• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.42 no.4
• /
• pp.373-379
• /
• 2009

This study investigated oxygen consumption rate (OCR), $Q_{10}$ coefficient and ammonia excretion rate of the greenling, Hexagrammos otakii Jordan et Starks with the average body weight of 250 g in a semi-recirculated respiratory measuring system. The experiment was done under three different water temperatures (10, 15, $20^{\circ}C$) and five different ambient ammonia concentrations (0, 2.5, 5, 10, 20 mg/L). As the water temperature and ambient ammonia concentration increased the OCR has significantly increased (P<0.05). Given experimental conditions, the OCR of greenling were $50.8{\sim}159.4\;mg\;O_2\;kg^{-1}\;hr^{-1}$ and the relationship of water temperature (T) and ambient ammonia concentration (C) on the OCR were following: OCR = 41.3 - 1.87T - 7.38C + $0.463T^2$ + $0.66lC^2$ + 0.642TC - $0.011T^3$ - $0.010C^2$ - $0.031TC^2$ - $0.001T^2$C ($r^2$= 0.9226). $Q_{10}$ coefficients were $1.88{\sim}3.50$ for $10^{\circ}C$ to $15^{\circ}C$, $1.03{\sim}2.73$ for $15^{\circ}C$ to $20^{\circ}C$ and $1.40{\sim}1.90$ for $10^{\circ}C$ to $20^{\circ}C$, respectively. In general, the ammonia excretion rate tended to increase with increasing of the water temperature within normal ambient ammonia concentration. However, interestingly, it was observed that ammonia was absorbed rather than excreted above the ambient ammonia concentration of $2.5\;mg\;L^{-1}$, regardless of the water temperature. Thus, the largest ammonia absorption rate (AAR) was obserbed at the level of $98.4\;mg\;TAN\;kg^{-1}\;hr^{-1}$. The relationship ambient ammonia concentration (C) on AAR was following: Y = 1.61 + $10.9X^{0.7}$ ($r^2$ = 0.889).

• Korean Journal of Environmental Biology
• /
• v.39 no.1
• /
• pp.100-107
• /
• 2021

Along with an increase in the frequency of high-concentration fine particulate matter in Korea, interest and research on ammonia (NH₃) are actively increasing. It is obvious that agriculture has contributed significantly to NH₃ emissions. However, studies on the long-term effect of fertilizer use on the ambient NH₃ concentration of agricultural land are insufficient. Therefore, in this study, NH₃ concentration in the atmosphere of agricultural land was monitored for 11 months using a passive sampler. The average ambient NH₃ concentration during the total study period was 2.02 ㎍ m^-3 and it was found that the effect of fertilizer application on the ambient NH₃ concentration was greatest in the month immediately following fertilizer application (highest ambient NH₃ concentration as 11.36㎍ m^-3). After that, it was expected that the NH₃ volatilization was promoted by increases in summer temperature and the concentration in the atmosphere was expected to increase. However, high NH₃ concentrations in the atmosphere were not observed due to strong rainfall that lasted for a long period. After that, the ambient NH₃ concentration gradually decreased through autumn and winter. In summary, when studying the contribution of fertilizer to the rate of domestic NH₃ emissions, it is necessary to look intensively for at least one month immediately after fertilizer application, and weather information such as precipitation and no-rain days should be considered in the field study.

• Journal of Biosystems Engineering
• /
• v.28 no.3
• /
• pp.225-230
• /
• 2003

This study was carried out to analyze the environmental variation of layer house at Iowa State in the USA. The analyzed seasons for this study were summer and winter. Analyzing factors are inside temperature and relative humidity, carbon dioxide concentration, ammonia concentration and emission. All factors were collected every 30 second from each house with portable monitoring units. In this study, two types of laying hen houses were monitored at the same season. One was a manure belt house, the other was a high-rise house. In order to estimate the ventilation rates of the laying hen houses, carbon dioxide concentration balance was used in this study. Ammonia concentrations and emission rates of the manure belt house are much lower than those of the high rise house. Daily mean ammonia concentrations in the manure belt house and high-rise house ranged from 3 to 7 ppm and 5 to 34 ppm, respectively. The daily ammonia emission rates averaged 0.68g/h$\cdot$500kg and 0.73g/h$\cdot$500kg for the manure belt house and 0.93g/h$\cdot$500kg and 2.89g/h$\cdot$500kg for the high-rise house in summertime and wintertime, respectively. Summertime is associated with much higher ammonia emission rates than wintertime because of much higher ventilation rates and ambient air temperature, even though the concentrations may be lower.

