• 대한금속재료학회지
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• 제47권11호
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• pp.759-772
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• 2009

Amorphous alloys, in addition to being promising materials for a variety of practical applications, provide an excellent test bed for evaluating our understanding of the underlying physics on deformation in amorphous solids. Like many amorphous materials, amorphous alloys can exhibit either homogeneous or inhomogeneous deformation depending on the stress level. The mode of deformation has a strong influence on whether the material behavior is classified as ductile or brittle. It was observed that the characteristics of these deformations are largely dependent on the atomic-scale structures of the alloys and determine the amount of the plastic deformation prior to failure. In this study, the structural features that control the homogeneous deformation of amorphous alloys are outlined on the basis on experiments and molecular dynamics simulations.

• 한국표면공학회지
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• 제53권6호
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• pp.322-329
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• 2020

The utilization of aluminum scrap is a subject of great importance in terms of reducing energy consumption and environmental protection. However, aluminum scrap contains impurities, which can degrade the properties of aluminum alloy, especially corrosion resistance. This study examines the effect of scrap charge rate of aluminum alloys about microstructures and corrosion characteristics. According to the metallographic examinations, Mg2Si tended to become coarser and its uniformity was decreased by increasing aluminum scrap charge rate. The immersion test exhibited corrosion progressed through the eutectic areas due to micro-galvanic interactions. Electrochemical measurements revealed that excess aluminum scrap could reduce the intergranular corrosion resistance of aluminum alloys. Results showed that the scrap charge rate is important factor in the design of corrosion resistance of aluminum die casting alloys.

• 한국주조공학회지
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• 제11권4호
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• pp.314-322
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• 1991

In this study, Na, Li, Sb, Sr were added as the modifiers to improve the mechanical proper ties of Al-Si alloys and their effects were compared one another Thermal analysis was carried out to measure the degree of undercooling, that is, the basic mechanism of modifying effect. The measurements of holding time and analyses of components of Al-Si alloys were carried out to compare the fading of the modifiers. Greater degree of undercooling was measured from the modified alloy than the normal alloys. In the modified alloy, the shape of Si was changed into a fine fiber phase or a lamellar phase from the coarse plate phase. There are not modifying effect of Sb below the $1.5^{\circ}C$ /sec of cooling rate. As the cooling rate increases, similar effects appears in the non-modified alloys like the modified alloys. Na and Li were faded in short time and were difficult to control on the melt, but Sb and Sr were scarcely faded for 6 hours of holding and were easy to control on the melt. Na and Sr are the good modifiers in terms of microstructure. Sb is the best modifier, but Na, Li are the inadequate modifiers in terms of fading.

• 한국재료학회지
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• 제14권8호
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• pp.547-551
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• 2004

The sulfidation behaviour of Fe-XAl-0.3Y(X=5, 10, 14, 25 $wt.\%$) alloys was investigated at 1123 K in $H_2/H_{2}S$ gas atmosphere for $1\sim24$ hrs using SEM/EDX, XRD and EPMA. The weight changes of Fe-XAl-0.3Y alloys followed the parabolic rate law, Sulfidation rates of iron aluminide alloys with high Al content were one-twentieth lower than that of 5Al alloys. This is due to the formation of protective $Al_{2}O_3$ oxides on the surface of 10Al, 14Al and 25Al alloys. By calculating partial pressure of impurity oxygen contained $H_2/H_{2}S$ gas, the $Al_{2}O_3$ oxides formation could be explained using Fe-Al-S-O thermodynamic stability diagram. The sulfidation product scales of the 5Al alloy showed that thick iron sulfide scale(FeS) containing porosities formed during early stages of sulfidation. With continued sulfidation, aluminum sulfide was formed at the alloy/scale interface.

• 한국표면공학회지
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• 제42권5호
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• pp.246-249
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• 2009

Cu-Ti alloys with titanium in the range of 0.5-6.0 wt% were developed to evaluate the effect of the titanium content and heat treatment on microstructure, hardness, and electrical conductivity. The hardness of the Ti-added copper alloys generally increased with the increase in titanium content and hardening was effective up to the 2.5 wt%-Ti addition. Microstructural examination showed that the second phase of $Cu_4Ti$ started to precipitate out from the 3.0 wt% Ti-addition, and the precipitate size and volume fraction increased with further Ti addition. Aging of the present Cu-Ti alloys at $450^{\circ}C$ for 1 h increased the hardness; however, the further aging up to 10 h did not much change the hardness. In the present study, it was inferred that in optimal Ti addition and aging condition Cu-Ti alloy could have the hardness and electrical conductivity values which are comparable to those of commercial Cu-Be alloy.

