• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.664-667
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• 2009

We would like to show a measuring technique of azimuthal anchoring energy of the nematic liquid crystals. The electro-optical setup of liquid crystal cell, crossed polarizers and magnetic field was assumed. The planar or hybrid alignment cells were prepared. The director in the light entering substrate and the polarization of light was adjusted into parallel to the magnetic field. The director orientation of exit substrate and analyser maintained perpendicular to the magnetic field. As the magnetic field strength is increased, the director deviates from the easy axis and rotates to the field direction. We obtained an equation calculating the change of transmission with the field and measured experimentally the transmission. By comparing the calculating and experimental data, we obtained the azimuthal anchoring strength.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.1
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• pp.105-112
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• 2022

Copper (Cu)-based catalysts have been widely used in a methanol steam reforming (MSR) reaction for hydrogen production for air-independent propulsion (AIP) applications and their good catalytic activities have attracted much attention. However, the agglomeration of the catalytic active site Cu causes deteriorating the catalytic performance and suppression of Cu agglomeration is a crucial issue in the AIP applications that the MSR system is typically operated at 250-300℃ for a long time. R. Sakai et al. recently showed a computational study on the anchoring effect that reduces an agglomeration of active sites by doping in a supporter. In order to present the anchoring effect on 𝛾-Al₂O₃ supported Cu-based catalysts, in this study, the adsorption energies of Cu on X-doped (X=ruthenium, phosphorus, silicon) 𝛾-Al₂O₃ were calculated and Cu adsorption energy decreased due to a change of the electronic structure originated from doping, thereby proving the anchoring effect.

• Journal of Ocean Engineering and Technology
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• v.35 no.4
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• pp.305-312
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• 2021

There is a gradual increase in the need for energy charging in marine environments because of energy limitations experienced by electric ships and marine robots. Buoys are considered potential energy charging systems, but there are several challenges, which include the need to maintain a fixed position and avoid hazards, dock with ships and robots in order to charge them, be robust to actions by birds, ships, and robots. To solve these problems, this study proposes a smart buoy robot that has multiple thrusters, multiple docking and charging parts, a bird spike, a radar reflector, a light, a camera, and an anchor, and its mechanism is developed. To verify the performance of the smart buoy robot, the position control under disturbance due to wave currents and functional tests such as docking, charging, lighting, and anchoring are performed. Experimental results show that the smart buoy robot can operate under disturbances and is functionally effective. Therefore, the smart buoy robot is suitable as an energy charging system and has potential in realistic applications.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.87-87
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• 2010

Photoelectrochemical (PEC) systems are promising methods of producing H2 gas using solar energy in an aqueous solution. The photoelectrochemical properties of numerous metal oxides have been studied. Among them, the PEC systems based on TiO2 have been extensively studied. However, the drawback of a PEC system with TiO2 is that only ultraviolet (UV) light can be absorbed because of its large band gap (3.2 - 3.4 eV). Two approaches have been introduced in order to use PEC cells in the visible light region. The first method includes doping impurities, such as nitrogen, into TiO2, and this technique has been extensively studied in an attempt to narrow the band gap. In comparison, research on the second method, which includes visible light water splitting in molecular photosystems, has been slow. Mallouk et al. recently developed electrochemical water-splitting cells using the Ru(II) complex as the visible light photosensitizer. the dye-sensitized PEC cell consisted of a dye-sensitized TiO2 layer, a Pt counter electrode, and an aqueous solution between them. Under a visible light (< 3 eV) illumination, only the dye molecule absorbed the light and became excited because TiO2 had the wide band gap. The light absorption of the dye was followed by the transfer of an electron from the excited state (S*) of the dye to the conduction band (CB) of TiO2 and its subsequent transfer to the transparent conducting oxide (TCO). The electrons moved through the wire to the Pt, where the water reduction (or H2 evolution) occurred. The oxidized dye molecules caused the water oxidation because their HOMO level was below the H2O/O2 level. Organic dyes have been developed as metal-free alternatives to the Ru(II) complexes because of their tunable optical and electronic properties and low-cost manufacturing. Recently, organic dye molecules containing multi-branched, multi-anchoring groups have received a great deal of interest. In this work, tri-branched tri-anchoring organic dyes (Dye 2) were designed and applied to visible light water-splitting cells based on dye-sensitized TiO2 electrodes. Dye 2 had a molecular structure containing one donor (D) and three acceptor (A) groups, and each ended with an anchoring functionality. In comparison, mono-anchoring dyes (Dye 1) were also synthesized. The PEC response of the Dye 2-sensitized TiO2 film was much better than the Dye 1-sensitized or unsensitized TiO2 films.

