• 제목/요약/키워드: Anion

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도심지내 분수유형별 음이온 분포 및 상관성 분석 (Anion Distribution and Correlation Analysis by Fountain Type in Urban)

  • 김정호;박승환;김원태;윤용한
    • 한국환경과학회지
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    • 제22권12호
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    • pp.1599-1610
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    • 2013
  • In order to verify the healing effect in the variety of effects according to fountain type, anion which is the representatives factor of healing, as the center of case studies which in Gwanghwamun(Ground fountain), Cheonggyecheon(Waterfall) and Myeongdong(Formative fountain). According to fountain type, the anion distribution as follow, figures typically$ 15,721{\pm}419ea/cm^3$, Formative fountain $40,190{\pm}788ea/cm^3$, Waterfall $4.480{\pm}290ea/cm^3$ and ground fountain $2.492{\pm}180ea/cm^3$. It is usually exceed to the distribution in natural green, which is $1070{\sim}2100ea/cm^3$. The interrelation between air temperature, relative humidity, wind speed and relative humidity, and wind speed is that, the relative humidity is directly proportional to wind speed and inversely proportional to temperature. As the temperature goes up, the distribution of anion goes down. And as the wind speed and relative humidity goes up, the distribution of anion decrease sharply. The result of interrelation between fountain type and the anion distribution is that, the distance of water falling is directly proportional to the anion distribution in the formative fountain and inversely proportional in the ground fountain. And the distribution of anion is largest in formative fountain. The distribution of anion in ground fountain is lower than in formative fountain, but it is far more than in natural greenery. And as the distance from fountain increase, the distribution of anion goes down.

폴리에테르설폰-폴리페닐렌설파이드설폰 블렌딩 고분자를 이용한 음이온교환막의 제조 (Preparation of an Anion Exchange Membrane Using the Blending Polymer of Poly(ether sulfone) (PES) and Poly(phenylene sulfide sulfone) (PPSS))

  • 이경한;한주영;유철휘;황갑진
    • 멤브레인
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    • 제29권3호
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    • pp.155-163
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    • 2019
  • 폴리에테르설폰(PES)과 폴리페닐렌설파이드설폰(PPSS)을 블렌딩한 고분자를 이용하여 음이온교환막을 제작하였다. EDXS와 FT-IR 분석으로부터 제작한 음이온교환막이 음이온교환기인 -N-을 갖는다는 것을 확인하였다. 1 mol/L의 황산용액에서 이온전도도를 측정하였다. 제작한 음이온교환막은 0.015~0.083 S/cm의 이온전도도를 가졌으며, 시판의 음이온교환막인 AFN과 APS의 값과 비교하여 동등 이상의 값을 가졌다. 제작한 음이온교환막의 바나듐 레독스 흐름 전지용 격막으로 사용한지를 평가하기 위해 각 바나듐 이온의 투과를 측정하였다. 제작한 음이온교환막의 각 바나듐 이온의 투과도는 시판의 양이온교환막인 Nafion 117과 시판의 음이온교환막인 AFN과 비교하여 낮은 값을 가졌다.

양양군 국유림 지역의 음이온 농도와 임상, 숲 관련인자와의 상관 (Correlations Between Concentrations of Negative Ions and Forest Type, and Site Factors at National Forests in Yangyang-gun)

