• 대한기계학회논문집B
• /
• 제20권11호
• /
• pp.3655-3665
• /
• 1996

An analytical solution is presented for the conduction-dominated solidification of a binary mixture in a semi-infinite medium. The present approach differs from that of other solution by these four characteristics. (1) Solid fraction is determined from the phase diagram, (2) thermophysical properties in mushy zone are weighted according to the local solid fraction, (3) non-equilibrium solidification can be simulated and (4) the cooling condition of under-eutectic temperature can be simulated. Up to now, almost all analyses are based on the assumption of constant properties in mushy zone and solid fraction linearly with temperature or length. The validation for these assumptions, however, shows that serious error is found except some special cases. The influence of microscopic model on the macroscopic temperature profile is very small and can be ignored. But the solid fraction and average solid concentration which directly influence the quality of materials are drastically changed by the microscopic models. An approximate solution using the method of weighted residuals is also introduced and shows good agreement with the analytical solution. All calculations are performed for NH$_{4}$Cl-H$_{2}$O and Al-Cu system.

• Journal of applied mathematics & informatics
• /
• 제29권5_6호
• /
• pp.1337-1349
• /
• 2011

So far as a solution of the given consistent linear system is concerned many numerical methods - both mathematically non-iterative as well as iterative - have been reported in the literature over the last couple of centuries. Most of these methods consider all the equations including linearly dependent ones in the system and obtain a solution whenever it exists. Since linearly dependent equations do not add any new information to a system concerning a solution we have proposed an algorithm that identifies them and prunes them in the process of solving the system. The pruning process does not involve row/column interchanges as in the case of Gauss reduction with partial/complete pivoting. We demonstrate here that the use of pruning as an inbuilt part of our solution process reduces computational and storage complexities and also computational error.

• 한국환경보건학회:학술대회논문집
• /
• 한국환경보건학회 2003년도 Challenges and Achievements in Environmental Health
• /
• pp.123-127
• /
• 2003

This experiment was performed to investigate the characteristics of sonolytic reaction as the basic data for development of the ultrasonic AOP(Advanced Oxidation Process) process from which the refractory organic compounds in aqueous solution which are not readily removed by the existing conventional wastewater treatment processes can be destructed and removed. Trichloroethylene (TCE), benzene, and 2,4-dichlorophenol(DCP) were used as the samples, and their destruction efficiency were measured in terms of experimental parameters of the initial solution concentration, initial solution pH, reaction temperature, acoustic frequencies and intensities. Results showed that the destruction efficiencies of all of the sample materials were above 80% within 120 minutes of sonolytic reaction in all reaction condition. The reaction order of these three compounds was verified as Pseudo first order. From the fore-mentioned results, it can be concluded that the refractory organic compounds could be removed by the ultrasonic irradiation with radicals, such as H$.$and OH$.$causing the high increase of pressure and temperature. Finally, it appears that the new AOP technology using ultrasonic irradiation can be applied to the treatment of refractory substances which are difficult to be decomposed by the conventional methods.

• Journal of Welding and Joining
• /
• 제31권3호
• /
• pp.84-88
• /
• 2013

These days embedded technology may be the most significant development in the electronics industry. The study focused on the development of active device embedding using flexible printed circuit in view of process and materials. The authors fabricated 30um thickness Si chip without any crack, chipping defects with a dicing before grinding process. In order to embed chips into flexible PCB, the chip pads on a chip are connected to bonding pad on flexible PCB using an ACF film. After packaging, all sample were tested by the O/S test and carried out the reliability test. All samples passed environmental reliability test. In the future, this technology will be applied to the wearable electronics and flexible display in the variety of electronics product.

• 한국정보과학회논문지:소프트웨어및응용
• /
• 제30권9호
• /
• pp.862-866
• /
• 2003

조합 최적화 문제인 순회 판매원 문제(Traveling Salesman Problem, TSP)를 유전자 알고리즘(Genetic Algorithm)과 Local Search Heuristic인 Lin-Kernighan(LK) Heuristic［1］을 이용하여 접근하는 것은 최적 해를 구하기 위해 널리 알려진 방법이다. 본 논문에서는 TSP 문제를 해결하기 위한 또 다른 접근법으로 ACS(Ant Colony system) 알고리즘을 소개하고 새로운 페로몬 갱신 방법을 제시하고자 한다. ACS 알고리즘은 다수의 개미들이 경로를 만들어 가는 과정에서 각 에지상의 페로몬 정보를 이용하며, 이러한 반복적인 경로 생성 과정을 통해 최적 해를 발견하는 방법이다. ACS 기법의 전역 갱신 단계에서는 생성된 모든 경로들 중 전역 최적 경로에 속한 에지들에 대하여 페로몬을 갱신한다. 그러나 본 논문에서는 전역 갱신 규칙이 적용되기 전에 생성된 모든 에지에 대하여 페로몬을 한번 더 갱신한다. 이 때 페로몬 갱신을 위해 각 에지들의 발생 빈도수를 이용한다. 개미들이 생성한 전체 에지들의 발생 빈도수를 페로몬 정보에 대한 가중치(weight)로 부여함으로써 각 에지들에 대하여 통계적 수치를 페로몬 정보로 제공할 수 있었다. 또한 기존의 ACS 알고리즘보다 더 빠른 속도로 최적 해를 찾아내며 더 많은 에지들이 다음 번 탐색에 활용될 수 있게 함으로써 지역 최적화에 빠지는 것을 방지할 수 있다.

