• Title/Summary/Keyword: Anti corrosion

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A Study on the Corrosivity according to Soil Characteristics and Electrolytic Protection for the Materials of Fuel Gas Pipe (토양 특성 및 전기방식에 따른 연료 가스용 강관의 부식 차이에 관한 연구)

  • Yim, Sang-Sik;Kim, Ji-sun;Ryu, Young-don;Lee, Jin-Han
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.16-22
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    • 2016
  • Coating pipe(PLP) has been generally used in buried site for protecting the corrosion. To prevent the damage by occurring the defect, other construction or execution works, an anti-oxidation environment was forcibly made by using protective potential. Coating and protective potential are applied simultaneously, but corrosion rate or defects are not easy to observe because soil composition has many uncertainty. Also, defect of coating pipe can not be directly observed. A corrosion coupon can easily measure a corrosion rate directly. The corrosion rate was measured with 6 scenarios using corrosion coupon during about 1 year(6 scenarios are based on soil type and protective potential or not in this research. Resultingly, the corrosion coupon has not occurred in the case of protected by potential current, but corrosion has occurred in a non-protected site. The corrosion rate was measured at least in the clay, and the propensity of corrosion rate was similar in other soil(sand and loams). The local corrosion has occurred in the clay because of high water content. On the other hand, general corrosion was occurred in sand and loams. Commonly, sand is not to corrosive soil. Although, corrosion occurred in sand can be estimated by chemical component and valid with chemical analysis report.

Effects of alloying elements on the mechanical and high temperature corrosion properties of solid-solution hardening nickel-base alloy (Ni-Cr계 고용강화형 합금에서 조성에 따른 기계적 및 고온부식 특성 평가)

  • Jung, Sujin;Kim, Dong-Jin
    • Corrosion Science and Technology
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    • v.13 no.5
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    • pp.178-185
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    • 2014
  • Alloy 617 is considered as a candidate Ni-based superalloy for the intermediate heat exchanger (IHX) of a very high-temperature gas reactor (VHTR) because of its good creep strength and corrosion resistance at high temperatures. Helium is used as a coolant in a VHTR owing to its high thermal conductivity, inertness, and low neutron absorption. However, helium inevitably includes impurities that create an imbalance in the surface reactivity at the interface of the coolant and the exposed materials. As the Alloy 617 has been exposed to high temperatures at $950^{\circ}C$ in the impure helium environment of a VHTR, the degradation of material is accelerated and mechanical properties decreased. The high-temperature strength, creep, and corrosion properties of the structural material for an IHX are highly important to maintain the integrity in a harsh environment for a 60 year period. Therefore, an alloy superior to alloy 617 should be developed. In this study, the mechanical and high-temperature corrosion properties for Ni-Cr alloys fabricated in the laboratory were evaluated as a function of the grain boundary strengthening and alloying elements. The ductility increased and decreased by increasing the amount of Mo and Cr, respectively. Surface oxide was detached during the corrosion test, when Al was not added to alloy. However the alloy with Al showed improved oxide adhesive property without significant degradation and mechanical property. Aluminum seems to act as an anti-corrosive role in the Ni-based alloy.

An Experimental Study on the Salt Resistance Properties with Concrete Materials under Marine Exposure Environment (I) (해양환경에 폭로한 콘크리트의 내염특성에 대한 실험적 연구 (I))

  • 신도철;김영웅;김용철;김동철
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.51-56
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    • 2002
  • Protection against salt attack in seawater is obtained by using a dense, quality concrete with a low water-cement ratio, and a components appropriate for producing concrete having the needed salt resistance. The objective of this study is to evaluate the feature of corrosion with using the various concrete materials under marine exposure environment. According to the test results, slag powder and anti -corrosion inhibitor showed high chloride resistance effect. Also concre crack have an influence on corrosion of steel in spite of mixed design for salt resistance concrete. The requirement for low permeability is essential not only to delay the effect of salt attack, but also to afford adquate protection to reinforcement with admixtures.

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A New Protection Strategy of Impressed Current Cathodic Protection for Ship

  • Oh, Jin-Seok;Kim, Jong-Do
    • Journal of Mechanical Science and Technology
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    • v.18 no.4
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    • pp.592-596
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    • 2004
  • Corrosion is never avoided in the use of materials with various environments. The underwater hull is normally protected against rusting by several coatings of anti-corrosive paint. The purpose of ICCP(Impressed Current Cathodic protection) system is to eliminate the rusting or corrosion, which occurs on metal immersed in seawater. The anode of ICCP system is controlled by an external DC source with converter. The function of anode is to conduct the protective current into seawater. The proposed algorithm includes the harmonic suppression control strategy and the optimum protection strategy and has tried to test the requirement current density for protection, the influence of voltage, the protection potential. This paper was studied the variation of potential and current density with environment factors, time and velocity, and the experimental results will be explained.

Development of Composite Pedestrian Bridge Deck and Its Snap-fit Connection (착탈결구식 복합소재 바닥판의 연결부 거동분석)

  • Lee, Sung-Woo;Jeong, Gyu-Sang
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.280-284
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    • 2005
  • Existing construction materials such as concrete and steel have chronic problems; deterioration and corrosion. Owing to its special features of light weight ‘ high durability, anti-corrosion, composite material used in civil infrastructure can not only solve fundamental problems of deterioration and corrosion, but also reduce both construction and maintenance cost significantly. After the fabrication of deck panel with snap-fit connection by pultrusion through composite design according to stacking sequence of composite laminates and structural analysis, performance of decks will be verified and evaluated by structural tests.

