• Elastomers and Composites
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• 제50권4호
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• pp.304-313
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• 2015

In this study, the anionic emulsified asphalt was prepared by dispersing asphalt particles evenly into water with combination of anionic and nonionic surfactants. Effects of NaOH and $CaCl_2$ on the phase stability of the emulsified asphalt were also investigated through zeta potential value and rheology behavior; the emulsified asphalt added with NaOH and $CaCl_2$ showed higher zeta potential value than that the asphalt with addition of only anionic and nonionic surfactants. In addition, with regard to shear thinning behaviors, it was found that pH of the emulsified anionic asphalt and $Ca^{2+}$, counter ion, affected the phase stability. SBR (styrene-butadiene-rubber) latex, EPD (water dispersed Epoxy), PU (polyurethane) and RI-10S, SBS (styrene-butadiene-styrene)-based property improvement additive, were used and studied to enhance the adhesion properties with the aggregates. RI-10S, however, was found to be only compatible with the anionic emulsified asphalt; the coating rate, adhesion and compression strength were increased with the RI-10S content.

• 식물조직배양학회지
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• 제25권4호
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• pp.277-282
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• 1998

장미(Rosa sp. cv Paul's Scarlet) 현탁 배양체의 배지에서는 정상적인 성장 조건하에서 cationic peroxidase (POD)만 관찰되었으나, 효모 세포벽으로부터 추출한 숙주 특이성이 낮은 elicitor를 10 mg glucan/L의 농도로 투여하여 24시간 정도 배양하였을 때 기존의 POD와 뚜렷하게 구분되는 anionic POD가 유도됨을 관찰하였다. Elicitor에 의해 유도되는 prominent한 anionic POD (pI 6.1)와 대조구로서 pI 8.4의 cationic isozyme을 분리한 후 효소학적 성질을 비교하였다. Ammonium sulfate농축, ion exchange chromatography, gel filtration chroma tography를 통하여 약 200배로 농축된 두 효소를 분리하였으며, 이 두 효소의 몇몇 기질에 대한 kinetic parameter들은 매우 의미있는 차이를 보여 주었다. 그 중에서 ferulic acid에 대한 Km은 anionic POD의 경우 4.6 mM, cationic POD는 1.38 mM로 측정되었으며, $\textrm{H}_2\textrm{O}_2$에 대한 Km은 각각 anionic POD가 0.72 mM, cationic isozyme이 0.45 mM로 나타났다. 특히 NADH 산화 반응의 활성은 anionic POD가 cationic POD에 비하여 약 2배 높은 것으로 측정되었다. 0.1 mM coniferyl alcohol의 첨가에 의한 NADH 산화 반응의 억제는 anionic POD fraction에서 약 60% 정도 일어난 반면에 cationic POD fraction에서는 약 15% 정도 일어났다.

• 한국응용과학기술학회지
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• 제33권3호
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• pp.449-458
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• 2016

Detergency and surface active properties of mixed anionic surfactants with amphoteric and nonionic were investigated. Sodium dodecyl sulfate (SDS) and ammonium dodecyl sulfate (ADS) as anionic surfactants and cocamidopropyl betaine (CAPB) as an amphoteric surfactant were used. Nonionic surfactants, which are butyl glucoside (BG), octyl glucoside (OG), decyl glucoside (DG), lauryl dimethylamine oxide (AO) and saponin were also used. To study the synergy effects of mixed SDS/ADS anionic surfactant systems, amphoteric and nonionic surfactants were added into the mixed anionic surfactants. Investigated properties of surfactant mixtures were critical micelle concentration (CMC), surface tension (${\gamma}$), wettability. In addition, based on these properties, detergency of each sample was examined. Surfactant mixtures are anionics (SDS/ADS), anionic/amphoteric/nonionic (SDS/ADS/CAPB/saponin), and anionic/nonionic (SDS/ADS/BG/saponin, SDS/ADS/OG/saponin, SDS/ADS/DG/saponin, and SDS/ADS/AO/saponin). With the addition of amphoteric and nonionic to mixed anionic surfactants, CMC and ${\gamma}$ were decreased. Addition of CAPB, which is amphoteric, showed the best property at CMC and ${\gamma}$. Furthermore, as the chain length of hydrocarbon in alkyl glucosides was increased, the CMC and ${\gamma}$ were enhanced. However, the wettability did not exactly match up with CMC and ${\gamma}$. The surfactant mixture, which contained DG, showed the best performance at wetting time. Detergency was measured at various temperatures ($15^{\circ}C$, $30^{\circ}C$, $50^{\circ}C$). The cleaning performance was enhanced by increasing washing temperature. Moreover, detergency was influenced by not only CMC and ${\gamma}$ but also wettability. Although CMC and ${\gamma}$ were not minimum at surfactant mixture that included DG, the best cleaning performance showed in that sample.