• 한국정보디스플레이학회:학술대회논문집
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• 2003.07a
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• pp.619-621
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• 2003

We have presented in the paper preliminary results on physical characteristic parameters of a photopolymer LPPF 301 CP. The weak azimuthal anchoring energy (${\sim}5.0{\times}10^{-6}J/m^2$) of a photopolymer was measured by using a simple optical method. High pretilt up to $30^{\circ}$ has been achieved in the photoaligned cell by irradiating an obliquely incident UV light.

• Journal of Information Display
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• v.7 no.1
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• pp.12-18
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• 2006

We investigated the horizontal alignment properties such as surface morphology, pretilt angle, and polar and azimuthal anchoring energy of organic alignment material-coated surface treated by ion beam. In this investigation the energy and incident angle of ion beam were changed. We also fabricated an in-plane switching (IPS) cell by ion beam alignment. The results showed similar voltage-transmittance characteristics to those of a rubbed cell and better dark state.

• Bulletin of the Korean Chemical Society
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• v.28 no.6
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• pp.953-958
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• 2007

Anchoring quantum dots (QDs) onto thermodynamically stable, large band gap oxide semiconductors is a very important strategy to enhance their quantum yields for solar energy conversion in both visible and near-IR regions. We describe a general procedure for anchoring a few chalcogenide QDs onto the titanium oxide layer. To anchor the colloidal QDs onto a mesoporous TiO2 layer, linker molecules containing both carboxylate and thiol functional groups were initially attached to TiO2 layers and subsequently used to capture dispersed QDs with the thiol group. Employing the procedure, we exploited cadmium selenide (CdSe) and cadmium telluride (CdTe) quantum dots (QDs) as inorganic sensitizers for a large band gap TiO2 layer of dye-sensitized solar cells (DSSCs). Their attachment was confirmed by naked eyes, absorption spectra, and photovoltaic effects. A few QD-TiO2 systems thus obtained have been characterized for photoelectrochemical solar energy conversion.

• International journal of advanced smart convergence
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• v.13 no.2
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• pp.103-109
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• 2024

A nonlinear numerical analysis of orientation and velocity fields of the full Ericksen-Leslie theory for a nematic liquid crystal under shear flow is given. We obtained for the first time the three-dimensional orientation and two component velocity profiles evolutions for both in- and out-of-shear plane orientation anchorings. Complex evolution routes to steady state were found even for shear aligning nematic. As the Ericksen number increases monotonic evolution of velocity and orientation shifts towards multi-region nucleating director rotation growth with complex secondary flow generations. We found that contrary to the in-shear-plane anchorings like homeotropic or parallel anchorings, binormal anchoring gives rise to substantial non-planar three-dimensional orientation with nonzero secondary flow.

• Journal of the Korean Applied Science and Technology
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• v.16 no.1
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• pp.15-20
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• 1999

Photo-crosslinkable polyimide(PI) which contains CF3 moiety was synthesized. Polarized UV light transformed ketone group of PI to hydroxyl group, which was confirmed by IR and UV-visible spectroscopy. We investigated the dichroic UV-absorption before and after photo-reaction with linearly polarized light. In particular we have attempted to clarify the relationship between the anisotropy of surface region and surface azimuthal anchoring energy and knew that the anchoring energy of photo-alignment PI is comparable with that of mechanical rubbing.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.948-950
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• 2009

A few organosilicon compounds (OC) - both cyclic and linear siloxanes with different structure of the substituents - have been synthesized. Properties of the LC anchoring on OC films have been measured. The OC investigated provide the homogeneous planar alignment with LC tilt angle in the range from $0.7^{\circ}$ to $1.9^{\circ}$. An increase of the microrelief depth results in a small increase of the tilt angle. The azimuthal anchoring is better for the films of the OC without molecular microrelief or the OC comprising polar groups.