• Title/Summary/Keyword: Alq$_3$

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Degradation Mechanisms of Organic Light-emitting Devices with a Glass Cap (유리 덮개로 보호된 OLED소자의 발광특성 저하 연구)

  • Yang Yong Suk;Chu Hye Yong;Lee Jeong-Ik;Park Sang-He;Hwang Chi Sun;Chung Sung Mook;Do Lee-Mi;Kim Gi Heon
    • Journal of the Korean Vacuum Society
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    • v.15 no.1
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    • pp.64-72
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    • 2006
  • We demonstrated organic light-emitting devices (OLEDs) based on the organic thin-film materials such as tris-(8-hydroxyquinoline) aluminum $(Alq_3)$. The structure of OLEDs was vacuum deposited upon transparent and thin glass substrates pre-coated with a transparent, conducting indium tin oxide thin film. The luminance characteristics, current, capacitance, and dispersion factor for degraded OLEDs, which were made by various bias currents $(0.5mA\;{\leq}\;I_{Bias}\;{\leq}9mA)$, are studied. The current dependences of lifetime were divided at approximately 2mA, and they represented nearly linear behaviors but had different slopes in a logarithmic plot of lifetime versus bias current. With lighting OLEDs, the anomaly of capacitance, as shown in the CV curve, occurred because of two factors, polarization in the bulk of organic materials and the interface between the metal and organic layers. In decayed OLEDs that had lower bias currents of less than 2mA, it was found that the degradation of luminance was related to both the decrease of polarization and to the lowering of the injection barrier.

Enhanced Efficiency of Organic Electroluminescence Diode Using PEDOT-PSS/NPD-$C_{60}$ Hole Injection/Transport Layers (PEDOT-PSS/NPD-$C_{60}$ 정공 주입/수송 층이 도입된 유기발광소자의 성능 향상 연구)

  • Park, Kyeong-Nam;Kang, Hak-Su;Senthilkumar, Natarajan;Park, Dae-Won;Choe, Young-Son
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.407-412
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    • 2009
  • Vacuum deposited N,N-di-1-naphthyl-N,N-diphenyl-1,1'-biphenyl-4,4'-diamine (NPD) as a hole transporting (HTL) materials in OLEDs was placed on PEDOT-PSS, a hole injection layer (HIL). PEDOT-PSS was spin-coated on to the ITO glass. $C_{60}$-doped NPD-$C_{60}$(10 wt%) film was formed via co-evaporation process and the morphology of NPD-$C_{60}$ films was investigated using XRD and AFM. The J - V, L - V and current efficiency of multi -layered devices were characterized. According to XRD results, the deposited $C_{60}$ thin film was partially crystalline, but NPD-$C_{60}$ film was observed not to be crystalline, which indicates that $C_{60}$ molecules are uniformly dispersed in the NPD film. By using $C_{60}$-doped NPD-$C_{60}$ film as a HTL, the current density and luminance of multi-layered ITO/PEDOT-PSS/NPD-$C_{60}/Alq_3$/LiF/Al device were significantly increased by about 80% and its efficiency was improved by about 25% in this study.

Emission Properties of the OELD with Cathode Interface Layer for Cz-TPD (Cz-TPD를 음극접합층으로한 OELD의 발광특성)

  • Choi, W.J.;Cho, M.J.;Park, C.H.;Lee, J.G.;Lim, K.J.;Park, S.K.;Kim, H.H.
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.109-111
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    • 2001
  • In this study, The cathode interface layer (CIL) was investigated using aromatic diamine derivatives. Cz-TPD (4,4'-biscarbazolyl (9)-biphenyl) used in the cathode interface layers is investigated emition charcaracteristics at the green organic electroluminescent devices TPD (N.N'-dyphenyl-N-N'-bis(3-methy phenyl)-1.1'-biphenyl-4.4'-diamine) as the hole transformer layer and $Alq_3$:tris (8-hydroxyquinoline) aluminium) as the electron transport layer and emiting layer maded use of the organic electroluminescent device. The Organic Electroluminescent Device with Ag, cathode and CIL of Cz-TPD(4,4'-biscarbazolyl(9)-biphenyl) showed good EL characteristics compare to a conventional Mg:Ag device and also an improved storage stability.[1] As the change in MgAg, Cz-TPD/Ag, Ag at the chthode, the electron and optical charcaracteriseics were investigated.

