• Title/Summary/Keyword: Ammonium chloride

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AN ANALYSIS OF THE CHIMNEY WALL

  • Yang, Young-Kyun
    • Korean Journal of Mathematics
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    • v.7 no.1
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    • pp.27-35
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    • 1999
  • As seen from the ammonium chloride experiment (Chen & Chen [1], Roberts & Loper [11], the interface near chimneys has an up-rising shape and we observe thickening of mush next to chimney. We analyze the thermal boundary layer around chimney that forms as the mush is cooled locally by the fluid rising through the chimney. We obtain solutions of the temperature, the solid fraction, and the pressure in the chimney wall. Also, our expression of the pressure shows that the fluid flow can require a huge pressure in order to pass through the chimney wall if its permeability is very small. We present a simple analytic description of the up-rising shape near the exit of the chimney, due to the fact that the comparatively solute (i.e. $NH_4Cl$ in the case of the ammonium chloride experiment)-rich fluid near the chimney tends to crystallize as it is chilled by the rising jet of cold fluid in the chimney.

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Visibility study in Seoul in Aug., 1993. (1993년 8월의 서울지역 시정 연구)

  • 이종훈;백남준;김용표;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.3
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    • pp.291-298
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    • 1995
  • An intensive field study was carried out during Aug. 1993 in Seoul to study the characteristics of summertime visibility and diurnal trend of ionic composition of ambient particles. A transmissometer, nephelometer with heated and unheated inlets, PM3 fine particle sampler, and cascade impactor were used to measure optical and particle properties of ambient air. During this study period, a weak smog episode has occurred. Light scattering by particles is the most dominant factor on total light extinction. The effect of light absorption by particles in Seoul is much higher than other major cities in U.S.A. throughout the summer and fall with relatively constant values. The effect of water on $b_{sp}$ was small during the period. The particle size distribution shows a typical bimodal one. Sulfate, ammonium, chloride, and nitrate are the major chemical species in fine fraction aerosols, about 30% of toral mass concentration. Concentraion of sulfate is higher during the daytime while those of nitrate and chloride are higher during the nighttime. Ammonium concentration is constant through the daytime.

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Crosslinked poly(vinylbenzyl trimethy ammonium chloride)-impregnated poly(ethylene) and poly(tetrafluoroethylene) composite membranes using for electrolysis process (전기투석공정을 위한 Poly(ethylene)과 poly(tetrafluoroethylene)다공성 필름을 이용한 가교된 poly(vinylbenzyl trimethyl ammonium chloride)복합막 제조)

  • Lee, Jung-Soo;Chang, Bong-Jun;Kim, Jeong-Hoon;Lee, Soo-Bok;Kang, Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2008.05a
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    • pp.180-184
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    • 2008
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On Compositional Convection in Near-Eutectic Solidification System Cooled from a Bottom Boundary

  • Hwang, In Gook
    • Korean Chemical Engineering Research
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    • v.55 no.6
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    • pp.868-873
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    • 2017
  • Natural convection is driven by the compositional buoyancy in solidification of a binary melt. The stabilities of convection in a growing mushy layer were analyzed here in the time-dependent solidification system of a near-eutectic melt cooled impulsively from below. The linear stability equations were transformed to self-similar forms by using the depth of the mushy layer as a length scale. In the liquid layer the stability equations are based on the propagation theory and the thermal buoyancy is neglected. The critical Rayleigh number for the mushy layer increases with decreasing the Stefan number and the Prandtl number. The critical conditions for solidification of aqueous ammonium chloride solution are discussed and compared with the results of the previous model for the liquid layer.

Purity Improvement of Calcium Lactate and Calcium Citrate Prepared with Shell of Anadarac tegillarca granosa (꼬막 패각으로 제조한 젖산칼슘과 구연산칼슘의 순도 향상에 대한 연구)

  • Kang mee-Sook;Soh Gowan-Soon;Shin Dong-Hwa
    • Journal of Food Hygiene and Safety
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    • v.20 no.3
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    • pp.128-133
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    • 2005
  • Ash of Anadarac tegillarca granosa shell was used for preparation of calcium lactate and calcium citrate, and improvement of their purity was carried out by using ammonium chloride process (ACP) and ammonium nitrate process (ACP). Purity of calcium lactate and calcium citrate made by the reaction of ash of Anadarac tegillarca granosa shell with lactic acid solution and with citric acid solution was 94.35-96.72 and $87.58-93.06\%$, respectively. However, purity of calcium lactate and calcium citrate prepared with purified calcium carbonate pre-purified from the ash of Anadarac fegiliarca granosa shell using ACP and ANP method was 99.53-100.34 and $99.32-99.88\%$, respectively. The purity of these calcium products were higher than those of calcium lactate and calcium citrate made with ash of Anadarac tegillarca granosa shell. Whiteness of calcium lactate and calcium citrate prepared with purified calcium carbonate pre-purified using ACP and ANP method was 94.8-98.5 and 99.4-101.5, respectively. Whiteness of these calcium products was higher than that of calcium lactate (91.8) and calcium citrate (92.9) made with the ash of Anadarac tegillarca granosa shell. Therefore, we estimated that calcium lactate and calcium citrate prepared with purified calcium carbonate using ACP and ANP method could be used potentially as a food additive for calcium supplement.

