• 한국건설순환자원학회논문집
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• 제9권2호
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• pp.143-151
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• 2021

이 논문에서는 철근 부식을 촉진시킨 휨 부재의 4점 재하 재하실험을 통하여 철근 지름 및 부식률의 변화에 따른 처짐과 곡률 및 균열모멘트의 변화를 측정하는 실험을 수행하였다. 부식률은 중량비로 0%, 2%, 5% 및 10%로 변화하였으며, 철근의 지름은 각각 10mm, 13mm 및 19mm로 하였다. 실험 결과에 따르면 처짐에 대한 철근 지름의 영향은 크지 않았으며, 철근의 부식률이 2%를 초과하는 경우 부식되지 않은 철근을 가진 부재에 비하여 처짐이 증가하고 균열모멘트가 감소하는 경향을 확인하였다. 이는 부식된 철근에 대한 직접인발 시험과 동일한 경향을 보이는 것이며, 철근의 부식률이 크지 않은 경우 휨거동에 대한 부식의 영향이 크지 않음을 의미한다. 또한, 철근이 부식된 철근콘크리트 부재의 처짐량을 산정하기 위하여 부식률에 따른 균열모멘트의 변화를 반영하는 처짐 보정계수를 도출하고 실험결과를 통하여 그 적용성을 확인하였다.

• Corrosion Science and Technology
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• 제7권2호
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• pp.119-124
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• 2008

Steel is generally not corrosion resistant to water with formation of non protective rusts on its surface. Rusts are composed of iron oxides such as $Fe_3O_4$, $\alpha-$, $\beta-$, $\gamma-$and ${\delta}-FeOOH$. However, steel, particularly weathering steel containing small amounts of Cu, Ni and Cr etc., shows good corrosion resistance against rural, industrial or marine environment. Its corrosion rate is exceedingly small as compared with that of carbon steel. According to the exposure test results undertaken in outdoor environments, the atmospheric corrosion rate for weathering steel is only 1 mm for a century. Atmospheric corrosion for steels proceeds under alternate dry and wet conditions. Dry condition is encountered on steel surface on fine or cloudy days, and wet condition is on rainy or snowy days. The reason why weathering steel shows superior atmospheric corrosion resistance is due to formation of corrosion protective rusts on its surface under very thin water layer. The protective rusts are usually composed of two layer rusts; the upper layer is ${\gamma}-FeOOH$ termed as lepidocrocite, and inner layer is nano-particle ${\alpha}-FeOOH$ termed as goethite. This paper is aimed at elucidating the atmospheric corrosion mechanism for steel in comparison with corrosion in bulky water environment by use of empirical data.The summary is as follows: 1. No corrosion protective rusts are formed on steel in bulky water. 2. Atmospheric corrosion for steel is the corrosion under wetting and drying conditions. Corrosion and passivation occur alternately on steel surface. Steel, particularly weathering steel with small amounts of alloying elements such as Cu, Ni and Cr etc. enhances forming corrosion protective rusts by passivation.

• Corrosion Science and Technology
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• 제4권2호
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• pp.45-50
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• 2005

A 3% NaCl solution of 1 $dm^3$ circulated with 1.5 $dm^3/min$ by a pump for 24 h in the presence of magnetic field. An iron plate immersed in a $100cm^3$ of test solution for 24 h. The rest potential and pH on surface fixed after 3 h. Containing 0~120 ppm of Fe(II) ion, the dissolution in the magnetically treated solution rose comparing with that in the non-magnetically treated solution. The dissolution amount reached to maximum at 50 ppm, then fixed in the non-magnetically treated solution. When Fe(II) ion existed in the magnetically treated solution, dissolution accelerated a little. In the non-magnetic treated solution containing 10~125 ppm of Fe(III) ion existed, the dissolution accelerated. The dissolution amounts reached to maximum at 50 ppm, then decreased from maximum value. In the magnetically treated solution, the dissolution amounts reached to minimum until 50 ppm, then increased from minimum value. The dissolution amounts affected larger with increasing of magnetic flux density. Fe(II), Fe(III) ions and magnetic treatment affected to formation of $Fe(OH)_2$ and/or $Fe_3O_4$ films. The magnetically treated effects memorized about one month.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.657-662
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• 2003

In this study. a micro-corrosion model of steel in RC structure is established for micro-structure development in view to micro-mechanics and the model is composed of chloride penetration model and oxygen diffusion model to evaluate for corrosion rate and accumulated corrosion amounts. Also the model is composed of corrosion-cracking model for prediction of corrosion-cracking. The time and space dependent induced corrosion-cracking of RC structures including changes of corrosion rates and concentrations of chloride ion are simulated using the finite element analysis adopted the proposed model Then, results of the analysis are compared with test results for verification.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1043-1044
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• 2006

Compositional dependence of corrosion behavior of rapidly solidified Mg-rich Mg-Zn-Y alloys in NaCl aqueous solution has been investigated. Mg-Zn-Y ternary alloys containing small amounts of Zn exhibited low corrosion rate, although the $Mg_{98}Y_2$ (at. %) binary alloy showed severe corrosion with violet evolution of hydrogen. The alloy with highest corrosion-resistance was $Mg_{97.25}Zn_{0.75_Y_2$, its corrosion rate was about 1 mm year-1 in 0.17 M (1.0 wt. %) NaCl solution. $Mg_{97.25}Zn_{0.75}Y_2$ alloy exhibited passive region in anodic polarization curves when immersed in NaCl solution. Rapidly solidification and small amount of Zn addition may bring about an increase in electrochemical homogeneity of Mg-Zn-Y alloys, resulting in enhancement of corrosion resistance.