• Journal of Photoscience
• /
• 제3권3호
• /
• pp.121-125
• /
• 1996

Quantum yield of photoisomerization of degassed n-hexane solution of all-trans-retinal (1) and all-trans-1, 4-diphenylbutadiene (4) at 25$\circ$C under direct irradiation conditions increases as the concentrations of 1 and 4 increase. Further, fluorescence lifetime of 4 at ambient temperature is also found to increase as the concentrations of 4 are increased. The results are discussed in terms quantum chain process which occurs due to exchange of energy between various conformers of the compounds concerned.

• 한국분말재료학회지
• /
• 제23권4호
• /
• pp.311-316
• /
• 2016

$Ni(OH)_2$ hollow spheres have been prepared by solvent displacement crystallization using a micro-injection device, and the effect of process parameters such as concentration and the relative ratio of the injection speed of the precursor solution, which is an aqueous solution of $NiSO_4{\cdot}6H_2O$, to isopropyl alcohol of displacement solvent have been investigated. The crystal phases after NaOH treatment are in the ${\beta}-phase$ for all process parameters. A higher concentration of $NiSO_4{\cdot}6H_2O$ aqueous solution is injected by a micro-injection device and bigger $Ni(OH)_2$ hollow spheres with a narrower particle size distribution are formed. The crystallinity and hardness of the as-obtained powder are so poor that hydrothermal treatment of the as-obtained $Ni(OH)_2$ at $120^{\circ}C$ for 24 h in distilled water is performed in order to greatly improve the crystallinity. It is thought that a relative ratio of the injection speed of $NiSO_4{\cdot}6H_2O$ to that of isopropyl alcohol of at least more than 1 is preferable to synthesize Ni(OH)2 hollow spheres. It is confirmed that this solution-based process is very effective in synthesizing ceramic hollow spheres by simple adjustment of the process parameters such as the concentration and the injection speed.

• 지능정보연구
• /
• 제6권2호
• /
• pp.29-40
• /
• 2000

Process planning (selection and ordering of processes) and material selection for product manufacturing are two key things determined before taking full-scale manufacturing. Knowledge on product design. material characteristics, processes, time and cost all-together are mutually related and should be considered concurrently. Due to the complexity of problem, human experts have got only one of the feasilbe solutions with their field knowledge and experiences. We propose a hierarchical expert system framework of knowledge representation and reasoning in order to overcome the complexity. Manufacturing processes have inherently hierarchical relationships, from top level processes to bottom level operation processes. Process plan of one level is posted in process blackboard and used for lower level process planning. Process information on blackboard is also used to adjust the process plan in order to resolve the dead-end or inconsistency situation during reasoning. Decision variables for process, material, tool, time and cost are represented as object frames, and their relationships are represented as constraints and rules. Constraints are for relationship among variables such as compatibility, numerical inequality etc. Rules are for causal relationships among variables to reflect human expert\`s knowledge such as process precedence. CRSP(Constraint and Rule Satisfaction Problem) approach is adopted in order to obtain solution to satisfy both constraints and rules. The trade-off procedure gives user chances to see the impact of change of important variables such as material, cost, time and helps to determine the preferred solution. We developed the prototype system using visual C++ MFC, UNIK, and UNlK-CRSP on PC.

• Bulletin of the Korean Chemical Society
• /
• 제35권5호
• /
• pp.1343-1348
• /
• 2014

A cholesterol-bridge-naphthopyran dyad (NP-MCB) was designed and synthesized. NP-MCB can readily self-assemble into gels under ultrasound-radiation in several organic solvents and the formed gels easily transfer to solution by heat. This reversible process can be repeated many times. Scanning Electron Microscopy results showed that the morphologies of all formed xerogels in different solvents have fibrillar microstructure. The gels formation was due to energy and pressure afforded by the ultrasonic process, resulting in formation of molecular hydrogen bonding and molecular aggregation. NP-MCB displayed the normal photochromism both in solution and gel states. The kinetic results confirm that the colored merocyanine in gels show a slower fading speed than that in solution due to the compact aggregation of NP-MCB molecules in gels. The xerogel film formed in polar gelling solvent had large surface wettability than that in nonpolar gelling solvent.

• The Korean Journal of Ceramics
• /
• 제4권3호
• /
• pp.199-203
• /
• 1998

$Pb(Zr, Ti)O_3$ (Pb:Zr:Ti=1:0.52:0.48) thin films were prepared on single crystal MgO(100) substrates by dipping-pyrolysis process using a solution of constituent metal naphthenates as starting materials. The solution was spin-coated onto substrate and the precursor films were pyrolyzed at $200^{\circ}C$ in air or at $200^{\circ}C$ in argon for 1, 2, 5 and 24h, followed by final heat treatment at $750^{\circ}C$. For all the films, highly (h00)/(00l)-oriented Pb$Pb(Zr, Ti)O_3$ thin films with smooth surfaces and crack-free were obtained, whereas thin film pyrolyzed in air for 24 h exhibited polycrystalline character. According to the pole-figure analysis, epitaxy of the product films was found to depend on pyrolysis atmosphere.