• 제목/요약/키워드: Aluminum(Al)

검색결과 2,475건 처리시간 0.195초

Immobilization of Thermomyces lanuginosus Xylanase on Aluminum Hydroxide Particles Through Adsorption: Characterization of Immobilized Enzyme

  • Jiang, Ying;Wu, Yue;Li, Huixin
    • Journal of Microbiology and Biotechnology
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    • 제25권12호
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    • pp.2016-2023
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    • 2015
  • Xylanase plays important roles in a broad range of industrial production as a biocatalyst, and its applications commonly require immobilization on supports to enhance its stability. Aluminum hydroxide, a carrier material with high surface area, has the advantages of simple and low-cost preparation and resistance to biodegradation, and can be potentially used as a proper support for xylanase immobilization. In this work, xylanase from Thermomyces lanuginosus was immobilized on two types of aluminum hydroxide particles (gibbsite and amorphous Al(OH)3) through adsorption, and the properties of the adsorbed enzymes were studied. Both particles had considerable adsorptive capacity and affinity for xylanase. Xylanase retained 75% and 64% of the original catalytic activities after adsorption to gibbsite and amorphous Al(OH)3. Both the adsorptions improved pH and thermal stability, lowered activation energy, and extended lifespan of the immobilized enzyme, as compared with the free enzyme. Xylanase adsorbed on gibbsite and amorphous Al(OH)3 retained 71% and 64% of its initial activity, respectively, after being recycled five times. These results indicated that aluminum hydroxides served as good supports for xylanase immobilization. Therefore, the adsorption of xylanase on aluminum hydroxide particles has promising potential for practical production.

2중 알루미늄 전극구조의 Charge Coupled Device를 이용한 저역 여파기 (A Transversal Low Pass Filter Using Charge Coupled Device with Two Level Aluminum Electrode Structure)

  • 신윤승;김오현
    • 대한전자공학회논문지
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    • 제18권3호
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    • pp.25-34
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    • 1981
  • 전하결합소자(charge coupled device)의 제작에 필요한 다중전극구조를 실현하기 위하여 알루미늄양극산화방법을 실험적으로 조사하였다. 양극산화의 전해질용액으로 2% ammonium tartrate를 사용하고, 산화전압을 30∼35 volt로 하여 2시간 정도 산화할 때 형성되는 Al2O3의 두께는 400∼500A이었고 절연파괴전압은 30volt 정도였다. 이와 같은 Al2O3의 성질을 이용하여 CCD transversal 저역여파기를 제작하였다. 17개의 tap coefficient를 갖는 저역파기의 stop band attenuation은 약 22dB 이었으며 사용가능한 주파수 범위는 3 KHz로부터 100KHz까지였다.

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CrW 전율고용체 첨가 내열 알루미늄 합금에 관한 연구 (The Study of Heat Resistant Aluminum Alloy with CrW Homogeneous Solid Solution)

  • 김진평;성시영;한범석;김상호
    • 한국주조공학회지
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    • 제33권3호
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    • pp.122-126
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    • 2013
  • Recently, heat-resistant aluminum alloy has been re-focused as a downsizing materials for the internal combustion engines. Heat-resistant Al alloy development and many researches are still ongoing for the purpose of improving thermal stability, high-temperature mechanical strength and fatigue properties. The conventional principle of heat-resistant Al alloy is the precipitation of intermetallic compounds by adding a variety of elements is generally used to improve the mechanical properties of Al alloys. Heat resistant aluminum alloys have been produced by CrW homogeneous solid solution to overcome the limit of conventional heat resistant aluminum alloy. From EPMA, it is found that CrW homogeneous soild solution phases with the size of $50-100{\mu}m$ have been dispersed uniformly, and there is no reaction between aluminum and CrW alloy. In addition, after maintaining at high temperature of 573 K, there is no growth of hardening phase, nor desolved, but CrW still exists as a homogeneous solid solution.

