• Title/Summary/Keyword: Ammonia removal rate

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Effect of Loading Rate in the Operation of DEPHANOX and Modified-DEPHANOX Processes (유입부하가 DEPHANOX 및 Modified-DEPHANOX 공정에 미치는 영향)

  • Ryu, Hong-Duck;Min, Kyung-Kook;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.24-31
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    • 2004
  • This study was initiated to evaluate the efficiencies of DEPHANOX and Modified-DEPHANOX, which were devoloped to enhance nitrogen removal efficiency in municipal wastewater treatment. In the results, removal efficiency of organic matters was not affected much by increased loading rate of organic matters which is contained in influent. The nitrogen removal efficiencies according to the loading rate of influent TN was decreased drastically in conditions of over $0.2kg/m^3{\cdot}day$, which is T-N loading rate, and the DEPHANOX process was affected more sensitively than the M-DEPHANOX was. When the temperature was altered from $25^{\circ}C$ to $16^{\circ}C$ at HRT 6hrs, the removal efficiency of ammonia nitrogen was still over 90% and it was concluded that both DEPHANOX and M-DEPHANOX were strong enough to endure temperature variation. Moreover, both processes showed over 90% in ammonia removal efficiencies in over HRT 5hrs, so it was concluded that they were strong in HRT variation. M-DEPHANOX process showed a higher value than DEPHANOX did in T-N removal efficiency to the extent of 4~21 %, which resulted from differency of denitrification rates and the biosorption efficiency of organic matter in both processes. In the condition of HRT less than 4hrs, concentrations of ammonia nitrogen contained in effluents and nitrification reactors, might be sensitively affected by biosorption efficiency of organic matters in first separation tank. In the effect of effluent nitrate concentration in phosphorus removal, the more effluent nitrate concentration was decreased, the more phosphorus removal efficiency was increased. This result is related to the decrease of concentration of effluent nitrate which resulted from nitrification inhibition by decreased HRT.

Application of Ferrate (VI) for Selective Removal of Cyanide from Plated Wastewater (도금폐수 중 시안(CN)의 선택적 제거를 위한 Ferrate (VI) 적용)

  • Yang, Seung-Hyun;Kim, Younghee
    • Clean Technology
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    • v.27 no.2
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    • pp.168-173
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    • 2021
  • The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.

Removal of Ammonia Nitrogen and Reduction of THMs in Low Temperature by BAC Pilot Plant (BAC Pilot Plant 를 이용한 겨울철 암모니아성 질소 제거 및 THMs 변화)

  • Kang, Eun-Jo;Seo, Young-Jin;Lee, Won-Kwon;Chun, Pyoung-Hee;Lee, Ji-Hyung;Yoon, Jung-Hyo;Kim, Dong-Youn
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.4
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    • pp.107-114
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    • 1995
  • The raw drinking water quality is getting worse because of the winter drought and the conventional treatment system is'nt suitable to obtain the satisfied quality of water. So, the advanced water system, BAC(Biological Activated Carbon) process is said to be effective to remove dissolved organics and ammonia nitrogen. In our study, the BAC pilot plant using Nak-dong river water is tested in low temperature. Following results are found from the study. The ammonia nitrogen removal rate of BAC system using wood-based carbon (PICABIOL) was 99% in $6^{\circ}C$ temperature. Chlorine dosage in wood-based BAC effluent was reduced to 67% of that in sand filtered wate. It resulted from the removal of ammonia nitrogen. Also, THM formed by chlorine addition in wood-based BAC effluent was decreased to 65% of that in sand filtered water. In the case of dual-filter, the removal efficiency of ammonia nitrogen was increased 30% more than in conventional sand filter. According to this result, the ammonia nitrogen load to BAC system could be lessened by the use of dual-filter.

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Towards a novel approach to improve drinking water quality at Dhaka, Bangladesh

  • Serajuddin, Md.;Chowdhury, Md. Aktarul Islam
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.136-142
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    • 2018
  • The river water source of Saidabad Surface Water Treatment Plant at Dhaka, Bangladesh, is deteriorated too much to be treated by conventional treatment process due to excessive ammonia pollution. In order to improve the raw water quality before it enters into the main treatment chain, a pilot study was conducted for pre-treatment of the raw water. The objective is to investigate the rate of reduction of ammonia using the Meteor pilot, a biological pretreatment system, which is a laboratory scale Moving Bed Biofilm Reactor with a nominal volume of hundred liters, filled with 50 L of Meteor 660 media. The reduction of ammonia was quite significant on average 73%, while the reduction of COD was in a range from 20 to 60%. The Meteor pilot was able to treat and nitrify the raw water and produce an effluent that respects the guarantee of ammonia < $4.0mg\;NH_3-N/L$ when the raw water ammonia concentration was < $15mg\;NH_3-N/L$. The study identified operating parameters necessary to achieve the desired goal of adequate ammonia removal. The study results would benefit a range of systems across the country by providing guidance on the design and operation of a biological pre-treatment system for ammonia removal.