• Applied Biological Chemistry
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• 제43권2호
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• pp.100-105
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• 2000

한국산 무(Raphanus sativus L.)로부터 황산암모늄 분별침전과 CM-cellulose ion exchange chromatography를 사용하여 anionic peroxidase(POD)를 분리하였다. 분리된 한국산 무 anionic POD를 비색효소로, o-tolidine 혹은 4-aminoantipyrine/diethylaniline(4AA/DEA)을 비색기질로 사용하여 630nm에서의 흡광도를 측정함으로써 당 정량반응을 실시하였다. 한국산 무 anionic POD는 비색기질로 4AA/DEA을 사용한 경우 o-tolidine을 사용했을 때 보다 더 높은 비색 반응성을 나타내었다. Glutosr의 농도증가에 따른 검정곡선을 작성하였을 때 o-tolidine과 4AA/DEA을 사용한 경우 상관계수가 각각 r=0.9983과 r=0.9963로서 두 가지 방법의 검정곡선이 모두 좋은 직선성을 보여 주었다. 한국산 무 anionic POD와 horseradish POD의 기질산화에 대한 반응성을 비교하기 위하여 o-dianisidine과 guaiacol Km값을 조사한 결과, 한국산 무 anionic POD가 horseradish POD보다 o-dianisidine에 대해 약 40배, guaiacol 대하여 약 2배의 높은 기질 반응성을 나타내었다. 이러한 결과들은 한국산 무 anionic POD를 비색효소로 사용하여 검출감도가 높은 당 정량용 진단시약을 개발할 수 없음을 보여준다.

• 한국염색가공학회지
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• 제15권6호
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• pp.47-54
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• 2003

To be dyed with cationic Berberine, the cotton fiber was modified with reactive anionic agent. The Berberine, a natural cationic colorant of pure yellow, is the major component of Amur Cork tree extract and also can be employed as a natural antimicrobial agent due to its characteristic of cationic quaternary ammonium salt. By LC/MS analysis, it became obvious that the Berberine was contained in Amur Cork tree extract as a major color component. The adsorption of the Berberine on the cotton fabrics pretreated with the anionic agent was greatly increased comparing to that of untreated fabric. Because the anionic agent was colorless, it did not cause unintended color change of the dyeings. The dyed fabric with the Berberine has strong antimicrobial activity showing 99.5% of reduction of bacteria against Staphylococcu aureus.

• Journal of Photoscience
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• 제7권1호
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• pp.9-13
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• 2000

An alternately assembled polycation-anionic dye film was prepared on a precursor assembly of poly(allylamine)hydrochloride (PAH) and poly(sodium styrenesulfonate) (PSS) or of poly (djallyldimethyl)ammonium chloride (PDDA) and PSS. The (PAH/PSS) precursor assembly gave better adsorptivity to the anionic dye than the (PDDA/PSS) one. Four kinds of anionic dyes (EB-T, AR-17 AR-18, AR-27) with different numbers of sulfonate substituents were compared. The extent of dye assembling was higher for the dye with a smaller number of sufonate substituents. Second harmonic generation (SHG) was clearly observed from the films. The SHG signal and the absorption intensity correlated well up to four polycation/dye bilayers, while further assembly did not increase the SHG signal appreciably. Second order nonlinear coefficients for ten bilayer assemblies were the order of pm/V.

