• Title/Summary/Keyword: Aluminum particles

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Immobilization of Thermomyces lanuginosus Xylanase on Aluminum Hydroxide Particles Through Adsorption: Characterization of Immobilized Enzyme

  • Jiang, Ying;Wu, Yue;Li, Huixin
    • Journal of Microbiology and Biotechnology
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    • v.25 no.12
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    • pp.2016-2023
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    • 2015
  • Xylanase plays important roles in a broad range of industrial production as a biocatalyst, and its applications commonly require immobilization on supports to enhance its stability. Aluminum hydroxide, a carrier material with high surface area, has the advantages of simple and low-cost preparation and resistance to biodegradation, and can be potentially used as a proper support for xylanase immobilization. In this work, xylanase from Thermomyces lanuginosus was immobilized on two types of aluminum hydroxide particles (gibbsite and amorphous Al(OH)3) through adsorption, and the properties of the adsorbed enzymes were studied. Both particles had considerable adsorptive capacity and affinity for xylanase. Xylanase retained 75% and 64% of the original catalytic activities after adsorption to gibbsite and amorphous Al(OH)3. Both the adsorptions improved pH and thermal stability, lowered activation energy, and extended lifespan of the immobilized enzyme, as compared with the free enzyme. Xylanase adsorbed on gibbsite and amorphous Al(OH)3 retained 71% and 64% of its initial activity, respectively, after being recycled five times. These results indicated that aluminum hydroxides served as good supports for xylanase immobilization. Therefore, the adsorption of xylanase on aluminum hydroxide particles has promising potential for practical production.

A Study on Combustion Characteristics of Paraffin Blended Fuel on Aluminum Particle Size (알루미늄 입자 크기에 따른 파라핀 혼합연료의 연소 특성 연구)

  • Ko, Soohan;Han, Seongjoo;Ryu, Sunghoon;Kim, Jinkon;Moon, Heejang;Kim, Junhyung;Ko, Seungwon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.791-796
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    • 2017
  • In this study, the combustion characteristics of paraffin blended fuel on aluminum particle size were investigated. The combustion experiments were carried out using aluminum particles with an average particle size of 100 nm and $8{\mu}m$ and microcrystalline paraffin wax (Sasol 0907). A series of comparison was conducted on the regression rate, the pressure curve and the characteristic velocity of pure paraffin and paraffin blended fuels with aluminum particles. It was found that the micro-sized particles enhance the regression rate as the oxidizer mass flux increased. However, the nano-sized particles decrease the regression rate as the oxidizer mass flux is increased.

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Development of aluminum powder feeding system (알루미늄입자의 유체화, 이송 및 점화에 대한 연구(I))

  • Lee, Sunkey;Kweon, Suhyeon;Lee, Byeong-Jun;Song, Dong Joo;Lee, Ji Hyung
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.241-243
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    • 2012
  • Experiments were conducted to get the design concepts for the continuous aluminum particle feeding system. Two opposed cylinders were used. Aluminum particles in one cylinder were ejected to the air by the supplying gas and the pressure of the other cylinder. It was not possible to eject more aluminum mass flowrate than that of gas if particles were just thrust by the pressure difference between two cylinders. Aluminum particle/air mixture in the flow system was successfully ignited by the electric spark.

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Surface modified rice husk ceramic particles as a functional additive: Improving the tribological behaviour of aluminium matrix composites

  • Cheng, Lehua;Yu, Dongrui;Hu, Enzhu;Tang, Yuchao;Hu, Kunhong;Dearn, Karl David;Hu, Xianguo;Wang, Min
    • Carbon letters
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    • v.26
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    • pp.51-60
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    • 2018
  • An electroless deposition method was used to modify the surface properties of rice husk ceramic particles (RHC) by depositing nano-nickel on the surface of the RHC (Ni-RHC). The dry tribological performances of aluminum matrix composite adobes containing different contents of RHC and Ni-RHC particles have been investigated using a micro-tribometer. Results showed that the Ni-RHC particles substantially improved both the friction and wear properties of the Ni-RHC/aluminum matrix adobes. The optimal concentration was determined to be 15 wt% for both the RHC and Ni-RHC particles. The improvements in the tribological properties of aluminum adobes including the Ni-RHC were ascribed to friction-induced peeling off of Ni coating and formation of protection layer on the wear zone, both of which led to low friction and wear volume.