Effect on the Hydrogen Peroxide in the Ozonation of Ammonia (오존에 의한 암모니아 산화시 과산화수소가 미치는 영향)

  • 박문숙;안재동;노봉오
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.1-7
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    • 2001
  • Ammonia is used in the manufacture of fertilizers, refrigerants, stabilizers and many household cleaning agents. These wide applications resulted in ammonia contamination in water. Ammonia can be removed from water by physical, biological, and chemical methods. Ozonation is effictive in the treatment of water with low concentration of ammonia. This study is undertaken to provide kinetic data for the ozonation of ammonia with or without hydrogen peroxide. The results were as follows; The destruction rate of ammonia increased gradually with the influent hydrogen peroxide concentration up to 0.23 mM and inhibited in the range of 0.23~11.4mM, and the maximum removal rate of ammonia achieved at 0.23mM of hydrogen peroxide, and the overall kinetics was first order. The combination effect of hydrogen and ozone to oxide ammonia in aqueous solution was better than ozone alone. The reacted ammonia was converted completely to nitrate ion.

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Bioaugmentation Treatment of Mature Landfill Leachate by New Isolated Ammonia Nitrogen and Humic Acid Resistant Microorganism

  • Yu, Dahai;Yang, Jiyu;Teng, Fei;Feng, Lili;Fang, Xuexun;Ren, Hejun
    • Journal of Microbiology and Biotechnology
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    • v.24 no.7
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    • pp.987-997
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    • 2014
  • The mature landfill leachate, which is characterized by a high concentration of ammonia nitrogen ($NH_3$-N) and humic acid (HA), poses a challenge to biotreatment methods, due to the constituent toxicity and low biodegradable fraction of the organics. In this study, we applied bioaugmentation technology in landfill leachate degradation by introducing a domesticated $NH_3$-N and HA resistant bacteria strain, which was identified as Bacillus cereus (abbreviated as B. cereus Jlu) and Enterococcus casseliflavus (abbreviated as E. casseliflavus Jlu), respectively. The isolated strains exhibited excellent tolerant ability for $NH_3$-N and HA and they could also greatly improved the COD (chemical oxygen demand), $NH_3$-N and HA removal rate, and efficiency of bioaugmentation degradation of landfill leachate. Only 3 days was required for the domesticated bacteria to remove about 70.0% COD, compared with 9 days' degradation for the undomesticated (autochthonous) bacteria to obtain a similar removal rate. An orthogonal array was then used to further improve the COD and $NH_3$-N removal rate. Under the optimum condition, the COD removal rate in leachate by using E. casseliflavus Jlu and B. cereus Jlu increased to 86.0% and 90.0%, respectively after, 2 days of degradation. The simultaneous removal of $NH_3$-N and HA with more than 50% and 40% removal rate in leachate by employing the sole screened strain was first observed.

Effect of an Additives on Simultaneous Removal of NOx, $So_2$by Corona Discharge (코로나 방전에 의한 NOx, $So_2$동시제거에서 첨가제의 영향)

  • 박재윤;고용술;이재동;손성도;박상현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.5
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    • pp.451-457
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    • 2000
  • Experimental investigations on the effect of two kinds of additives ; aqueous NaOH solution and ammonia(NH$_3$) for removal of NOx and SO$_2$ simultaneously by corona discharge were carried out. The simulated combustion flue gas was[NO(0.02[%])-SO$_2$(0.08[%])-$CO_2$-Air-$N_2$] Volume percentage of aqueous NaOH solution used was 20[%] and $N_2$flow rate was 2.5[$\ell$/min] for bubbling aqueous NaOH solution Ammonia gas(14.81[%]) balanced by argon was diluted by air. NH$_3$ molecular ratios(MR) based on [NH$_3$] and [NO+SO$_2$] were 1, 1.5 and 2.5 The vapour of aqueous NaOH solution and NH$_3$was introduced to the main simulated combustion flue gas duct through injection systems which were located at downstream of corona discharge reactor. NOx(NO+NO$_2$) removal rate by injecting the vapour of aqueous NaOH solution was much better than that by injecting NH$_3$however SO$_2$removal rate by injecting NH$_3$was much better than that by injecting the vapour of aqueous NaOH SO$_2$removal rate slightly increased with increasing applied voltage. When the vapour of aqueous NaOH solution and NH$_3$were simultaneously injection NOx and SO$_2$ removal rate were significantly increased.