  • 엄태원;김갑태
    • 한국환경생태학회지
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    • 제24권5호
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    • pp.539-546
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    • 2010
  • 본 숲에서 발생하는 음이온의 농도가 임상과 숲 관련인자에 따른 변이를 파악하고자, 강원도 고성군, 양양군에 위치한 국유림지역에서 52개의 방형구에서 산림조사와 음이온의 농도를 측정하고 관련성을 분석하였다. 측정된 음이온의 평균값 2,405개/$cm^3$는 일반적인 숲에서 보고된 2,000개/$cm^3$ 보다는 조금 높은 값이었다. 음이온 농도와 지형에서는 5% 유의수준에서, 음이온 농도와 토양수분, 해발고에서는 1% 유의수준에서 각각 정의 상관이 인정되었다. 조사지의 음이온 농도는 토양수분 수준간 고도의 통계적 유의성이 인정되었으며, 다습한 지역에서 평균 음이온 농도가 4,524.4개/$cm^3$로 가장 높았다. 지형에서는 계곡부 조사지의 평균 음이온 농도가 3,372.4개/$cm^3$로 가장 높았으며, 사면, 능선 순으로 점차 낮아지는 경향을 보였다. 측정시간대에서는 오전(12시 이전)에 측정된 평균 음이온 농도가 3,133.4개/$cm^3$로 가장 높았으며, 낮(12:00~15:00), 저녁(15시 이후) 순으로 점차 낮아지는 경향을 보였다. 임상에서는 활엽수 혼효림에서 측정된 평균 음이온 농도가 3,503.9개/$cm^3$로 가장 높았으며, 참나무림, 소나무림, 소나무-참나무 혼효림 순으로 점차 낮아지는 경향을 보였다. 이 연구의 결과는 치유의 숲 입지선정에 활용할 수 있을 것이라 사료된다.

음이온교환수지 혼입 시멘트 모르타르의 압축강도 및 염소이온 침투 저항성에 관한 실험적 연구 (An Experimental Study on the Compressive Strength and Chloride ion penetration resistance of Cement Mortar mixing Anion Exchange Resin)

  • 정도현;이윤수;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 추계 학술논문 발표대회
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    • pp.23-24
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    • 2018
  • Reinforced concrete is a building material that is generally used in modern society. Also, reinforced concrete structures in high salinity environments have low durability due to corrosion of reinforcing bars due to infiltrated chlorine ions. Anion exchange resins have an ability to immobilize chlorine ions in the resin while releasing their anions. As a material, it has already been shown that it is possible to fix the chloride ion inside the cementitious material through the cement mortar experiment. The purpose of this study is to confirm the compressive strength of cement mortar using powdered anion exchange resin after powdering an anion exchange resin. In order to confirm the chloride ion fixation ability of the powder anion exchange resin, chlorine ion penetration resistance test was carried out.

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방사선그라프팅 음이온교환막의 기계적 물성에 대한 4차 암모늄 음이온교환기의 영향 (Influence of Quaternary Ammonium Anion Exchange Moieties onto Mechanical Properties of Radiation-grafting Anion Exchange Membranes)

  • 고범석;손준용;신준화
    • 방사선산업학회지
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    • 제6권1호
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    • pp.49-54
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    • 2012
  • Various anion exchange membranes were prepared by radiation graft copolymerization of vinylbenzyl chloride onto fluorinated films and subsequent quaternization with various tertiary amines such as trimethylamine, N,N-dimethylbuthylamine, N,N-dimethylaniline, and N-methylpiperidine. The quaternizations of the anion exchange membranes were confirmed by measuring of the ion exchange capacities of the membranes. The mechanical properties and the water uptakes were also measured. The elongation at break was found to be largely dependent on the fluorinated film, the quateranry ammonium, and the degree of grafting. The results indicate that the poly (ethylene-alt-tetrafluoroethylene) with quaternized trimethylamine moiety exhibits higher flexible property compared to the other prepared anion exchange membranes.

음이온교환수지와 활성탄을 이용한 산업 폐수 중 셀레늄의 흡착 (Adsorption of Selenium in Industrial Wastewater Using Anion Exchange Resin and Activated Carbon)