A STUDY ON THE BOND STRENGTH OF HEAT-CURING ACRYIC RESIN BONDED TO A SURFACE OF CASTED ALLOY (주조 금속 표면과 열 중합 수지 표면간의 결합 강도에 관한 연구)

  • Lee, Yong-Seok;Chang, Ik-Tae
    • The Journal of Korean Academy of Prosthodontics
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    • v.34 no.3
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    • pp.620-631
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    • 1996
  • Bonding of resin to cast alloy has traditionally been provided by mechanical retention. But, chemical bonding methods such as silicoating, tin plating, heat treatment, application of 4-META adhesives, have been developed to overcome the problems of the mechanical bonding methods. Silicoating has been used availaby in fixed prosthodontics, but is also reported to be used in removable prosthodontics. The aim of this study is to measure the tensile bond strength between resin and metal, and compare the effect of the type of metal and the grain size of the aluminum oxide on the bond strength, after metal surface roughening, coating of the opaque resin, and curing of heat-curing resin were performed. The test groups were divided into 4 groups according to the cast alloys and the aluminum oxide particles used. Group 1 : Type 4 gold alloy(DM66) blasted with $$50{\mu}m\;Al_{2}O_3$$ Group 2 : Type 4 gold alloy(DM66) blasted with $$250{\mu}m\;Al_{2}O_3$$, Group 3 : Co-Cr alloy(Nobilium) blasted with $$50{\mu}m\;Al_{2}O_3$$ Group 4 : Co-Cr alloy(Nobilium) blasted with $$250{\mu}m\;Al_{2}O_3$$ * 10 test specimens were made on each group. The specimens were thermocycled, and Instron Universal testing machine was used to measure the tensile bond strength of the finished specimens. The results were as follows : 1. Bond strengths showed that the group of gold alloy blasted with $250{\mu}m$ aluminum oxide particle had higher bond strength, and the group of gold alloy blasted with $50{\mu}m$ aluminum oxide particles had lower bond strength than any of the other groups. 2. Gold alloy had significantly higher bond strength when blasted with $250{\mu}m$ aluminum oxide particles than $50{\mu}m$, but. Co-Cr alloy showed no statistically significant difference between the two particle sizes. 3. When blasted with $50{mu}m$ aluminum oxide particles, Co-Cr alloy showed significantly higher bond strength than gold alloy. And, when blasted with $250{\mu}m$ aluminum oxide particles, gold alloy had significantly higher bond strength than Co-Cr alloy. 4. On the examination of the fractured sites, only the group of Co-Cr alloy blasted with $50{\mu}m$ aluminum oxide particles showed a part of residual opaque resin, but all the samples of the other groups fractured between the resin and the metal.

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Aluminum ignition in laser-generated aluminum particles in high temperature and high pressure environment (고온 고압 환경에서 레이저를 이용한 알루미늄 입자 생성과 점화)

  • Lee, Kyung-Cheol;Taira, Tsubasa;Koo, Goon Mo;Lee, Jae Young;Park, Jeong Su;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.101-103
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    • 2012
  • Characteristic of aluminum ignition under high temperature and high pressure is studied using lasers. The laser ablation method is used to generate aluminum particles exposed to a high pressure by using a nanosecond pulsed laser where the range of ablation pressure varies between 0.35 and 2.2 GPa. A $CO_2$ laser is used to supply radiative heat to the aluminum target surface for providing high temperature ranging between 5000~9300 Kelvin. The ignition is confirmed using spectroscopy analysis of AlO vibronic band 484 nm wavelength. Also the radiative temperature is measured in various high pressure range for tracing the ignition temperature in high pressure conditions.

