• Resources Recycling
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• v.28 no.1
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• pp.15-22
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• 2019

There are three hydrometallurgical methods by which pure alumina can be prepared, such as hydrolysis of aluminum alkoxides, thermal decomposition of ammonium alum and thermal cracking of ammonium aluminum carbonate (AACH). The effect of solution pH and temperature and the nature of the impurities on the phase transition and the purity of the alumina thus produced was investigated. Hydrolysis of aluminum alkoxides and thermal decomposition of ammonium alum produce ${\alpha}$ and ${\gamma}$ alumina, while only ${\alpha}$ alumina can be produced by thermal cracking of AACH.

• Journal of Conservation Science
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• v.35 no.2
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• pp.153-158
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• 2019

The traditional sizing treatment for the Hanji is performed to give the following functions. Those are to stabilize the paint of the painting, to prevent the paint of painting and moisture from smearing into the painting itself, to prevent the paint of the painting and moisture from passing to the lining paper, and to make the colors of painting match the surrounding.This study analyzed a result of the effect of Hanji sizing characteristic according to glue and alum mixing ratio and applying times, affects to pigments of painting and fastness of Hanji using accelerated aging test. As a result of color measurement of sizing treated Hanji, the concentration of glue and the number of application increased, the brightness and the $L^*$ value decreased but the yellowness index increased.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.8
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• pp.549-556
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• 2012

T-P removal efficiency was analyzed according to the metal to initial T-P ratio (mole basis) with respect to the samples from different WWTPs having various initial T-P and SS conditions. Also, operating costs were calculated based on the injected coagulant amount and the amount of sludge production. Most experiments were conducted by the standard jar-test protocol. Molar ratio of coagulant dose was varied considerably according to the initial SS concentration range in secondary clarifier effluent samples which had above 0.5 mg/L of initial T-P. Based on 90% T-P removal efficiency, results were: At the initial SS range of below 10 mg/L, Alum (8%) = 11 mol Al/mol P needed and PAC (17%) = 9.6 mol Al/mol P needed; At the initial SS range of above 10 mg/L, Alum (8%) = 3.9 mol Al/mol P needed and PAC (17%) = 3.2 mol Al/mol P needed.

• The Journal of Pediatrics of Korean Medicine
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• v.32 no.3
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• pp.1-15
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• 2018

Objectives Alismatis Rhizoma has been known to suppress inflammation and allergic reaction. However, the cellular target of Alismatis Rhizoma and its mechanism of action remain unclear. This study was designed to examine the effect of Alismatis Rhizoma extract (ALC) on the RBL-2H3 mast cells in vitro and on the OVA/alum sensitized mice ex vivo. Methods In the study, RBL-2H3 mast cells were cultured in minimal essential medium (MEM) for 24 hours, and treated separately with cyclosporin A and varying doses of ALC, and then stimulated with Phorbol 12-myristate 13-acetate (PMA) (50 ng/ml) and Ionomycin ($0.5{\mu}M$). The levels of IL-13, IL-4 were measured by ELISA analysis. The mRNA levels of IL-4, IL-5, IL-6, IL-13, GM-CSF, $TNF-{\alpha}$ were analyzed with Real-time PCR. Also, manifestations of MAPKs transcription factors and $NF-{\kappa}B$ p65 translocation were analyzed by western blotting in vitro. Subsequently, for ex vivo experiment, we induced allergic inflammation on Balb/c mice by OVA/alum and administered ALC orally. And we measured serum OVA-specific IgE level and IL-4, IL-13 in the splenocyte culture supernatant by ELISA analysis. Results ALC was shown to suppress mRNA expression of IL-4, IL-5, IL-6, IL-13, GM-CSF, $TNF-{\alpha}$, and to inhibit the IL-13, IL-4 production. Also ALC reduced an activation of mast cells specific signal MAPKs transcription factors and $NF-{\kappa}B$ p65 from the western blot analysis in in vitro experiment. In ex vivo, ALC oral adminstration decreased the level of OVA-specific IgE in serum, and IL-4, IL-13 in the splenocyte culture supernatant. Conclusions ALC is shown to reduce inflammation and allergic response by suppressing Th2 cytokines through the regulation of transcription factors MAPKs and $NF-{\kappa}B$ p65 in mast cells. Administration of ALC suppressed OVA-specific IgE in ovalbumin allergy model through the inhibition of Th2 cytokine. In conclusion, ALC can be considered as an effective treatment for allergic diseases such as atopic dermatitis.