Toxicity of Disinfectants in Flounder Paralichthys olivaceus, Black Rockfish Sebastes pachycephalus and Black Sea Bream Acanthopagrus schlegelii (시판 소독제의 넙치 Paralichthys olivaceus, 조피볼락 Sebastes pachycephalus, 감성돔 Acanthopagrus schlegelii에 대한 독성)

  • Park, Kyung-Hee;Kim, Seok-Ryel;Kang, So-Young;Jung, Sung-Ju;Oh, Myung-Joo
    • Journal of Aquaculture
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    • v.21 no.1
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    • pp.7-12
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    • 2008
  • Toxicity of ten commercial disinfectants(hydrogen peroxide, sodium hypochlorite, chlorine dioxide, povidon iodine, formaldehyde, glutaraldehyde, quaternary ammonium compounds(QAC), didecyl dimethyl ammonium chloride(DDAC), ortho-dichlorobenzene, and copper sulfate) was measured by chinook salmon embryo-214 cell line and three fish species: flounder Paralichthys olivaceus, black rockfish Sebastes pachycephalus, and black sea bream Acanthopagrus schlegelii. The $LC_{50}$ levels of 24 hours acute toxicity with the ten disinfectants were tested in three species of fish. Effectiveness of ten chemical disinfectants were varied by each chemical as well as by species. Hydrogen peroxide showed the higest activity at 201, 269, and 139 ppm in the flounder, the black rockfish, and black sea bream, respectively. DDAC showed the lowest activity at 2.1, 1.0, and 1.5 ppm in the flounder, the black rockfish, and black sea bream, respectively. The highest variation was observed in copper sulfate by both the chemicals and the species.

Evaluation on Design Factors of Electrolytic Flotation Reactor by Measuring Polarization Curve (분극곡선 측정을 통한 전해부상조의 설계인자 평가)

  • Lim, Bong-Su;Jin, Jing-Zhu;Choi, Chan-Soo
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.244-250
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    • 2007
  • This study was carried out to obtain the optimum design factors for an eletrolytric flotation reactor. When the effluent of the leachate treatment facility was treated under the condition of 10 volts, 30 minutes, at the Al-Al electrode system; COD removal efficiency was 45%, and total phosphorus removal efficiency was 98%. The high removal efficiency was caused by the fact that phosphate was removed by leaching $Al^{3+}$ from two electrodes. The leachate containing high ammonium nitrogen concentration was treated by a batch test under the condition of 60 minutes reaction time and added chloride ion; ammonium nitrogen removal efficiency was 89%. This high efficiency was affected by added chloride ion to wastewater. To find the optimum current density and voltage of the leachate containing chloride ion (ratio of $Cl^-/NH_4-N$ is 11) a electrochemical polarization curve was used. These values were found to be $4.5mA/cm^2$ and about 2.1 V, respectively. When C-Al electrode system was used at a batch test, the total nitrogen removal efficiency was increased by 1.8 to 3.3 times, compared to Al-Al electrode system due to high $Cl_2$ gas production.

Effect of Chemical Forms of Nitrogen Fertilizers on Rice Growth and Soil Characteristics (시용(施用) 질소(窒素)의 화학적(化學的) 형태(形態)가 수도생육(水稻生育) 및 토양특성(土壤特性)에 미치는 영향(影響))

  • Yoo, Sun-Ho;Song, Kwan-Cheol;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.3
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    • pp.242-252
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    • 1984
  • A port experiment was conducted to compare the effect of chemical forms of nitrogen fertilizers on the rice growth and soil characteristics. The nitrogen fertilizers used for this study were ammonium sulfate, ammonium nitrate, ammonium chloride and urea. The results are summarized as follows. 1. The differences in pH of the soil and surface water between treatments during the first week after fertilizer application were great and the pH values were in the order of urea > ammonium nitrate > ammonium sulfate > ammonium chloride treatment. However the differences were insignificant after the first week. 2. The differences in pH of the air-dried soil somewhat increased and pH values were in the order of urea > ammonium nitrate > ammonium chloride > ammonium sulfate treatment. 3. Sulfur contents of the soil and the rice leaf and N content of the rice leaf were highest when ammonium sulfate was applied. But there were few differences between the treatments in total N content of the soil and in P, K, Ca and Mg contents of the soil and the rice leaf. 4. Number of tillers and dry matter weight of the rice plant were highest in ammonium sulfate plot throughout all the growing stages. 5. Number of panicle per hill was highest in ammonium sulfate plot, and this brought the highest grain yield in ammonium sulfate plot. The lowest grain yield in ammonium nitrate plot resulted from the lowest number of panicle per hill and ripened grain ratio.

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Preparation of Ultra Fine Ammonium Perchlorate Crystals (초미세 크기의 과염소산암모늄 결정체 제조)

  • 김준형;임유진
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.1
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    • pp.1-7
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    • 2004
  • The precipitation of ultra fine ammonium perchlorate(UFAP) crystals from the N-methyl pyrrolidone(NMP) solutions of ammonium perchlorate(AP) was studied. The characteristics of the precipitated crystals were investigated by means of scanning electron micrograph(SEM), X-ray diffraction(XRD), and thermogravimetric analysis(TGA). When chloroform, methylene chloride and toluene were the precipitants, the product crystals had a mean particle size less than 2$\mu\textrm{m}$. The crystallographical property and thermal decomposition behavior of the prepared UFAP were almost the same as those of the commercial AP.