• 제목/요약/키워드: An equation of state

검색결과 986건 처리시간 0.033초

인력 포텐셜을 갖는 강체구형 기체에 대한 2-매개변수 상태방정식 (A New Two-Parameter Equation of State for Pure Gases of Hard Spheres with An Attractive Potential)

  • 정해영
    • 대한화학회지
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    • 제56권2호
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    • pp.207-211
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    • 2012
  • 강체구형입자에 대한 Carnahan-Starling식과 인력 포텐셜을 갖는 격자 모델을 이용하여 새로운 2-매개변수 상태식을 유도하였다. 이 식을 이용하여 압축인자를 계산하고 Nelson-Obert 압축인자도표와 비교하여 보았다. 그 결과 이 식은 Redlich-Kwong식과 평균적으로 비슷한 정도로 실험적인 압축인자도표와 일치한다는 것을 알 수 있다. 그런데 새 상태식에서 나타나는 매개변수와 항들은 Redlich-Kwong equation의 경우보다 분명한 물리적 의미를 갖고 있다.

고분자 액체에 대한 새로운 상태방정식 (A New Equation of State for Polymeric Liquids)

  • 정해영
    • 대한화학회지
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    • 제44권6호
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    • pp.587-591
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    • 2000
  • 고분자액체의 상태방정식을 구하기 위하여 많은 이론들이 제안되어 왔다. 이론들의 대부분은 cell, hole, free volume 또는 lattice 등의 개념에 근거를 두고 있다. 가장 성공적인 이론중의 하나로 평가받고 있는 것이 free volume의 개념을 근거로 한 Flory의 상태방정식 이론이다. 본 연구에서는 Flory 이론에서 사용한 van der Waals 포텐셜을 수정하여 새로운 상태방정식을 만들었다. 계산결과 새로운 상태방정식은 Flory 이론보다 PVT 실험값과 더 잘 일치함을 알 수 있었다.

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가변속 냉동시스템의 상태방정식 모델링과 최적제어 (State Equation Modeling and the Optimum Control of a Variable-Speed Refrigeration System)

  • 이단비;정석권;정영미
    • 설비공학논문집
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    • 제26권12호
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    • pp.579-587
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    • 2014
  • This paper deals with precise analytical state equation modeling of a variable speed refrigeration system (VSRS) for optimum control in state space. The VSRS is described as multi-input and multi-output (MIMO) system, which has two controlled variables and two control inputs. First, the Navier-Stokes equation and mass flow rate were applied to each component of the basic refrigeration cycle to build a dynamic model. The dynamic model, represented by a differential equation, was transformed into the state equation formula. Next, a full-order state observer was built to estimate all of the state variables to compose an optimum control system. Then, an optimum controller was designed to minimize an evaluation function that has input energy and control error. Finally, simulations and experiments were conducted to verify the validity of the proposed modeling and designed optimum controller to regulate target temperature and superheat in a 1RT oil cooler system. The results show that the proposed method, state equation modeling and optimum control, is efficient to ensure optimal control performance of the VSRS.

한계상태식의 3차 다항식 근사를 통한 구조물 신뢰도 평가 (Structure Reliability Analysis using 3rd Order Polynomials Approximation of a Limit State Equation)

  • 이승규;김성찬;김태욱
    • 한국전산구조공학회논문집
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    • 제26권3호
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    • pp.183-189
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    • 2013
  • 본 논문에서는 불확실성을 확률변수로 가정하고 구조물의 파손기준을 한계상태식(Limit State Equation)으로 정의하였다. 한계상태식을 Fleishman의 3차 다항식으로 근사하고 이론적인 확률 모멘트(Moments)를 계산하였다. Fleishman은 표준정규 분포 확률변수에 대해서만 3차 다항식을 제시하였으나, 본 논문에서는 이를 확장하여 베타, 감마, 균일 분포 등 다양한 확률 변수에 적용하였다. 확률 모멘트를 계산하기 위해서 누률(Cumulants)과 정규화된 한계상태식을 활용하였으며, 피어슨 시스템(Pearson System)을 통해 한계상태식의 확률분포를 근사하였다.