• Journal of Korean Society for Atmospheric Environment
• /
• v.24 no.1
• /
• pp.43-54
• /
• 2008

Management and control of ammonia at the sources and ambient largely depend on sampling and measurement techniques. Good sampling and measurement techniques provide high quality data. The main purpose of the study is compare the analytical characteristics of the Indolphenol method which is one of the standard method in Korea with automatic analyzers for continued measuring gaseous ammonia. For comparison with other analytical methods, the verification test was designed to evaluate performance parameters; linearity, absorption efficiency, reproducibility and repeatability test, accuracy, and response time test. $R^2$ of calibration curve using IPM and CLM was very high (value is 1.000), but for EcSM $R^2$ value was estimated to be lower than IPM and CLM (as 0.991). The RSD of the CLM ranged from 0.1 to 2.3% over the nine concentration levels measured, %Ds was 0.1 to 10.7%, and average RA over all the measurements was 3.3%. The RSD of IPM and EcSM was ranged from 1.0 to 8.1, 3.9 to 14.0 respectively, and average RA were 8.71, 4.9% respectively. Rise in response times of EcSM was estimated to be 1 minute. It is found to be more sensitive than response time (which ranged from 2 to 9 minute) of CLM. For ammonia concentration measured using the IPM and the CLM from the same ammonia source, linear regression of IPM versus CLM show a slope of 0.805, an intercept of 637 ppb, and $R^2$ of 0.868.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.6
• /
• pp.2039-2044
• /
• 2011

A semi-continuous and automated method for quantifying atmospheric ammonia at the parts per billion level has been developed. The instrument consists of a high efficiency diffusion scrubber, an electrolytic on-line anion exchange device, and a conductivity detector. Water soluble gases in sampled air diffuse through the porous membrane and are absorbed in an absorbing solution. Interferences are eliminated by using an anion exchange devises. The electrical conductivity of the solution is measured without chromatographic separation. The collection efficiency was over 99%. Over the 0-200 ppbv concentration range, the calibration was linear with $r^2$ = 0.99. The lower limit of detection was 0.09 ppbv. A parallel analysis of Seoul air over several days using this method and a diffusion scrubber coupled to an ion chromatography system showed acceptable agreement, $r^2$ = 0.940 (n = 686). This method can be applied for ambient air monitoring of ammonia.

• Asian-Australasian Journal of Animal Sciences
• /
• v.27 no.8
• /
• pp.1211-1218
• /
• 2014

Higher concentrations of ammonia ($NH_3$) and carbon dioxide ($CO_2$) in animal barns can negatively affect production and health of animals and workers. This paper focuses on measurements of summer concentrations of ammonia ($NH_3$) and carbon dioxide ($CO_2$) in a naturally ventilated laying henhouse located at an egg production facility in Bursa region, western Turkey. Also, indoor and ambient environmental conditions such as temperature and relative humidity were measured simultaneously with pollutant gas concentrations. The average $NH_3$ concentrations during summer of 2013 was 8.05 ppm for exhaust and 5.42 ppm for inlet while average $CO_2$ concentration was 732 ppm for exhaust and 625 ppm for inlet throughout summer. The overall minimum, average and maximum values and humidity were obtained as $16.8^{\circ}C$, $24.72^{\circ}C$, and $34.71^{\circ}C$ for indoor temperature and 33.64%, 63.71%, and 86.18% for relative humidity. The lowest exhaust concentrations for $NH_3$ and $CO_2$ were 6.98 ppm and 609 ppm, respectively. They were measured in early morning at the maximum diurnal ventilation rate in July 2013 and August 2013. The highest concentrations were 10.58 ppm for $NH_3$ and 904 ppm for $CO_2$ recorded in the afternoon when the ventilation rate was the lowest in June 2013.