• Corrosion Science and Technology
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• 제17권2호
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• pp.60-67
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• 2018

The compounds associated with corrosion, in metallic archaeological samples of carbon steel of insular origin were evaluated to establish their degree of deterioration and structural damage against air pollution. The iron phases present in samples of archaeological artifacts were detected by Raman spectroscopy and confocal Raman microcopy. These samples mainly exhibited ing mainly ${\beta}$-FeO(OH) type goethite oxyhydroxides and small amounts of akaganeite ${\alpha}$-FeO(OH) lepidocrocite ${\gamma}$-FeO(OH) due to dominant chloride in a marine environment and non-stoichiometric oxyhydroxides Fe (II + / III +) as indicators of early corrosion. Some parts showed the presence of magnetic maghemite indicating high corrosion. ${\gamma}$-FeO(OH) is a precursor of phases associated with advanced marine corrosion. By studying its decomposition by Raman spectroscopy, it was synthesized with the following sequence: ${\gamma}-FeO(OH){\rightarrow}{\alpha}-FeO(OH)+{\gamma}-FeO(OH)$, ${\rightarrow}{\gamma}-Fe_2O_3+Fe_3O_4$. Ferric compounds provided evidence for the effect of intensity of laser on them, constituting a very useful input for the characterization of oxidation of iron in this type of artifacts. Thus, destructive analysis techniques should be avoided in addition to the use of small amounts of specimen.

• 한국해양공학회지
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• 제20권6호
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• pp.1-6
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• 2006

Corrosion of reinforcing steel bars is a major concern for ocean engineers when reinforced concrete structures are exposed to marine environments. Evaluating the degree of corrosion and corrosion-induced defects is extremely necessary to pursue a proper retrofit or rehabilitation plan for reinforced concrete structures. A promising inspection should be carried out for the evaluation, otherwise the retrofit or rehabilitation process would be useless. Nowadays, ultrasonic guided wave-based inspection techniques become quite promising for the inspection, mainly because of their long-range propagation capability and their sensitivity to different types of defects or conditions. Evaluating haw the guided waves response to the different types of defects or conditions is quite challenging and important. This study shows how surface conditions of reinforcing bars and a corrosion-induced defect, separation, affect guided wave propagation in reinforced concrete. Experiments and associated signal analysis show the sensitivity of guided waves to the surface conditions, as well as the amounts of separation at the interface between. concrete and steel bar.

• Corrosion Science and Technology
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• 제5권5호
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• pp.153-159
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• 2006

Austenitic stainless steels with addition of various amounts of Mo and W were evaluated in terms of corrosion and contact resistance to determine optimum alloy composition of metallic bipolar plate for PEMFC. The corrosion property was evaluated by both acid fume exposure test at $130^{\circ}C$ and by electrochemical polarization tests in $H_3PO_4$ solution at $80^{\circ}C$. Austenitic stainless steel with proper amount of Mo and W demonstrated not only good corrosion resistance but also low contact resistance. Analyses on the passive film show that partial substitution of Mo by W enhances passive film stability and repassivation property. Test results suggest that austenitic stainless steel with 2 wt%Mo and 4 wt%W has optimum composition for metallic bipolar plate used in PEMFC.

• 콘크리트학회논문집
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• 제11권6호
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• pp.129-135
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• 1999

Reinforced concrete structures are constructed under the basic assumption of perfect bonding between steel and concrete. The corrosion of steel in the reinforced concrete beams results in the excessive cracks and gradual deterioration of concrete. This paper are concerned about the slip characteristics of reinforced concrete between steel and concrete. The accelerated test by external power supply was conducted with the three corrosion rates in the laboratory. As a result, it was obtained as follows: (1) the yield strength of steel was reduced according to corrosion states. (2) the equivalent steel area should be considered for detailed analysis. (3) According to the use of corroded steel or not, slip amounts between concrete and steel in test beams increased as the corrosion rate increased. These results can be explained from the bond loss between concrete and steel in test beams.

• Corrosion Science and Technology
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• 제16권6호
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• pp.278-284
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• 2017

The effects of TIG welding and post-treatment procedures on the microstructure and the pitting corrosion resistance of welded lean duplex stainless steel S82441 were investigated. Autogenous TIG welding was used with different amounts of heat input and shielding gases such as Ar, and mixtures of $Ar-N_2$ and Ar-He. The addition of 5% to 15% of nitrogen to argon practically did not affect the level of the pitting corrosion resistance. However, the application of gas mixtures (50% Ar + 50% He) resulted in a significant decrease in pitting corrosion resistance. We found that increased current (200 A and 250 A) led to lower values of CPT of welds compared with welds obtained with 50 A, 100 A and 150 A. In addition, the removal of the weld surface layer (0.2 ~ 0.3 mm thickness) in most cases not only resulted in a significant increase in resistance to the pitting corrosion but also post-treatment of weld, implying that corrosion resistance depended on factors such as surface roughness or the presence of undesirable oxides.