• Applied Biological Chemistry
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• v.40 no.4
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• pp.289-293
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• 1997

The effects of different types of additives(sucrose fatty acid ester(SE), oligosaccharide and alum) on 40% nonwaxy rice starch gels stored at $20{\pm}1^{\circ}C$ were investigated by ${\alpha}-amylase-iodine$ method, X-ray diffractometry and differential scanning calorimetry. The addition of SE retarded the retrogradation of gels throughout storage period and the antistaling effect of SE was increased with increasing concentration. Oligosaccharide(0.1%) inhibited the retrogradation, but oligosaccharide(0.1% or 0.5%) retarded the retrogradation at early stage of storage, and stimulated the retrogradation after 3 days. Alum of 0.1% level retarded the retrogradation, but 0.3% level activated the retrogradation after 24 hours and 0.5% level did after 12 hours. The effect of additives on the retrogradation of rice starch gels showed the different tendencies at the level of additives. On 0.1% level, the effect of those was similar but on 0.5%, the degree of retardation increased in order of oligosaccharide, SE1170, alum, no addition for up to 2 days of storage and SE1170, no addition, oligosaccharide, alum for 3 days of storage.

• IMMUNE NETWORK
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• v.13 no.6
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• pp.295-300
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• 2013

Der f 2 is the group 2 major allergen of a house dust mite (Dermatophagoides farinae) and its function has been recently suggested. To determine the optimal condition of sensitization to recombinant Der f 2 (rDer f 2) in murine model of asthma, we compared the effectiveness with different adjuvants in BALB/c and C57BL/6 mice. Mice from both strains sensitized with rDer f 2 by intraperitoneal injection or subcutaneous injection on days 1 and 14. The dosage was $20{\mu}g$. Freund's adjuvants with pertussis toxin (FP) or alum alone were used as adjuvants. On days 28, 29, and 30, mice were challenged intranasally with 0.1% rDer f 2. We evaluated airway hyperresponsivenss, eosinophil proportion in lung lavage, airway inflammation, and serum allergen specific antibody responses. Naive mice were used as controls. Airway hyperresponsiveness was increased in C57BL/6 with FP, and BALB/c with alum (PC200: $13.5{\pm}6.3$, $13.2{\pm}6.7$ vs. >50 mg/ml, p<0.05). The eosinophil proportion was increased in all groups; C57BL/6 with FP, BALB/c with FP, C57BL/6 with alum, BALB/c with alum ($24.8{\pm}3.6$, $20.3{\pm}10.3$, $11.0{\pm}6.9$, $5.7{\pm}2.8$, vs. $0.0{\pm}0.0$%, p<0.05). The serum allergen specific IgE levels were increased in C57BL/6 with FP or alum (OD: $0.8{\pm}1.4$, $1.1{\pm}0.8$, vs. $0.0{\pm}0.0$). C57BL/6 mice were better responders to rDer f 2 and as for adjuvants, Freund's adjuvant with pertussis toxin was better.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.10
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• pp.724-729
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• 2013

Simultaneous nitrification and denitrification (SND) occurs concurrently in the same reactor under micro dissolved oxygen (DO) conditions. Anaerobic zone was applied for phosphorus release prior to an aerated membrane bio-reactor (MBR), and anoxic zone was installed by placing a baffle in the MBR for enhancing denitrification even in high DO concentration in the MBR. Phosphorus removal was tested by alum coagulation in the anaerobic reactor preceding to MBR. DO concentration were 2.0, 1.5, 1.0, 0.75 mg/L in the MBR at different operating stages for finding optimum DO concentration in MBR for nitrogen removal by SND. pH was maintained at 7.0~8.0 without addition of alkaline solution even with alum addition due to high alkalinity in the raw sewage. Both TCODcr and $NH_4^+$-N removal efficiency were over 90% at all DO concentration. TN removal efficiencies were 50, 51, 54, 66% at DO concentration of 2.0, 1.5, 1.0, 0.75 mg/L, respectively. At DO concentration of 0.75 mg/L with addition of alum, TN removal efficiency decreased to 54%. TP removal efficiency increased from 29% to 95% by adding alum to anaerobic reactor. The period of chemical backwashing of the membrane module increased from 15~20 days to 40~50 days after addition of alum.

