• Title/Summary/Keyword: An equation of state

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A New Two-Parameter Equation of State for Pure Gases of Hard Spheres with An Attractive Potential (인력 포텐셜을 갖는 강체구형 기체에 대한 2-매개변수 상태방정식)

  • Jung, Hae-Young
    • Journal of the Korean Chemical Society
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    • v.56 no.2
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    • pp.207-211
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    • 2012
  • Using Carnahan-Starling equation for hard spheres and a lattice model with an attractive potential, a new twoparameter equation of state for pure gases is derived. Using this equation, compressibility factors are calculated and compared with Nelson-Obert generalized compressibility factor charts. The results show that the agreement of this equation with the experimental Nelson-Obert charts is similar to that of Redlich-Kwong equation in the average. But parameters and terms of the new equation have physical meanings which are more definite than those of Redlich-Kwong equation.

A New Equation of State for Polymeric Liquids (고분자 액체에 대한 새로운 상태방정식)

  • Jung, Hae Young
    • Journal of the Korean Chemical Society
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    • v.44 no.6
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    • pp.587-591
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    • 2000
  • Many theories have been suggested to obtain an equation of state for polymeric liquids. Most of them are based on the concepts of cell, hole, free volume or lattice etc. One of the most succesful theories is an equation of state theory of Flory and his coworkers based on the concept of free volume. In this work, van der Waals potential used in Flory's theory was modified, giving a new equation of state for polymeric liquids. The calculated results showed that the new equation of state gave better agreement with experimental PVT data than Flory's theory.

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State Equation Modeling and the Optimum Control of a Variable-Speed Refrigeration System (가변속 냉동시스템의 상태방정식 모델링과 최적제어)

  • Lee, Dan-Bi;Jeong, Seok-Kwon;Jung, Young-Mi
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.26 no.12
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    • pp.579-587
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    • 2014
  • This paper deals with precise analytical state equation modeling of a variable speed refrigeration system (VSRS) for optimum control in state space. The VSRS is described as multi-input and multi-output (MIMO) system, which has two controlled variables and two control inputs. First, the Navier-Stokes equation and mass flow rate were applied to each component of the basic refrigeration cycle to build a dynamic model. The dynamic model, represented by a differential equation, was transformed into the state equation formula. Next, a full-order state observer was built to estimate all of the state variables to compose an optimum control system. Then, an optimum controller was designed to minimize an evaluation function that has input energy and control error. Finally, simulations and experiments were conducted to verify the validity of the proposed modeling and designed optimum controller to regulate target temperature and superheat in a 1RT oil cooler system. The results show that the proposed method, state equation modeling and optimum control, is efficient to ensure optimal control performance of the VSRS.

Structure Reliability Analysis using 3rd Order Polynomials Approximation of a Limit State Equation (한계상태식의 3차 다항식 근사를 통한 구조물 신뢰도 평가)

  • Lee, Seung Gyu;Kim, Sung Chan;Kim, Tea Uk
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.3
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    • pp.183-189
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    • 2013
  • In this paper, uncertainties and failure criteria of structure are mathematically expressed by random variables and a limit state equation. A limit state equation is approximated by Fleishman's 3rd order polynomials and the theoretical moments of an approximated limit state equation are calculated. Fleishman introduced a 3rd order polynomial in terms of only standard normal distiribution random variables. But, in this paper, Fleishman's polynomial is extended to various random variables including beta, gamma, uniform distributions. Cumulants and a normalized limit state equation are used to calculate a theoretical moments of a limit state equation. A cumulative distribution function of a normalized limit state equation is approximated by a Pearson system.

State Equation Formulation of Nonlinear Time-Varying RLC Network by the Method of Element Decomposition (회전소자분해법에 의한 비선형시변 RLC 회로망의 상태방정식 구성에 대하여)

  • 양흥석;차균현
    • 전기의세계
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    • v.22 no.2
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    • pp.40-44
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    • 1973
  • A method for obtaining state equation for nonlinear time-varying RLC networks is presented. The nonlinear time-varying RLC elements are decomposed by using Murata method to formulate nonlinear state equation. A nonlinear time-varying RLC network containing twin tunnel diode is solved as an example. In consequence of solving the examjple, simple methods are presented for revising the original network model so that the formulation of state equation is simplified.