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A Study on the Chemical Treatment Techniques of High Concentration Ammonia Nitrogen in Food Wastewater

  • Tae-Hwan JEONG;Su-Hye KIM;Woo-Taeg KWON
    • Journal of Wellbeing Management and Applied Psychology
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    • v.6 no.3
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    • pp.33-36
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    • 2023
  • Purpose: Since the food wastewater contains a high concentration of nitrogen, it is very important to find a way to efficiently remove it. Research design, data and methodology: A total of four experiments were conducted under different conditions to remove ammonia nitrogen present in the food wastewater. The experiment was designed by adding sodium hypochlorite to the raw food wastewater and varying conditions such as pH control, aeration/precipitation, and stirring. Results: The ammonia nitrogen removal rate in Experiment 1 was about 12% (sodium hypochlorite added), ammonia nitrogen increased about 4.7% in Experiment 2 (sodium hypochlorite added after aeration/precipitation in a bioreaction tank, stirring), and decreased about 52.5% (sodium hypochlorite added after controlling and stirring). Conclusions: When the concentration of sodium hypochlorite was high, ammonia nitrogen was best removed, and the pH was adjusted to 12, and sodium hypochlorite was added after stirring, and the removal was the second best. If the method of this study is further studied and developed, it can be basic data for ammonia nitrogen removal in the future.

Effect of F/R ratio of ASBR (Anaerobic Sequencing Batch Reactor) Process on Removal of the Organic Matters in Ammonia Stripped Swine Wastewater (ASBR(Anaerobic Sequencing Batch Reactor) 공정의 F/R비가 암모니아가 탈기된 축산폐수의 유기물 제거에 미치는 영향)

  • Whang, Gye-Dae;Cho, Young-Moo
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.687-694
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    • 2005
  • Lab-scale experiments have been carried out to investigate the effect of F/R ratio of ASBR (Anaerobic Sequencing Batch Reactor) process on the removal of the organic matters in ammonia stripped swine wastewater. Three ASBR inoculated with sludge mixed with granular sludge of UASB (Upflow Anaerobic Sludge Blanket) and anaerobic digested sludge of municipal wastewater treatment plant were operated. Ammonia stripped swine wastewater was used as influent. Prior to conducting the experiments with varied conditions, the effect of increasing organic loading rate from 2.34 to $5.79gTCOD_{Cr}/L$-day at a fixed F/R ratio of 0.1 on the organic removal efficiency has been studied during start-up period. As the result of the experiment, under the condition of varied organic loadings, less than $4.14gTCOD_{Cr}/L$-day, the removed efficiency $TCOD_{Cr}$ of the ASBR process is 83% resulted from the mean value of effluent $TCOD_{Cr}$, 9,125 mg/L during the start-up period. Then ASBRs were operated with F/R ratio of 0.024, 0.303 and 0.91 respectively. Organic loading rate was increased from 4.56 to $15.43gTCOD_{Cr}/L$-day to investigate the effects of F/R ratio and organic loading rate on the organic removal efficiency. As the result of the experiment, less than $6.23gTCOD_{Cr}/L$/L-day, F/R ratio haven't an effect on the organic removal efficiency and the mean removal efficiency of TSS, $TCOD_{Cr}$ and $SCOD_{Cr}$ was about 80%, 86% and 78% at the all of F/R ratio. But as organic loading rate was increased from 8.54 to $12.04gTCOD_{Cr}/L$-day at the F/R ratio of 0.024, the removal efficiency of $SCOD_{Cr}$ decreased from 71% to 63%. The range of decreased removal efficiency of $SCOD_{Cr}$ at the F/R ratio of 0.024 was much more higher than at the F/R ratio of 0.303, 0.91. Thus, as organic loading rate was increased, ASBRs were operated with high F/R ratio to obtain high removal efficiency.

Zeolite Filtration for Ammonium Nitrogen Removal in Drinking Water Treatment (정수처리에서 암모니아성질소 제거를 위한 제올라이트 여과)

  • 김우항;김충환
    • Journal of Environmental Science International
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    • v.12 no.3
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    • pp.281-286
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    • 2003
  • This study was conducted to evaluate the feasibility of ammonia removal by zeolite adsorption in drinking water treatment. In generally, drinking water treatment process is conducted coagulation/flocculation, sedimentation, sand filtration and disinfection. We tested feasibility with two method, one is powdered zeolite dosing to coagulation tank and the other is to substitute granular zeolite for sand of sand filter. In powdered zeolite test, raw water is used tap water with putting of 2 mg/l of NH$_4$$\^$+/-N. Filtration of granular zeolite was conducted with 80 cm of effective column high and 120 m/d of flow rate. At above 100 mg/1 of zeolite dosage, ammonia concentration was decreased below 0.5 mg/l of NH$_4$$\^$+/-N in powdered zeolite test. But, turbidity was increased to 30 NTU by powdered zeolite dosage. That turbidity was scarcely decreased in generally coagulant using condition in drinking water treatment. In granular zeolite test, ammonia was not detected in treated water until 8 days. This result suggest that using of granular zeolite in sand filter could be removal ammonia in winter. But we need regeneration at zeolite filtration for ammonia removal. So, it is to make clear that zeolite regeneration ability was compared KCl with NaCl. The result reveal that KCl was more excellent than NaCl. Optimum regeneration concentration of KCl was revealed 100 mM. Regeneration efficient was not increased at pH range 10∼12.5.