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배면 유기 발광 소자의 각도에 따른 발광 패턴

  • Mok, Rang-Gyun;Ju, Hyeon-U;Han, Won-Geun;Song, Min-Jong;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.195-196
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    • 2009
  • 각도에 따른 배면 유기 발광 소자의 발광 패턴에 대해서 연구하였다. 소자 내에서 발광한 빛은 등방성으로 퍼져 나가고 굴절률이 n인 매질과 공기의 계면에서 굴절하게 된다. 소자 내에서 굴절되어 퍼져 나온 빛의 각도에 따른 빛의 세기를 측정하였다. 또한 배면 유기 발광 소자에서의 시야각을 $10^{\circ},\;20^{\circ},\;30^{\circ},\;40^{\circ},\;50^{\circ},\;6^{\circ}$로 변화시켜 각도에 따른 발광 패턴을 알 수 있었다. 소자 내에서 발광한 빛이 소자 밖으로 퍼져 나올 때의 발광 패턴을 편광판을 이용하여 $0^{\circ}$$90^{\circ}$로 변화시켜 실험하였다. 소자의 구조는 ITO(170nm)/TPD(40nm)/$Alq_3$(60nm)/LiF(0.5nm)/Al(100nm)으로 하고, 유기물층과 음전극은 $2{\times}10^{-5}$Torr에서 증착하였다. 유기물의 증착 조건은 $2{\times}10^{-5}$torr의 진공도에서 $1.5{\sim}2.0{\AA}/s$ 속도로 열 증착하였다. 전극의 증착 조건은 $2{\times}10^{-5}$torr의 진공도에서 $1.5{\sim}2.0{\AA}/s$ 속도로 열 증착하였다. 발광 면적은 $3mm{\times}5mm$이다. 소자의 각도에 따른 발광 스펙트럼 측정은 USB-2000을 사용하였다. 소자 밖으로 나오는 편광되어진 빛을 측정하기 위하여 편광판을 사용하여 측정하였다.

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F4-TCNQ를 이용한 유기 발광 소자의 전기적 특성 변화

  • Na, Su-Hwan;Kim, Tae-Wan;Jang, Gyeong-Uk;Han, Won-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.166-167
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    • 2009
  • 본 연구에서는 2,3,5,6-fluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ)를 이용한 유기 발광 소자의 전기적 특성에 대하여 연구하였다. F4-TCNQ 는 높은 전자 친화도를 가지고 있어서 전하 수송층이나 전하 주입층에 많이 사용되고 있다. 또한 TCNQ 유도체들은 물질의 전도도를 조절하는 용도로 많이 이용된다. TCNQ 유도체를 유기 발광 소자의 전하 수송층이나 전하 주입층에 이용할 경우, 소자의 구동 전압이나 효율과 같은 특성들이 향상된다고 알려져 있다. 우리는 소자 특성에 있어서 F4-TCNQ의 영향을 알아보기 위해서 ITO(170nm)/TPD(40nm)/$Alq_3$(60nm)/LiF(0.5nm)/Al(100nm)의 구조로 기본 소자를 제작하였다. 그리고 TPD층에 F4-TCNQ를 도핑하여 소자를 제작하였다. 도핑 농도는 5와 10%로 하였다. 또한 ITO와 TPD층 사이에 F4-TCNQ층을 1, 2, 그리고 5nm의 두께로 하여 소자를 제작하였다. F4-TCNQ를 5와 10% 도핑한 소자의 구동 전압은 도핑하지 않은 소자에 비해 감소하였다. 그리고, ITO와 유기물층 사이에 F4-TCNQ층을 삽입한 소자의 특성은 삽입하지 않은 소자에 비해 향상되었다.

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Synthesis and Characterization of 9,9'-Diethyl-2-diphenylaminofluorene Derivatives as Blue Fluorescent Materials for OLEDs

  • Oh, Suh-Yun;Lee, Kum-Hee;Seo, Ji-Hoon;Kim, Young-Kwan;Yoon, Seung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1593-1598
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    • 2011
  • Blue fluorescent materials based on 9,9'-diethyl-2-diphenylaminofluorene derivatives were synthesized and characterized. These materials were used as the blue dopant materials for the emitting layer of organic light-emitting diode devices with the following device structure: ITO/DNTPD (40 nm)/NPB (20 nm)/MADN: dopants (2%, 20 nm)/$Alq_3$ (40 nm)/Liq (1.0 nm)/Al. All devices exhibited highly efficient blue emission. One of these devices exhibited a maximum luminance, luminous efficiency, power efficiency and CIE x, y coordinates of 8400 $cd/m^2$, 8.10 cd/A at 20 $mA/cm^2$, 3.36 lm/W at 20 $mA/cm^2$ and (0.151, 0.159), respectively. A deep blue device with CIE coordinates of (0.152, 0.139) showed the maximum luminance, luminous efficiency and power efficiency of 8630 $cd/m^2$, 6.31 cd/A at 20$mA/cm^2$ and 2.62 lm/W at 20 $mA/cm^2$, respectively.