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An Equation of State for the PVT Behavior of Gaseous Refrigerants (기체냉매의 PVT 거동을 나타내기 위한 상태방정식)

  • Park, K.;Sonntag, R.E.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.1
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    • pp.98-111
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    • 1995
  • The objective of this work is to investigate the form of equations of state for specific refrigerants. In particular, equations of the extended van der Waals form have been studied. As a result, a new equation of state has been developed and tested over ranges of pressure and density up to 5 and 1.5 times critical, respectively. The equation of state separates the compressibility factor into two parts. One is the repulsive compressibility factor and the other is attractive. The former is in the same form of Carnahan-Starling's repulsive term with constant hard-sphere volume. The latter is based on a combination of two different functions linear to density. The equation of state developed here has 12 adjustable parameters and correlates PVT data successfully. All properties are in reduced forms.

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Characteristics Analysis of a Forward Converter by Finite Element Method and State Variables Equation (유한요소법과 상태방정식을 이용한 포워드 컨버터의 동작 특성 해석)

  • Park, Seong-Jin;Gwon, Byeong-Il;Park, Seung-Chan
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.48 no.9
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    • pp.467-475
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    • 1999
  • This paper presents an analysis method of a forward converter, using both the finite element method considering the external circuit and a state variables equation. The converter operates at 50kHz and its one period is divided into two modes for the simplicity of the analysis. In the first mode, the switching transistor turns on and an input power is transferred into the load by the electromagnetic conversion action of a ferrite transformer. In the second mode, the switching transistor turns off and the stored energy in an inductor is delivered to the load, and the transformer core is demagnetized by the reset winding current. In this paper, time-stepping finite element method taking into account the on-state electrical circuit of the converter in used to analyze both the electrical circuit and electromagnetic field of the magnetic device during the first mode and the demagnetization period of the transformer core. Then a state variables equation for the circuit which the inductor current flows is constituted and solved during the second mode. As a result, the simulation results have been good agreement with the results obtained form experiment.

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BIFURCATIONS IN A DISCRETE NONLINEAR DIFFUSION EQUATION

  • Kim, Yong-In
    • Bulletin of the Korean Mathematical Society
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    • v.35 no.4
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    • pp.689-700
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    • 1998
  • We consider an infinite dimensional dynamical system what is called Lattice Dynamical System given by a discrete nonlinear diffusion equation. By assuming the nonlinearity to be a general nonlinear function with mild restrictions, we show that as the diffusion parameter changes the stationery state of the given system undergoes bifurcations from the zero state to a bounded invariant set or a 3- or 4-periodic state in the global phase space of the given system according to the values of the coefficients of the linear part of the given nonlinearity.

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Molecular Spinless Energies of the Morse Potential Energy Model

  • Jia, Chun-Sheng;Cao, Si-Yi
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3425-3428
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    • 2013
  • We solve the Klein-Gordon equation with the Morse empirical potential energy model. The bound state energy equation has been obtained in terms of the supersymmetric shape invariance approach. The relativistic vibrational transition frequencies for the $X^1{\sum}^+$ state of ScI molecule have been computed by using the Morse potential model. The calculated relativistic vibrational transition frequencies are in good agreement with the experimental RKR values.

SHARP THRESHOLDS OF BOSE-EINSTEIN CONDENSATES WITH AN ANGULAR MOMENTUM ROTATIONAL TERM

  • Lu, Zhongxue;Liu, Zuhan
    • Journal of applied mathematics & informatics
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    • v.29 no.3_4
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    • pp.901-908
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    • 2011
  • In this paper, we establish a sharp condition of global existence for the solution of the Gross-Pitaevskii equation with an angular momentum rotational term. This condition is related to the ground state solution of some steady-state nonlinear Schrodinger equation.