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A STUDY ON THE ANTI-CORROSION OF Al-Cu AFTER PLASMA ETCHING (Al-Cu막의 플라즈마 식각후 부식 억제에 관한 연구)

  • Kim, Hwan-Jun;Kim, Chang-Il;Kwon, Kwang-Ho;Kim, Tae-Hyong;Seo, Yong-Jin;Chang, Eui-Goo
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1277-1279
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    • 1997
  • In this study, the mechanism underlying the corrosion problem have been investigated using X-ray photoelectron spectroscopy(XPS) and scanning electron microscopy(SEM), AES(Auger electron spectroscopy) In regard to the removal of Al-Cu corrsion, the subsequent treatment of the $SF_6$ plasma has also been completed. This work evaluated the effects of grain boundary on the AlCu after dry etching and the role of subsequent $SF_6$ plasma for the removal of AlCu corrosion.

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Cavitation-erosion Resistance of Stabilized Stainless Steel with Niobium Addition in Sea Water Environment (해수 내 캐비테이션-침식 저항성에 미치는 스테인리스강의 Nb 첨가의 영향)

  • Choi, Yong-Won;Han, Min-Su;Kim, Seong-Jong
    • Journal of Surface Science and Engineering
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    • v.49 no.3
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    • pp.274-279
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    • 2016
  • Stainless steel is widely used in various industries due to its excellent anti-corrosion characteristics. However, if the stainless steel is exposed to high speed fluid flow and chloride ion in the marine environment, corrosion and cavitation damage occurred on the surface easily. Therefore, to prevent these problems, stabilzed stainless steel is applied to offshore and shipbuilding industries. In this study, stabilized stainless steel specimen was made by 19%Cr-9%Ni with different Nb contents (0.29%, 0.46% and 0.71%). And then, their cavitation characteristics were investigated. As a result, the characteristics of cavitation resistance of stainless steel could be improved by increasing Nb contents.

Anti Corrosive Performance of Al and Zn Coatings Deposited by Plasma Arc Thermal Spray Process in Artificial Ocean Water (인공해양환경에서 플라즈마 아크 용사 공법이 적용된 Al 및 Zn 코팅의 부식 방지 성능 평가)

  • Adnin, Raihana Jannat;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.52-53
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    • 2020
  • The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.

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Evaluation of Corrosivity of Antifreeze for Automobiles Containing Non-amine Type Corrosion Inhibitors for Copper (Non-amine계 부식방지제를 포함하는 자동차용 부동액의 구리 부식성 평가)

  • Soh, Soon-Young;Chun, Yong-Jin;Park, In-Ha;Han, Sang-Mi;Jang, Hee-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.2
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    • pp.619-626
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    • 2020
  • The development of new antifreeze mixtures containing non-amine-type corrosion inhibitors, which considers environmental protection, has become a major issue. In this study, four non-amine-type corrosion inhibitors were synthesized and used to produce five kinds of new antifreeze for automobiles to evaluate the rate of copper corrosion. The effects were evaluated by the weight change, surface observation, roughness measurement, and measurement of copper elution in the solution. The amount of copper eluted measured by ICP from Sample 4 was small, and the elution rate was prolonged. Sample 4 showed the best anti-corrosion performance owing to a corrosion suppression effect by passivating copper because the metal surface was smooth after the test, and the corrosion product layer was formed evenly on the surface as small local corrosion was observed. The major corrosion inhibitor added to Sample 4 was 1-aminomethyl(N',N'-di(2-hydroxyethyl)benzotrazole, which contained a certain amount in Sample 5 to show relatively high local corrosion but passivation in progress. Therefore, among the four corrosion inhibitors, 1-aminomethyl(N',N'-di(2-hydroxyethyl)benzotrazole had the highest corrosion inhibitory effect. This corrosion inhibitor prevents corrosion by promoting the passivation of copper on the antifreeze.

A Study on Corrosion Resistance of CA2-Mixed Paste (CA2 혼입 페이스트의 부식저항성에 관한 연구)

  • Kim, Jae-Don;Jang, Il-Young
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.2_2
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    • pp.289-297
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    • 2022
  • Deterioration in durability of structures due to the steel corrosion is difficult to determine whether or not corrosion is initiated and how much propagated, and moreover, repair and maintenance are not easy to deal with. Therefore, preventive treatments can be the best option to avoid the deterioration. Various methods for preventing corrosion of steel, such as electrochemical treatments, anti-corrosion agents and steel surface coatings, are being developed, but economic and environmental aspects make it difficult to apply them to in-situ field. Thus, the purpose of this study was to improve corrosion resistance by using CA-based clinker that are relatively simple and expected to be economically profitable Existing CA-based clinkers had problems such as flash setting and low strength development during the initial hydration process, but in order to solve this problem, CA clinker with low initial reactivity were used as binder in this study. The cement paste used in the experiments was replaced with CA2 clinker for 0%, 10%, 20%, and 30% in OPC. And the mixture used in the chloride binding test for the extraction of water-soluble chloride was intermixed with Cl- 0.5%, 1%, 2%, and 3% by weight of binder content. To evaluate characteristic of hydration heat evolution, calorimetry analysis was performed and simultaneously chloride binding capacity and acid neutralization capacity were carried out. The identification of hydration products with curing ages was verified by X-ray diffraction analysis. The free chloride extraction test showed that the chlorine ion holding ability improved in order OC 10 > OC 30 > OC 20 > OC 0 and the pH drop resistance test showed that the resistance capability in pH 12 was OC 0 > OA 10 > OA 20 > OA 30. The XRD analyses showed that AFm phase, which can affect the ability to hold chlorine ions, tended to increase when CA2 was mixed, and that in pH12 the content of calcium hydroxide (Ca(OH)2), which indicates pH-low resistance, decreased as CA2 was mixed