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Recycling Technology of Aluminum UBC To Can Body Sheets

  • Lim, Cha-Yong;Kang, Seuk-Bong
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.173-178
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    • 2001
  • The materials processing factors such as remelting and casting, heat treatment and microstructure, sheet rolling and can body forming in the aluminum can-to-can recycling procedure have been investigated. Aluminum used beverage can(UBC) was remelted together with virgin aluminum. The ceramic filter was used during casting to remove large impurities. As-cast microstructure was composed of large intermetallic compound (mainly $\beta$ -phase) distributed in the aluminum matrix. By heat treatment, $\beta$ -phase was transformed to $\alpha$ -phase which was also formed from $Mg_2$Si particles. The heat treated ingots were hot-rolled at 48$0^{\circ}C$ and cold-rolled to thin sheets. Can making from this thin sheets was successful and earing was measured after can making. There was a critical cold reduction rate for minimum earing. Some cracks were initiated from the impurity particles which was not removed during filtering.

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Spark Plasma Sintering Behavior and Heat Dissipation Characteristics of the Aluminum Matrix Composite Materials with the Contents of Graphite (흑연 함량에 따른 알루미늄 기지 복합재료의 방전플라즈마소결 거동 및 방열 특성)

  • Kwon, Hansang;Park, Jehong;Joo, Sungwook;Hong, Sanghwui;Mun, Jihoon
    • Journal of Powder Materials
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    • v.23 no.3
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    • pp.195-201
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    • 2016
  • Composite materials consisting of pure aluminum matrix reinforced with different amounts of graphite particles are successfully fabricated by mechanical ball milling and spark plasma sintering (SPS) processes. The shrinkage rates of the composite powders vary with the amount of graphite particles and the lowest shrinkage value is observed for the composite with the highest amount of graphite particles. The current slopes of time increase with increase in the amount of graphite particles whereas the current slopes of temperature show the opposite trend. The highest thermal conductivity is achieved for the composite with the least amount of graphite particles. Therefore, the thermal properties of the composite materials can be controlled by controlling the amount of the graphite particles during the SPS process.

Property Evaluation of HVOF Sprayed Multi-walled Carbon Nanotube Aluminum Composite Coatings (고속 화염 용사를 통하여 형성된 다중벽 탄소 나노튜브 알루미늄 복합소재 코팅의 특성 평가)

  • Kang, Ki-Cheol;Park, Hyung-Kwon;Lee, Chang-Hee
    • Journal of the Korean institute of surface engineering
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    • v.45 no.1
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    • pp.1-7
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    • 2012
  • Multi-walled carbon nanotube (MWCNT) aluminum composite powders were deposited to form coatings using a high velocity oxygen fuel (HVOF) spraying process. High thermal energy and contact with atmospheric oxygen were supplied as the MWCNT aluminum composite particles were exposed to a gas flow field at high temperature (${\sim}3.0{\times}10^3$ K) during HVOF spraying. As a result, the particles underwent full or partial melting and rapid solidification due to the high thermal energy, and the exposure to oxygen induced the interfacial reaction of MWCNTs within the particle. The electrical and mechanical properties of MWCNT aluminum composite coatings were evaluated based on microstructure analysis. Electrical resistivity, elastic modulus, and micro-hardness, of the MWCNT aluminum composite coatings were higher than those of pure aluminum coating. The contribution of MWCNTs to the aluminum matrix can be attributed to their high electrical conductivity, dispersion hardening and anchoring effects. The relationship among the properties and the interaction of the MWCNTs with the aluminum matrix is discussed.

Thermal degradation properties of blue emitting phosphor particles prepared by the spray pyrolysis for PDP (분무열분해공정에서 제조된 PDP용 청색형광체의 열화특성)

  • Kang, Yun-Chan;Lee, Dong-Youl;Park, Hee-Dong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1060-1062
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    • 2002
  • Spherical and dense BAM phosphor particles were prepared by spray pyrolysis. The key idea of dense BAM particles is to lead gelation in droplets, which was successfully achieved by using the aluminum polycation as the precursor solution for the spray pyrolysis. The BAM phosphor particles prepared by spraying the aluminum polycation solution have completely spherical shape and dense structure. When directly applied to make phosphor film on the glass by the screen-printing method, the prepared spherical BAM phosphor particles showed better packing density and surface morphology than that of commercial one, which has irregular shape and large particle size. It was also found that the thermal degradation in the photoluminescence intensity for dense and spherical BAM particles was less than that of commercial one.

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