A Study on Dependent Characteristic between The Organic Deposition Rate and The Performance in Organic Light Emitting Device

  • Kim, Mun-Su;Choe, Byeong-Deok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.150.2-150.2
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    • 2015
  • In this study, we analyzed the electric and optical characteristics by using various deposition rate ($0.5{\AA}$, $1.0{\AA}$ and $1.5{\AA}/s$) in order to enhance the performance in organic light-emitting devices (OLED). The organic multi-layer structures were deposited with NPB ($500{\AA}$ as hole transport layer), Alq3 ($600{\AA}$ as electron transport layer and emission layer) and LiF ($8{\AA}$ as electron injection layer) via SUNIC PLUS200 on Glass/ITO substrates. In this experiment, we examined the relationship between porous state of organic deposition and mobility of the organic materials. Among the three deposition rates, $0.5{\AA}/s$ achieved the highest performance of (10,786cd/m2, 4.387cd/A) comparing with that of $1{\AA}/s$ (7,779cd/m2, 3.281cd/A) and $1.5{\AA}/s$ (5,167cd/m2, 2.693cd/A). We confirmed that low deposition rate helps to arrange organic materials densely and to move easily another atomic location using inter-chain transporting by orbital overlap.

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Study on the characteristics of white organic light-emitting diodes using a new material

  • Shim, Hye-Yeon;Jeong, Ji-Hoon;Kwon, Hyuk-Joo;Cho, Young-Jun;Kim, Bong-Ok;Kim, Sung-Min;Kim, Chi-Sik;Yoon, Seung-Soo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.688-691
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    • 2004
  • In this study, we synthesized a new red emitting material of a Red225 doped into $Alq_3$ (tris(8-quinolinolato)aluminum (III)) and fabricated white organic light-emitting diodes (OLEDs) with a simple device structure. With a blue emitting material of DPVBi (4,4'-bis(2,2'-diphenylvinyl)1,1'-biphenyl) that can transfer effectively both a hole and an electron, OLEDs with a narrow emission layer could be possible without a hole-blocking layer. Consequently, the driving voltage and stability of devices have been improved. The devices show the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.36, 0.35) at luminance of 2000 cd/$m^2$. The luminous efficiency is about 3.5 cd/A, luminance is about 12000 cd/$m^2$ and current density is about 350 mA/$cm^2$ at 12 V, respectively.

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Emission Properties of OLED Devices with Various Hole Injection Materials (정공주입층에 따른 OLED 소자의 발광 특성)

  • Lee, Bong-Sub;Gao, Xin-Wei;Park, Jong-Yek;Baek, Yong-Gu;Yang, Jae-Woong;Paek, Kyeong-Kap;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.562-568
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    • 2008
  • In this paper, the hole injection layer(HIL) materials have been synthesized and analyzed. Their HOMO levels are $4.93{\sim}5.22\;eV$, and their energy band gaps are $2.74{\sim}3.19\;eV$. Their glass transition temperatures($T_g$) are all above $114^{\circ}C$, which implies that they are highly thermal-stable. The green OLED devices with a structure of ITO(150 nm)/NEW_HIL(50 nm)/NPB(30 nm)/$Alq_3$(50 nm)/Al:Li(100 nm) were fabricated and tested, incorporating these newly synthesized HIL materials. According to the test results of OLED devices, the I-V-L performances of these devices increase in the following sequence: ELM307 > ELM200 > ELM321 > ELM327 > ELM325. In addition, the OLED device with ELM307 as a HIL has the highest brightness and efficiency at the same driving voltage. These experimental results have shown that ELM307 can be used as one of the most promising candidates for HIL materials.

The Study on Characteristics of Green Organic Light Emitting Device with Transparency Conductive Oxide Electrodes (투명전도성 산화물 전극에 따른 Green OLED의 특성연구)

  • Ki, Hyun-Chul;Kim, Seon-Hoon;Kim, Hwe-Jong;Kim, Sang-Gi;Choi, Young-Sung;Hong, Kyung-Jin
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.4
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    • pp.615-618
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    • 2009
  • In order to apply for transparent conductive oxide(TCO), we deposited ZnO thin film on the glass at room temperature by RF magnetron sputtering method. Deposition conditions for low resistivity were optimized in our previous studies. Under the deposition condition with the RF power of 800 [W]. Sheet resistance and surface roughness of ITO and ZnO thin film were measured by Hall-effect measurement system and AFM, respectively. The sheet resistance of ITO and ZnO thin film were 7.290 [$\Omega$] and 4.882 [$\Omega$], respectively. and surface roughness were 3.634 [nm] and 0.491 [nm], respectively. Green OLED was fabricated with the structure of TPD(400 [$\AA$])/Alq3(600 [$\AA$])/LiF(5 [$\AA$])/Al(1200 [$\AA$]). Turn-on voltage of green OLED applied ITO was 7 [V] and luminance was 7,371 [$cd/m^2$]. And, Turn-on voltage of green OLED applied ZnO was 14 [V] and luminance was 6,332 [$cd/m^2$].