회전소자분해법에 의한 비선형시변 RLC 회로망의 상태방정식 구성에 대하여 (State Equation Formulation of Nonlinear Time-Varying RLC Network by the Method of Element Decomposition)

  • 양흥석;차균현
    • 전기의세계
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    • 제22권2호
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    • pp.40-44
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    • 1973
  • A method for obtaining state equation for nonlinear time-varying RLC networks is presented. The nonlinear time-varying RLC elements are decomposed by using Murata method to formulate nonlinear state equation. A nonlinear time-varying RLC network containing twin tunnel diode is solved as an example. In consequence of solving the examjple, simple methods are presented for revising the original network model so that the formulation of state equation is simplified.

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기체냉매의 PVT 거동을 나타내기 위한 상태방정식 (An Equation of State for the PVT Behavior of Gaseous Refrigerants)

  • 박경근
    • 설비공학논문집
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    • 제7권1호
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    • pp.98-111
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    • 1995
  • The objective of this work is to investigate the form of equations of state for specific refrigerants. In particular, equations of the extended van der Waals form have been studied. As a result, a new equation of state has been developed and tested over ranges of pressure and density up to 5 and 1.5 times critical, respectively. The equation of state separates the compressibility factor into two parts. One is the repulsive compressibility factor and the other is attractive. The former is in the same form of Carnahan-Starling's repulsive term with constant hard-sphere volume. The latter is based on a combination of two different functions linear to density. The equation of state developed here has 12 adjustable parameters and correlates PVT data successfully. All properties are in reduced forms.

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유한요소법과 상태방정식을 이용한 포워드 컨버터의 동작 특성 해석 (Characteristics Analysis of a Forward Converter by Finite Element Method and State Variables Equation)

  • 박성진;권병일;박승찬
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제48권9호
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    • pp.467-475
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    • 1999
  • This paper presents an analysis method of a forward converter, using both the finite element method considering the external circuit and a state variables equation. The converter operates at 50kHz and its one period is divided into two modes for the simplicity of the analysis. In the first mode, the switching transistor turns on and an input power is transferred into the load by the electromagnetic conversion action of a ferrite transformer. In the second mode, the switching transistor turns off and the stored energy in an inductor is delivered to the load, and the transformer core is demagnetized by the reset winding current. In this paper, time-stepping finite element method taking into account the on-state electrical circuit of the converter in used to analyze both the electrical circuit and electromagnetic field of the magnetic device during the first mode and the demagnetization period of the transformer core. Then a state variables equation for the circuit which the inductor current flows is constituted and solved during the second mode. As a result, the simulation results have been good agreement with the results obtained form experiment.

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BIFURCATIONS IN A DISCRETE NONLINEAR DIFFUSION EQUATION

  • Kim, Yong-In
    • 대한수학회보
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    • 제35권4호
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    • pp.689-700
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    • 1998
  • We consider an infinite dimensional dynamical system what is called Lattice Dynamical System given by a discrete nonlinear diffusion equation. By assuming the nonlinearity to be a general nonlinear function with mild restrictions, we show that as the diffusion parameter changes the stationery state of the given system undergoes bifurcations from the zero state to a bounded invariant set or a 3- or 4-periodic state in the global phase space of the given system according to the values of the coefficients of the linear part of the given nonlinearity.

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Molecular Spinless Energies of the Morse Potential Energy Model

  • Jia, Chun-Sheng;Cao, Si-Yi
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3425-3428
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    • 2013
  • We solve the Klein-Gordon equation with the Morse empirical potential energy model. The bound state energy equation has been obtained in terms of the supersymmetric shape invariance approach. The relativistic vibrational transition frequencies for the $X^1{\sum}^+$ state of ScI molecule have been computed by using the Morse potential model. The calculated relativistic vibrational transition frequencies are in good agreement with the experimental RKR values.

SHARP THRESHOLDS OF BOSE-EINSTEIN CONDENSATES WITH AN ANGULAR MOMENTUM ROTATIONAL TERM

  • Lu, Zhongxue;Liu, Zuhan
    • Journal of applied mathematics & informatics
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    • 제29권3_4호
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    • pp.901-908
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    • 2011
  • In this paper, we establish a sharp condition of global existence for the solution of the Gross-Pitaevskii equation with an angular momentum rotational term. This condition is related to the ground state solution of some steady-state nonlinear Schrodinger equation.