• Corrosion Science and Technology
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• 제12권1호
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• pp.50-55
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• 2013

The purpose of this study was to investigate corrosion characteristics of Ti-xTa alloys with Ta contents. Ti-xTa alloys used as samples (x=30, 40%) were arc-melted under argon atmosphere of 99.9% purity. Ti-xTa alloys were homogenized for 12hr at $1000^{\circ}C$ and then water quenched. The surface characteristics of Ti-xTa alloys were investigated using optical microscopy (OM) and X-ray diffractometer (XRD). The anodic corrosion behaviors of the specimens were examined through potentiodynamic, potentiostatic and galvanostatic test in 0.9 % NaCl solution at $36.5{\pm}1^{\circ}C$. After corrosion test, the surface characteristics of Ti-xTa alloys were investigated using OM. The microstructure of Ti-Ta alloy showed the beta structure with Ta content. The corrosion resistance of Ti alloy was improved by increasing Ta content and the corrosion morphology of Ti-Ta alloy showed that the site attacked by chloride ion decreased from the active to passive region with Ta content. Potential of Ti-40Ta alloy increased as time increased, whereas, current density of Ti-40Ta alloy decreased as time increased compared to Ti-30 alloy.

• Journal of Electrochemical Science and Technology
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• 제8권4호
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• pp.294-306
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• 2017

Stainless steels and titanium alloys are widely used in the medical industry as replacement materials. These materials may be affected by the conditions and type of environment. In the same manner, soft drinks are widely consumed products. It is of interest for dental industry to know the behavior of medical-grade alloys when these are in contact with soft drinks, since any excessive ion release can suppose a risk for human health. In the present study, the electrochemical behavior of three stainless steel alloys and pure titanium was analyzed using three types of cola soft drinks as electrolyte. The objective of this study was to evaluate the response of these metallic materials in each type of solution (cola standard, light and zero). Different electrochemical techniques were used for the evaluation of the alloys, namely potentiodynamic polarization, linear polarization, and open-circuit potential measurements. The corrosion resistance of the stainless-steel alloys and titanium in the cola soft drinks was provided by the formation of a stable passive film formed by metal oxides. Scanning electron microscopy was used as a complementary technique to reveal corrosion phenomena at the surface of the materials evaluated.

• 열처리공학회지
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• 제28권1호
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• pp.1-6
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• 2015

The ductile-to-brittle transition behavior of two austenitic Fe-18Cr-10Mn alloys with the combined addition of nitrogen and carbon was investigated in this study. The alloys exhibited a ductile-to-brittle transition behavior because of unusual brittle fracture at low temperatures unlike conventional austenitic alloys. The alloy with higher carbon content had higher yield and tensile strengths than that with lower carbon content due to the solid solution strengthening effect resulting from carbon addition. However, the increase in carbon content promoted the occurrence of intergranular fracture, and thus deteriorated the impact toughness. In order to develop successfully the austenitic Fe-18Cr-10Mn alloys with the excellent combination of strength and toughness in the future, therefore, more systematic studies are required to find the appropriate amount and ratio of nitrogen and carbon.

• Nuclear Engineering and Technology
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• 제49권7호
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• pp.1571-1574
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• 2017

In the present work, the gamma ray backscattering technique was used to determine the effective atomic numbers for certain binary alloys. With the help of a muffle furnace, the binary alloys were synthesized using the melt quenching technique with different compositions of $_{82}Pb$, $_{50}Sn$, and $_{30}Zn$. The intensity distribution of backscattered photons from radioactive isotope $^{22}Na$ (511 keV) was recorded with the help of GAMMARAD5 [$76mm{\times}76mm$ NaI(Tl) scintillator detector] and analyzed as a function of both atomic number and thickness of the target material. The effective atomic numbers for the same binary alloys were also computed theoretically using the atomic to electronic cross-section method with the help of the mass attenuation coefficient database of WinXCom (2001). Good agreement was observed between theoretical and experimental results for the effective atomic numbers of all the selected alloys.

• 마이크로전자및패키징학회지
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• 제25권2호
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• pp.9-17
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• 2018

Aluminum (Al) and its alloys have been used widely in a variety of industries such as structural, electronic, aerospace, and particularly automotive industries due to their lightweight characteristic, outstanding ductility, formability, high oxidation and corrosion resistance, and high thermal and electrical conductivity. Al have different kinds of alloys according to the various additional elements system and they should be selected properly depending on their effectiveness and suitability for their particular purpose. The major elements for Al alloys are silicon (Si), magnesium (Mg), manganese (Mn), copper (Cu), and zinc (Zn). In order for Al alloys to use for each industry, it is necessary to study of Al to Al joining and/or the Al to dissimilar materials joining to combine the individual parts into one. Many studies on joining technologies about Al to Al and Al to dissimilar materials have been performed such as press joining, bolted joint, welding, soldering, riveting, adhesive bonding, and brazing. This study reviews a variety of Al alloys and their joining method including its principles and properties with recent trends.