Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
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Precursor and Substituent Effects on the Alternate Adsorption of Polycation and Anionic Dyes as Studied by Second Harmonic Generation and Absorption Spectroscopies

  • Yamada, Sunao (Department of Materials Physics and Chemistry, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan) ;
  • Niidome, Yasuro (Department of Materials Physics and Chemistry, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan) ;
  • Hinoguchi, Takeshi (Department of Materials Physics and Chemistry, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan)
  • Published : 2000.03.01
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Abstract

An alternately assembled polycation-anionic dye film was prepared on a precursor assembly of poly(allylamine)hydrochloride (PAH) and poly(sodium styrenesulfonate) (PSS) or of poly (djallyldimethyl)ammonium chloride (PDDA) and PSS. The (PAH/PSS) precursor assembly gave better adsorptivity to the anionic dye than the (PDDA/PSS) one. Four kinds of anionic dyes (EB-T, AR-17 AR-18, AR-27) with different numbers of sulfonate substituents were compared. The extent of dye assembling was higher for the dye with a smaller number of sufonate substituents. Second harmonic generation (SHG) was clearly observed from the films. The SHG signal and the absorption intensity correlated well up to four polycation/dye bilayers, while further assembly did not increase the SHG signal appreciably. Second order nonlinear coefficients for ten bilayer assemblies were the order of pm/V.

Keywords

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