• Applied Science and Convergence Technology
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• 제24권6호
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• pp.284-288
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• 2015

Anionic small molecules are hard to penetrate the cell membranes because of their negative charges. Encapsulation of small molecules into liposome particles can provide target specific delivery of them. In our previous study, siRNA could be efficiently encapsulated into liposome particles using an asymmetric preparation method of liposomes. In this study, the same method was applied for encapsulation of small anionic fluorescent chemicals such as calcein and indocyanine green (ICG). More than 90% fluorescent chemicals were encapsulated in the asymmetric liposome particles (ALPs). No intracellular fluorescent signal was observed in the tumor cells treated with the unmodified calcein/ALPs and ICG/ALPs, whereas the surface modification with a cell-penetrating polyarginine peptide (R8 or R12) allows cellular uptake of the ALPs. The results demonstrate that the ALPs encapsulating small anionic drugs will be useful for target-specific delivery after modification of target-specific ligands.

• 한국건축시공학회지
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• 제11권6호
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• pp.557-566
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• 2011

The surfactants facilitate the formation of foam bubbles under a proper condition and provide stability of foam bubbles by decreasing the surface tension of solutions and increasing the viscosity of foam surface. However, there have been almost no practical data of foam concrete in this regard so far. This study aims to understand the effects of foaming agents such as anionic synthetic surfactant and anionic natural material surfactant on the low density foamed concrete. From the experiment, the vegetable soap of anionic natural material surfactants showed a higher foaming rate, more open pores, slightly lower compressive strength, and a higher permeability coefficient compared to the vegetable soap of anionic synthetic surfactants. It is believed that the natural material surfactants make not only the surface tension of the solution low but also the viscosity of slurry high.

• 한국응용과학기술학회지
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• 제19권2호
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• pp.86-96
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• 2002

Oligomer type anionic surfactants(RmM-Na or RmD-Na} were synthesized from $C_{8}{\sim}C_{16}$ long chain alkylvinylether and maleic anhydride (or maleic diethylether). And also their fluorescent anionic surfactants (RmF- Na) were obtained from alkali neutralization which opens the lactone ring of the condensing materials produced by maleic anhydride alkylvinylether copolymer and 3-aminophenol. The measurement results for the surface active properties of water soluble oligomer type anionic surfactants with fluorescent structure (RmF-Na) exhibited a remarkable surface tension lowing property, foam breaking property, and a ernulsing power.

• 한국염색가공학회지
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• 제17권1호
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• pp.20-29
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• 2005

Cotton fabric was treated with a reactive anionic agent in order to have anionic sites(-S03-) on it, which made it possible for the fabric to adsorb various cationic materials. In this study, the adsorptivity of various heavy metal ions such as Pb(II), Cd(II), Cr(III), Co(II), Cu(II), Ni (II) and Cr(VI) on the cotton fabrics treated with anionic agent was examined at the various conditions; concentrations of heavy metal ions, pHs of solution, reaction time and temperature. As a result, the adsorptivity of the heavy metal ions on the cotton fabrics treated with the anionic agent was highly increased comparing to that of untreated cotton fabrics. The order of the adsorptivity was as follows: $Pb(II)>Cd(II)>Cu(II)\geqNi(II)\geqCo(II)>Cr(III)\ggCr(VI)$. The adsorption amounts of most heavy metal ions were increased in weak alkaline conditions and were reached to an adsorption equilibrium within 10 ~ 30 minutes. The maximum adsorption ratios of Pb(II) and Cd(II) were respectively 99% and 80% of the initial concentration of heavy metal ions. Therefore the anionized cotton fabrics seem to be utilized as an adsorption fabrics for the removal of heavy metal ions in the waste water.