• Carbon letters
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• 제14권1호
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• pp.51-54
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• 2013

In this study, polyaniline (PANI)/graphene nanosheet (GNS) composites were synthesized through chemical oxidation polymerization by changing the weight ratio of aniline monomers. To examine the morphological structure of the composites, scanning electron microscopy and transmission electron microscopy (TEM) were conducted. TEM results revealed that fibril-like PANI with a diameter of 50 nm was homogeneously coated on the surface of the GNS. The electrochemical properties of the composites were studied by cyclic voltammetry in 1 M $H_2SO_4$ electrolyte. Among the prepared samples, the PANI/GNS (having 40 wt% aniline content) showed the highest specific capacitance, 528 $Fg^{-1}$, at 10 $mVs^{-1}$. The improved performance was attributed to the GNS, which provides a large number of active sites and good electrical conductivity. The resulting composites are promising electrode materials for high capacitative supercapacitors.

• Korea-Australia Rheology Journal
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• 제16권4호
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• pp.193-199
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• 2004

Poly(o-ethoxy)aniline (PEOA)/organoclay nanocomposite was prepared via a solvent intercalation using chloroform as a cosolvent with organically modified montmorillonite (OMMT) clay. The PEOA initially synthesized from a chemical oxidation polymerization in an acidic condition at pH = 1 was intercalated into interlayers of the clay with $25\;wt{\%}$ clay content. Electrical conductivity of the PEOA/OMMT nano­composite was found to be controlled via the intercalating process. The synthesized PEOA/OMMT nano­composite was characterized via an XRD and a TGA, and then adopted as an electrorheological (ER) material. The PEOA/OMMT synthesized with controllable electrical conductivity without a dedoping pro­cess was found to show typical ER characteristics possessing a yield stress from both steady state and dynamic measurements under an applied electric field.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.121.2-121.2
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• 2014

Synthesis of catecholamine from aniline is achieved by plasma enhanced CVD process. Catecholamine has a variety of functions in body such as brain and bloodstream controls. Catecholamine also has an interesting property of a material independent ability of functionalizing surface, which is found at mussels' adhesive nature. Synthesis of catecholamine has only been available from DOPA by chemical reduction and oxidation. This study presents the direct synthesis of catecholamine from further elemental source, aniline, which has not been achieved by a conventional chemical method. The process also indicates that a variety of catecholamine can be formed by controlling reactant gases. In additional to PECVD's very useful properties such as conformal, ultrathin and uniform coatings, a direct synthesis from aniline and a capability of controlling formation of a variety catecholamine is believed to open up a numerous applications.

• 분석과학
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• 제30권1호
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• pp.49-56
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• 2017

Here, we demonstrate surface functionalization of Au chips with 4-(carboxymethyl)aniline (CMA) and amine-terminated polyamidoamine (PAMAM) dendrimers for immobilization of antibodies on the Au surfaces. Use of the functionalization strategy led to high surface density of the immobilized antibodies on the Au chips. Specifically, we found that the functionalization of Au chips with CMA and amine-terminated $6^{th}$ generation PAMAM dendrimers allowed immobilization of immunoglobulin (IgG) antibodies with high surface density, which is 5 times higher than that obtained with Au surfaces functionalized with CMA and ethylenediamine.

• 공업화학
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• 제17권5호
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• pp.504-508
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• 2006

사슬성장의 핵심생성자리인 dimer (p-aminodiphenylamine)의 비율을 조절하여 아닐린 중합반응 과정에 첨가함으로서 oligomer에서 저분자량(Mw~40000)까지의 폴리아닐린 분자량이 조절되었다. 상대점도분자량 및 GPS 측정을 통하여 합성된 폴리아닐린의 분자량을 확인하였으며, UV, FT-IR, 전기전도도 등을 측정하여 분자량에 따른 폴리아닐린의 물리적, 화학적 성질을 조사하였다.

• 한국의류학회지
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• 제23권2호
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• pp.326-334
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• 1999

Polyaniline(PAn)-nylon 6 composite fabrics were prepared by immersing the nylon 6 fabrics in 100% distilled aniline for specified diffusion time and drawn out. Then the excess aniline on the fabric surface was blotted and successive polymerization was initiate by immersing them into oxidant and dopant solution for in situ polymerization of polyaniline. Consequently highly conductive PAn-nylon 6 composite fabrics could be obtained and the conductivity reaches as high as 10-2 S/cm. The maximum conductivity was obtained when the fabric was immersed in 100% aniline at 4$0^{\circ}C$ for 3hours and polymerization was proceeded in 0.25M ammonium peroxydisulfate solution at 5$^{\circ}C$ for 1hour.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.364-371
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• 2018

Enzyme polymerization is a benign process exploiting the unique activity of enzymes. In this study, a peroxidase-mimetic catalyst is demonstrated as an alternative to horseradish peroxidase (HRP) for the polymerization of aniline. The mimetic catalyst successfully catalyzes the polymerization of aniline monomers to produce polyaniline (PANI) in an aqueous solution. The PANI produced is rich of para-structure that is generally observed when HRP is used as a catalyst. Compared to HRP, the peroxidase-mimetic catalyst shows a considerably higher catalytic activity at neutral and weak basic conditions (pH >6.5) and at temperatures over $45^{\circ}C$, at which HRP is denatured.

• Bulletin of the Korean Chemical Society
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• 제10권5호
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• pp.459-462
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• 1989

The transition state (TS) structure for the reactions of phenacyl benzenesulfonates with N,N-dimethylanilines (DMA) is investigated using various selectivity parameters, especially with cross-interaction constants, ${\rho}_{ij}$, ${\beta}_{ij}$ and ${\lambda}_{ij}$. The trends in reactivity were similar to aniline series but the TS was found to be somewhat looser than that for aniline series. It was found that the RSP and BEP principle hold within the DMA series but are violated between two different reaction series with DMA and aniline.

• Bulletin of the Korean Chemical Society
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• 제11권6호
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• pp.546-552
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• 1990

Enthalpies of solution of aniline, pyridine and benzylamine in iso-dielectric mixtures of methanol with acetonitrile (AN), nitrobenzene (NB) and nitromethane (NM) have been measured calorimetrically. The solute-solvent interaction was analyzed using a model developed by Waghorne et al. and found that the relatively weak base, aniline, tended to behave anomalously, especially in the NB and NM binary systems by forming bidentate hydrogen bonds between the two-$NH_2$ hydrogens and the two-$NO_2$ oxygens. Pyridine and benzylamine were found to be preferentially solvated by methanol in all the binary mixtures.

• 대한금속재료학회지
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• 제47권2호
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• pp.91-98
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• 2009

The titania nanotubular layer for photocatalytic application was synthesized by anodization process in HF solution and the photocatalytic efficiencies of nanotubular film were evaluated by the decomposition rate of aniline blue. In order to facilitate the photocatalytic reaction, the electron acceptors such as potassium bromate, hydrogen peroxide and ammonium persulfate were added to aniline blue solution and the effects of electron acceptors on the dye degradation efficiency were evaluated. The results showed that the photocatalytic efficiency has markedly improved by adding the electron acceptors.