근사 상사 이론을 이용한 비축대칭 등온 단조의 가공하중 예측 (Prediction of the Forming Load of Non-Axisymmetric Isothermal Forging using Approximate Similarity Theory)

  • 한정영;최철현;배원병;김영호;이종헌
    • 한국정밀공학회지
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    • 제17권1호
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    • pp.204-208
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    • 2000
  • An approximate similarity theory has been applied to predict the forming load of non-axisymmetric forging of aluminum alloys through model material tests. The approximate similarity theory is applicable when strain rate sensitivity, geometrical size, and die velocity of model materials are different from those of real materials. Actually, the forming load of yoke, which is an automobile part made of aluminum alloys(Al-6061), is predicted by using this approximate similarity theory. Firstly, upset forging tests are have been carried out to determine the flow curves of three model materials and aluminum alloy(Al-6061), and a suitable model material is selected for model material test of Al-6061. And then hot forging tests of aluminum yokes have been performed to verify the forming load predicted from the model material, which has been selected from above upset forging tests. The forming loads of aluminum yoke forging predicted by this approximate similarity theory are in good agreement with the experimental results of Al-6061 and the results of finite element analysis using DEFORM-3D.

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Alcaligens eutrohus 고농도 배양액으로부터 알루미늄(Al)계 응집제를 이용한 세포분리 (Cell separation from high density culture broths of Alcaligenes eutrophus by using Al-based coagulants)

  • 조경숙;류희욱;정현우;곽종운;장용근
    • KSBB Journal
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    • 제13권3호
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    • pp.272-278
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    • 1998
  • Cell recovery from high cell density broths of Alcaligenes eutrophus by pretreatment with aluminum-based coagulants such as aluminum sulfate, polyaluminum hydrooxide chloride silicate (PACS), and polyaluminum hydrooxide chloride (Hi-PAX) was carried out. Cells coagulated with coagulants could be successfully recovered above 95-99% by centrifugation or filtration. The optimum initial pH of fermentation broths for cell recovery was in the range of 10 to 12. Optimum coagulants dosage for cell recovery increased with increasing of cell concentrations (21-160 g/L). The optimum coagulant dosages to recover cells with more than 95% cell recovery by centrifugation for the cell concentrations ranged 21-160 g/L were as follows: aluminum sulfate, 416-1708 mg Al/L; PACS, 211-826 mg Al/L; Hi-PAX, 320-960 mg Al/L. At optimum conditions for the coagulation of cells, centrifugal forces for 95% of cell recovery were dependent on the cell concentration. The centrifugal forces at 82 g/L and 160 g/L of cell concentration were only 45${\times}$g and 1600${\times}$g, respectively.

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IMPROVEMENT OF FATIGUE LIFE IN POST-WELD COLD WORKED ALUMINUM RESISTANT SPOT WELDS

  • Kim, D.;Blake, D.M.;Ryu, S.J.;Lim, B.S.
    • International Journal of Automotive Technology
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    • 제7권5호
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    • pp.579-584
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    • 2006
  • Aluminum Resistance Spot Weld(Al RSW) is an enabling technology for body assembly of low mass fraction vehicles. Due to the unreliable durability of spot-welded joints, applications of Al RSW are limited. This study presents experimental investigation on the use of a post-weld cold working process to improve the fatigue strength of Al RSW. The post-weld cold working process includes special shaped indenters that are pressed or driven into the structure to induce compressive residual stresses. The mechanical properties of the post-weld cold worked Al RSW were investigated, including the experimental results of fatigue and micro-hardness tests. Comparisons of the mechanical properties and qualitative results between the as-welded RSW specimens and the post-weld cold worked RSW specimens are discussed. The post-weld cold worked Al RSW samples had an increase in both microhardness and fatigue life.

복합주조공정으로 제조한 Al/Cu 하이브리드 소재의 계면특성 (Interfacial Characteristics of Al/Cu Hybrid Materials Prepared by Compound Casting)

  • 김남훈;김정민
    • 한국주조공학회지
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    • 제35권6호
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    • pp.141-146
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    • 2015
  • Aluminum-based hybrid parts were fabricated through a compound casting process with Al or Cu inserts which can be used for applications requiring high conductivity. Because the interface stability between the insert and the aluminum matrix is important, the effects of process variables on the interfacial adhesion strength were investigated. Additions of Cu and Mg to Al melt were found to enhance the adhesion strength, though the melt fluidity was slightly deteriorated when a small amount of Mg was added. An isothermal heating process after casting further improved the strength. However AlCu intermetallic compounds formed and their thickness increased during the heating process. As a result, deterioration in the interfacial adhesion strength was observed after an excessive annealing treatment.