  • 한상욱;박진도;이학성
    • 한국환경과학회지
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    • 제18권12호
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    • pp.1411-1416
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    • 2009
  • Several adsorbents were tried to remove the selenium ions from industrial wastewater and the following ascending order of the adsorption performance for the selenium at pH 9 was observed: cation exchange resin < chelate resin < zeolite < brown marine algae < granular activated carbon < anion exchange resin. Initial concentration of selenium(146 mg/L) in industrial wastewater was reduced to 63 mg/L of selenium at pH 9 by neutralization process. The maximum uptake of Se calculated from the Langmuir isotherm with anion exchange resin was 0.091 mmol/g at pH 10 and that with granular activated carbon was 0.083 mmol/g at pH 6. The affinity coefficients of Se ion towards anion exchange resin and granular activated carbon were 3.263 L/mmol at pH 10 and 0.873 L/mmol at pH 6, respectively. The sorption performance of anion exchange resin at the low concentration of Se, namely, was much better than that of granular activated carbon. The Se ions from industrial wastewater throughout neutralization process and two steps of adsorption using anion exchange resin was removed to 97.7%.

Durability enhancement of anion exchange membranes for water electrolysis: an updated review

  • Akter, Mahamuda;Park, Jong-Hyeok;Kim, Beom-Seok;Lee, Minyoung;Jeong, Dahye;Shin, Jiyun;Park, Jin-Soo
    • 한국표면공학회지
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    • 제55권6호
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    • pp.319-327
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    • 2022
  • Ion exchange membranes have been developed from laboratory tools to industrial products with significant technical and trade impacts in the last 70 years. Today, ion exchange membranes are successfully applied for water and energy for different electro-membrane processes. Hydrogen could be produced by electrochemical water splitting using renewable energy, for example, solar, biomass, geothermal and wind energy. This review briefly summarizes the recent studies reporting the state-of-the-art anion-exchange membrane water electrolysis, especially focusing on the enhancement of the durability of anion-exchange membranes. Anion-exchange membrane water electrolysis could be used as inexpensive non-noble metal electrocatalysts that are capable of producing low cost of hydrogen. However, the main challenge of anion-exchange membrane water electrolysis is to increase the performance and durability. In this mini review, the limiting factors of the durability and the technology enhancing the durability will be discussed for anion exchange membrane water electrolysis.

Anion Receptors with 2-Imidazolidone Molecular Scaffold

  • Kim, Hyung-Il;Kang, Jong-Min
    • Bulletin of the Korean Chemical Society
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    • 제28권9호
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    • pp.1531-1534
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    • 2007
  • Anion receptor based on 2-imidazolidone molecular scaffold has been synthesized. Anion binding studies carried out using 1H NMR and UV?vis spectroscopy revealed that this receptor 6 displays selectivity for the for the oxyanions such as acetate and dihydrogenphosphate ions and the affinity for the anions simply reflects the basicity of anions.

알칼리 수전해용 격막으로서 폴리염화비닐(polyvinyl chloride) 음이온교환막의 제조에 관한 연구 (Study on the Preparation of Polyvinyl Chloride Anion Exchange Membrane as a Separator in the Alkaline Water Electrolysis)

  • 박종호;봉수연;유철휘;황갑진
    • 멤브레인
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    • 제23권6호
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    • pp.469-474
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    • 2013
  • 알칼리 수전해용 격막으로 사용하기 위해 음이온교환막을 제작하였다. 음이온교환막은 PVC (polyvinyl chloride)를 출발물질로 하여 클로로메틸화 및 아민화에 의해 제작하였다. 제작한 막은 막 특성(막 저항, 이온교환용량)을 평가하였다. 제작한 음이온교환막의 1M NaOH수용액에서의 최저 막 저항은 $2.9{\Omega}{\cdot}cm^2$를 나타냈다. 이 막은 2.17 meq./g-dry-membrane의 이온교환용량과 43.4%의 함수율을 보였다. 제작한 음이온교환막의 막 특성을 시판의 막 특성과 비교 평가하였다. 1M NaOH수용액에서의 막 저항은 AHT>IOMAC>Homemade membrane>AHA>APS=AFN의 순으로 저항 값이 높았다. 이온교환 용량은 Homemade membrane>AFN>APS>AHT>AHA>IOMAC의 순으로 높은 값을 가졌다.