• Asian Journal of Atmospheric Environment
• /
• v.4 no.1
• /
• pp.55-61
• /
• 2010

The sensitivity of aerosol light extinction coefficient to the aerosol chemical composition change is estimated by (1) calculating the aerosol water content and chemical concentrations by a gas/particle equilibrium model and (2) calculating the aerosol light extinction coefficient by a Mie theory based optical model. The major chemical species are total (gas and particle phase) sulfuric acid, total nitric acid, and total ammonia which are based on the measurement data at Seoul and Gosan. At Seoul, since there were enough ammonia to neutralize both total sulfuric acid and total nitric acid, the dry ionic concentration is most sensitive to the variation of the total nitric acid level, while the total mass concentration (ionic concentration plus water content) and thus, the aerosol light extinction coefficient are primarily determined by the total sulfuric acid. At Gosan, since the concentration of ambient sulfuric acid was the highest among the inorganic species, sulfate salts determined aerosol hygroscopicity. Thus, both ionic and total mass concentration, and resultant aerosol light extinction coefficient are primarily determined by the sulfuric acid level.

• Korean Journal of Ichthyology
• /
• v.29 no.1
• /
• pp.13-21
• /
• 2017

We investigated that changes of survival rate and hematological factors in sevenband grouper (Epinephelus septemfasciatus), exposed to ammonia. First, the fish was exposed and was observed survival rate. We observed the survival rate of the fish when exposed at each ammonia concentrations (0, 0.35, 0.4, 0.5, 0.8 mg/L, $NH_3$) for 96 hours. The 96-h $LC_{50}$ (lethal ambient concentration for 50% of the population) of $NH_4^+$ and un-ionized ammonia ($NH_3$) for sevenband grouper were 26.7 and 0.6 mg/L, respectively. Secondly, we exposed the fish to 96-h $LC_{50}$ ammonia concentration (0.6 mg/L) for 96 hours, then sampled the blood of groupers for analysis of cortisol, glucose, $NH_3$, GOT, GPT, total protein (TP), electrolytes ($Na^+$, $Cl^-$) and osmolality in plasma. The plasma cortisol, glucose, GOT and GPT were increased with increasing of elapsed time and ammonia concentration. In addition, the $NH_3$ and total protein in plasma were significantly increased to 12 hours exposed to ammonia, and then decreased. But, the values were significantly higher than the control. The plasma electrolytes ($Na^+$, $Cl^-$) and osmolality were decreased with increasing of elasped time. The results in the present study suggest that the continuous exposure of ammonia to juveniles of sevenband grouper may be a stressor and negative influence.

• Journal of Sensor Science and Technology
• /
• v.8 no.1
• /
• pp.24-31
• /
• 1999

Ammonia gas sensors were fabricated with ZnO-based thin films grown by RF-magnetron sputtering method. The films which were doped with $MoO_3$ catalysts of various weight percents were grown in different sputtering gases to fabricate the sensors with a high sensitivity, low working temperature and rapid response time. To improve electrical stability, the films were aged in various conditions. The sensors doped with the catalysts and grown in oxygen sputtering gas showed the improvement of sensitivity. These exhibited the increase of surface carrier concentration and electron mobility. The sensor with 0.875wt.% $MoO_3$ catalysts showed the maximum sensitivity of 70 in ammonia gas concentration of 160 ppm at a working temperature of $300^{\circ}C$. The sensor which is aged at $330^{\circ}C$ for 72hrs in oxygen ambient exhibited tourer sensitivity of 57, but more stable properties, excellent linearity.

• Journal of Environmental Impact Assessment
• /
• v.21 no.5
• /
• pp.695-705
• /
• 2012

The purpose of this study is to investigate concentration level and characteristics of malodour substances generated from landfill site in C city. Also, it is tried to predict distribution of concentration level using ISCST3 model around landfill site. From the results, it can be confirmed that twelfth-class malodour substances such as ammonia, methyl mercaptan, hydrogen sulfide, dimethyl sulfate, dimethyl disulfate, toluene, acetaldehyde, styrene, propionaldehyde, butylaldehyde, n-Valeraldehyde, xylene were generated from landfill site. The levels of the malodour substances were lower than that of permeable concentration regulated by odor control law in Korea. However, the concentration of malodour substances including methyl mercaptan, hydrogen sulfide, acetaldehyde, and propionaldehyde exceeded threshold limit value(TLV). It was seemed that these substances caused the problem of offensive odor around circumstance of landfill. The concentration of malodour substances was higher in slant than in upper part of landfill. The concentrations of malodour substances measured at night time were shown higher level than those at night time because atmospheric condition was stable at night time. It showed that the concentration of malodour substances were higher in spring. The results of atmospheric diffusion model predicted that tolerance limit level of hydrogen sulfide and methyl mercaptan was detected within nearly 5km from the boundary of landfill.