Aluminum Isopropoxide의 가수분해법에 의한 고순도 $\alpha$-Al2O3의 제조 (Preparation of High Purity Alumina by Alkoxide Process)

  • 백행남;이명기;곽중협;서태수
    • 한국세라믹학회지
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    • 제26권3호
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    • pp.445-451
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    • 1989
  • Hydrolysis of aluminum isopropoxide with excess water in the presence of excess isopropyl alcohol resulted in the formation of boehmite in independence of temperature of hydrolysis and aging. Stoichiometric and substoichiometric amount of water hydrolyzed aluminum isopropoxide to pseudo-boehmite and amorphous one, respectively. $\alpha$-Al2O3 with 0.3${\mu}{\textrm}{m}$ in median size was produced by calcination of boehmite, bseudo-boehmite and amorphous boehmite at 125$0^{\circ}C$, 120$0^{\circ}C$, and 115$0^{\circ}C$ for one hour, respectively. Singnificant reduction in particle size was found during transition from $\theta$-Al2O3 to $\alpha$-Al2O3. $\alpha$-Al2O3 produced in this study was relatively uniform spherical and its purity was found to be over 99.9%.

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An Alternative X-ray Diffraction Analysis for Comprehensive Determination of Structural Properties in Compositionally Graded Strained AlGaN Epilayers

  • Das, Palash;Jana, Sanjay Kumar;Halder, Nripendra N.;Mallik, S.;Mahato, S.S.;Panda, A.K.;Chow, Peter P.;Biswas, Dhrubes
    • Electronic Materials Letters
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    • 제14권6호
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    • pp.784-792
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    • 2018
  • In this letter, a standard deviation based optimization technique has been applied on High Resolution X-ray Diffraction symmetric and asymmetric scan results to accurately determine the Aluminum molar fraction and lattice relaxation of Molecular Beam Epitaxy grown compositionally graded Aluminum Gallium Nitride (AlGaN)/Aluminum Nitride/Gallium Nitride (GaN) heterostructures. Mathews-Blakeslee critical thickness model has been applied in an alternative way to determine the partially relaxed AlGaN epilayer thicknesses. The coupling coefficient determination has been presented in a different perspective involving sample tilt method by off set between the asymmetric planes of GaN and AlGaN. Sample tilt is further increased to determine mosaic tilt ranging between $0.01^{\circ}$ and $0.1^{\circ}$.

Aluminium-Pillared Clay의 제조 및 특성 (Characterization and Preparation of Al-Pillared Clay)

  • 박세준;하백현;정순용;서정권;이정민
    • 공업화학
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    • 제10권2호
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    • pp.304-309
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    • 1999
  • 한국산 벤토나이트에 0.2 M $AlCl_3{\cdot}6H_2O$ 수용액과 0.5 M NaOH 수용액을 혼합하여 제조한 수산화 알루미늄 올리고머를 층간 삽입시켜 다공성의 Al-pillared clay를 합성하여 특성 분석 및 열 안정성을 조사하였다. 합성한 aluminum-pillared clay는 수산화 알루미늄 올리고머의 OH/Al의 몰비가 0.25~2.25로 증가할수록 비표면적은 $104{\sim}228m^2/g$으로 증가하였고, 미세세공 면적과 미세세공 부피도 비표면적과 함께 증가하였다. 또한 BJH식으로 계산된 기공분포로부터 약 $40{\AA}$ 정도의 mesopore도 많이 생성되었음을 알 수 있었다. 이 결과는 수산화 알루미늄 올리고머가 층간 삽입되어 층간 공간을 확장하고 알루미늄 산화물이 층간에 지주가 되어 기공이 잘 발달하였기 때문인 것으로 생각된다. 또한 OH/Al 몰비가 클수록 층간기둥이 잘 발달되어 기공이 더욱 증가되었음을 알 수 있었다. OH/Al의 비가 큰 수산화 알루미늄 올리고머 용액으로 제조된 Al-pillared clay는 층간 지주들이 많이 생성되므로서 층간 기둥 밀도를 증가시켜 열안정성을 향상시킨 것으로 생각된다.

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