• The Korea Journal of Herbology
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• v.36 no.5
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• pp.15-27
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• 2021

Objectives : The processing of Pinelliae Tuber and Arisaematis Rhizoma is a crucial step to reduce the severe acrid irritation mainly due to the needle-like crystals (raphides). Ginger, alum and bile juice have been used as adjuvant materials for the processing. Methods : Bibliographic research on ancient processing and experimental processing was performed to investigate the toxicity reduction mechanisms of the processing with ginger, alum and bile juice. Results : Ginger has been a major adjuvant for the processing of Pinelliae Tuber, followed by alum and bile juice since Song (宋) and Myeong (明) dynasties, and Arisaematis Rhizoma has been mainly used as Damnamseong (膽南星). The raphides consisting of calcium oxalate, lectin, agglutinin and polysaccharides can induce acrid irritation and the inflammatory reactions. The lipophilic components in the ginger denatured the structure of raphides and 6-gingerol-contained ginger extract attenuated the inflammatory reaction. The calcium ion (Ca²⁺) of calcium oxalate was substituted to the aluminium ion (Al³⁺) of the alum, which damaged the calcium oxalate structure. Lectin attached to the surface of raphides was dissolved in alum solution and consequently its structure was denatured. The cholate in the bile juice formed the complex with the oxalate anion or the calcium cation. Moreover, the enzymes activated by Lactobacillus or Bifidobacterium during the fermentation promoted the fragmentation of oxalate. Conclusion : The adjuvant materials damaged the raphides by denaturing or degrading the calcium oxalate, resulting in the reduction of acrid irritation. Further experimental studies would support the toxicity reduction mechanism of the processing.

• Korean Journal of Mineralogy and Petrology
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• v.36 no.1
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• pp.19-32
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• 2023

This study was conducted to remove fluorine (F) (initial concentration of 9.5 mg/L) from leachate of reclaimed mine waste dump site via different methods: (1) co-precipitation using Ca-based materials; (2) adsorption using activated carbon and fly ash; and (3) coagulation and sedimentation using alum. The F removal efficiencies of each case were estimated as 65.6% (Ca co-precipitation), 27.9% (adsorption of activated carbon), 71.5% (adsorption of fly ash), and 96.6% (alum coagulation and sedimentation). In addition, the applicability of the continuous treatment process using alum coagulation was evaluated by lab-scale experiments using simulated mine drainage containing F of lower (6.4 mg/L) and higher (15.7 mg/L) concentrations, and it was confirmed that the treatment of both cases met the domestic standard (below 3 mg/L) for discharged water in clean areas. Furthermore, the results of bench-scale field tests indicated that the water quality standard of discharged water could be satisfied with the proper operation and management of the process.

• Journal of Conservation Science
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• v.20
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• pp.9-22
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• 2007

Three kinds of natural pesticides extracted from plants which are being sold in the Korean markets, were estimated effects on materials of art of museum. Tested samples were 1) silk fabrics : undyed, dyed(amur cork tree, gallut, gallut(alum post mordancy), gallut(copperas post mordancy), gardenia, turmeric, acorn, acorn(copperas post mordancy), gromwell, madder, madder(alum post mordancy), safflower, sappanwood, sappanwood(alum pre mordancy, post mordancy), indigo, indigo+amur cork tree, indigo+sappanwood) 2) cotton fabrics : undyed, dyed(amur cork tree, gallut, gallut(alum post mordancy), gardenia, acorn, acorn(copperas post mordancy), gromwell, madder, madder(alum post mordancy), safflower, sappanwood, sappanwood(alum pre mordancy, post mordancy), indigo, indigo+sappanwood) 3) undyed ramie fabric 4) Korean papers : undyed, dyed(sappanwood, indigo, gardenia, amur cork tree, safflower) 5) pigments : azurite, malachite, red lead, litharge, orpiment, hematite, iron oxide, cinnabar, vermilion, indigo, lake indigo, kaolin, lead white, oyster shell white 6) painted plates : azurite, malachite, red lead, litharge, orpiment, hematite, iron oxide, cinnabar, vermilion, indigo, lake indigo, kaolin, lead white, oyster shell white. Conditions of tests were that after samples were exposed to 10 times of promoted concentration for 9 months in relative humidity $55{\pm}1%$ and temperature $20{\pm}2^{\circ}C$, they were compared with standards. Items of estimation were color difference(${\Delta}E^*$) and tenacity. After exposure to pesticides, undyed silk cotton ramie fabrics and Korean papers were not nearly changed in their colors, but colors of most of dyed samples were clearly changed by pesticides except for partial samples(acorn- and madder-dyed fabrics etc, gardenia-dyed samples). Especially changes of colors of turmeric-dyed silk fabrics were most distinct. And colors of pigments and painted plates containing lead, copper, arsenic, mercury and vegetable pigments, were clearly changed. Tenacities of yams of undyed silk fabrics were not nearly changed and undyed cotton fabrics were a little reduced as compared with standards. But tenacities of yams of dyed silk and cotton fabrics were clearly reduced or increased as compared with standards. Especially, madder-dyed silk fabrics were increased 10% or more and indigo-dyed silk fabrics were reduced 10% or less in all pesticides. Also madder- and sappanwood(alum post mordancy)-dyed cotton fabrics were increased 10% or more in all pesticides.