermore anti-corrosive cover depths are obtained through Life365 program and the results are compared with those from this study. The results shows relatively big difference in cracked concrete, however provide similar anti-corrosive conditions in sound concrete.

Characteristics of LDPE resin film depending on RP contents (적인 함유량에 따른 LDPE 수지 film의 특성연구)

  • JO, Dong-Soo;Noh, Young-Tai;Park, Byung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6655-6665
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    • 2015
  • Due to tightened environmental regulations on halogen type flame retardants, the portions of those based on phosphorous compounds that are non-halogen type is rising. When producing functional film, the physical and thermal properties become distinctly different depending on the amount of Red-phosphorus(RP) addition which causes flame resistance. The physical properties of resin fall in big scale when too much flame retardants are added, and it is hard to be applied to functional films such as shrink or anticorrosive film. The purpose of this research is to study the effects on mechanical, physical, and other properties of RP-LDPE films by changing the RP-MB contents. The LDPE film used for this study was produced through blow-type injection molding. The flame resistance was VTM-0, and the tear resistance showed inverse trends of MD and TD. Contraction percentage showed no relationship with the amount of RP content, but the anti-corrosive property showed 0.05 % better result than the national anti-corrosion shrink film reliability standard.

Effect of cavitation for electrochemical characteristics in seawater for austenitic 304 stainless steel (오스테나이트계 STS 304강의 해수 내 전기화학적 특성에 미치는 캐비테이션의 영향)

  • Kim, Seong-Jong;Lee, Seung-Jun;Chong, Sang-Ok
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.5
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    • pp.484-492
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    • 2013
  • With the industrial acceleration in a lot of countries of the world, the demand for anti-corrosion and anti-abrasion material increases continuously. Particularly, stainless steel with the fine surface and excellent corrosion resistance is widely used in various industrial fields including ship, offshore structures tidal power plant, and etc. In marine environment, however, it is easy to generate by the corrosion damage by $Cl^-$ ion and cavitation damage due to high rotation speed on stainless steel. Therefore, in this research, the cavitation erosion-corrosion test (Hybrid test) was performed for 304 stainless steel specimen used in the high flow rate seawater environment. And the cavitation damage behavior in the corrosive environment was analyzed overall. The high hardness was shown due to the formation of compressive residual stress by the water cavitation peening effect in cavitation condition. However, high current density in the potentiodynamic polarization experiment presented with the breakdown of the passive film caused by physical impact. Therefore, both electrochemical characteristics and mechanical properties must be taken into account to improve the cavitation resistance in seawater.

Study on the Characteristics of the dehumidification LDPE film (제습 LDPE 필름에 관한 특성 분석연구)

  • JO, Dong-Soo;Noh, Young-Tai;Park, Byung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.7917-7924
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    • 2015
  • In this study, based on CMA which is increasingly used for eco-friendly deicing materials, dehumidification MB made of sodium carbonate, $MgCl_2$/MgO (M/M), and SAP is to be produced. And its moisture absorption rate and dehumidification performance of the film are to be analyzed. And the data on the materials used for the dehumidification film are to be acquired. In case of the dehumidification MB, in which CMA and SAP are mixed, had poor film machinability due to foaming and moisture issues, but adding bentonite and calcium carbonate solved the problem. When a foaming agent was added to extend surface area between substances, CMA and M/M showed no remarkable difference, but SC showed large increase to 3.15 g/g. As the result of anti-corrosive test, CMA dehumidification film showed no corrosion while SC showed pitting corrosion and M/M showed corrosion.

Fabrication and Characteristics of Parylene Coated Isolated Type Pressure Sensor (파릴렌 막이 증착된 봉입형 압력센서의 제작 및 그 특성)

  • 김우정;조용수;김홍균;최시영
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.40 no.2
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    • pp.81-86
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    • 2003
  • To measure the pressure using semiconductor type pressure sensor in water or chemical solution, the sensor must be protected from the solution using proper packaging materials. stainless steel isolated type pressure sensor packaged with SUS316 can be widely used to measure the pressure in water or chemical due to its high corrosion-resistance and good performance in tensility and welding. Even if the surface of SUS316 has a plenty of nickel and chromium, the SUS316 is highly corrosive in acidic or alkaline solution. We coated parylene and adhesion promoting copper layer are 5${\mu}{\textrm}{m}$ and 200nm, respectively. The parylene coated stainless steel pressure sensor showed good anti-corosive characteristics in various strong acids. The accuracy of pressure sensor wasn't varied after parylene coating with 0.5%FSO.

A Study on Corrosive Behavior of Spring Steel by Shot-Peening Process (쇼트피닝 가공을 통한 스프링강의 부식거동에 관한 연구)

  • An, Jae-Pil;Park, Keyung-Dong
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.325-330
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    • 2004
  • Recently, the request for the high strength of material is more and more increased in the area of industrial environment and machinery. To accomplish the high strength of materials, carbonizing treatment, nitrifying treatment, shot-peening method are representatively applied, however, shot-peening method is generally used among the surface processes. Shot peening is a cold working process used to impact Compressive residual stressed in the exposed surface layers. Benefits due to shot peening are increase in resistance to fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in 3.5% NaCl. The immersion test as performed on the two kinds of specimens. Corrsion potential, polarization curve, residual stress and etc, were investigated from experiment results. From test result the effect of shot peening on the corrosion was evaluated. The important results of the experimental study on the effects of shot peened on the environment corrosion of spring steels are as follows; In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent mental. Surface of specimen, which is treated with the shot peened is placed as more activated state against inner base metal. It can cause t도 anti-corrosion effect on the base metal.

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Minimization of Friction and Wear Damage of Marine Structures by Using the Advanced Anti-corrosive Composite Materials (첨단복합방식재를 이용한 각종 선박구조물의 마찰마모손상의 최소화)

  • 김윤해;김진우
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.5 no.2
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    • pp.15-26
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    • 1999
  • The marine structures with sea water cooling system always expose to the oceanic atmosphere. Therefore, the protection of the equipments is very important. To investigate the effectiveness of advanced composite materials for the application in offshore environments, the tensile test, hardness test, undercutting property test, permeance test and the friction and wear test were carried out by using various applicable coating materials. The main results obtained can be summarized as follows; 1. The micro-hardness of the Archcoat 502B showed the highest value. 2. The coefficient of friction of the Rigspray coating at the speed of 2.21m/sec showed the lowest value, and that of the Archcoat 502B coating at 1.08m/sec and 0.18m/sec indicated the lowest values. 3. The wear mass at the speed of 0.18m/sec and 1.08m/sec in dry condition showed the smallest values. 4. The Archcoat 502B coating is fitted to the dynamic instruments in the range of low speed and middle speed. Rigspray coating is fitted to the dynamic instruments in the range of high speed. 5. The wear mass of five kinds of coating materials at the range of low speed was very small, and those of the Archcoat S02B, Archcoat 402B and Rigspray coating at high speed range were quitely smaller than those of the Modified Epoxy and Tar Epoxy.

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