• Title/Summary/Keyword: Alkali activated

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An Experimental Study on the Chloride Attack Resistibility of Alkali-Activated Ternary Blended Cement Concrete (알칼리 활성화 3성분계 혼합시멘트의 염해 저항성에 관한 실험적 연구)

  • Yang, Wan-Hee;Hwang, Ji-Soon;Jeon, Chan-Soo;Lee, Sea-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.321-329
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    • 2016
  • The use of ternary blended cement consisting of Portland cement, granulated blast-furnace slag (GGBFS) and fly ash has been on the rise to improve marine concrete structure's resistance to chloride attack. Therefore, this study attempted to investigate changes in chloride attack resistibility of concrete through NT Build 492-based chloride migration experiments and test of concrete's ability to resist chloride ion penetration under ASTM C 1202(KS F 2271) when 1.5-2.0% of alkali-sulfate activator (modified alkali sulfate type) was added to the ternary blended cement mixtures (40% ordinary Portland cement + 40% GGBFS + 20% fly ash). Then, the results found the followings: Even though the slump for the plain concrete slightly declined depending on the use of the alkali-sulfate activator, compressive strength from day 2 to day 7 improved by 17-42%. In addition, the coefficient from non-steady-state migration experiments for the plain concrete measured at day 28 decreased by 36-56% depending on the use of alkali-sulfate. Furthermore, total charge passed according to the test for electrical indication of concrete's ability to resist chloride ion penetration decreased by 33-62% at day 7 and by 31-48% at day 28. As confirmed in previous studies, reactivity in the GGBFS and fly ash improved because of alkali activation. As a result, concrete strength increased due to reduced total porosity.

Alkali activated ceramic waste with or without two different calcium sources

  • Zedan, Sayieda R.;Mohamed, Maha R.;Ahmed, Doaa A.;Mohammed, Aya H.
    • Advances in materials Research
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    • v.4 no.3
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    • pp.133-144
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    • 2015
  • The aim of this investigation is to prepare geopolymer resin by alkali activation of ceramic waste (AACW) with different sodium hydroxide (NaOH) and liquid sodium silicate (LSS) concentrations. In order to prepare geopolymer cement, AACW was replaced by 10 and 30 % by weight (wt.,) of concrete waste (CoW) as well as 10 and 30 wt., % ground granulated blast-furnace slag (GGBFS). The results showed that, the compressive strength of AACW increases with the increase of activator content up to 15:15 wt., % NaOH: LSS. All AACW hardened specimens activated by 3:3 (MC6), 6:6 (MC12), 12:12 (MC24) and 15:15 wt., % (MC30) NaOH: LSS destroyed when cured in water for 24h. The MC18 mix showed higher resistivity to water curing. The results also showed that, the replacement of AACW containing 9:9 wt., % NaOH: LSS (MC18) by 10 (MCCo10) and 30 (MCCo30) wt., % CoWdecreased the compressive strength at all ages of curing. In contrast, the MCCo10 mix showed the lower chemically combined water content compared to MC18 mix. The MCCo30 mix showed the higher chemically combined water content compared to MC18 and MCCo10 mixes. The compressive strength and chemically combined water of all AACWmixes containing GGBFS (MCS10 and MCS30) were higher than those of AACWwith no GGBFS (MC18). As the amount of GGBFS content increases the chemically combined water increases. The x-ray diffraction (XRD) proved that as the amount of CoWcontent increases, the degree of crystallinity increases. Conversely, the replacement of AACW by GGBFS leads to increase the amorphiticity character. The infrared spectroscopy (FTIR) confirms the higher reactivity of GGBFS compared to CoW as a result of successive hydration products formation, enhancing the compaction of microstructure as observed in scanning electron microscopy (SEM).

The Strength and Drying Shrinkage Properties of Alkali-Activated Slag Mortars as the Particle Size of Blended Fine Aggregate (혼합 잔골재의 입자 크기에 따른 알칼리 활성화 슬래그 모르타르의 강도와 건조수축 특성)

  • Kim, Tae Wan
    • Journal of the Korea Concrete Institute
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    • v.27 no.3
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    • pp.273-281
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    • 2015
  • In this paper, the performance of alkali-activated slag cement (AASC) is assessed in terms of compressive strength and drying shrinkage, using three different types of silica sand and river sand. The sand type has an important influence on the properties of AASC mortar. Three silica sands (SS1, SS2 and SS3) and river sand (RS) were considered. Three series of blended sands have been tested. A first series (S1) with RS and SS1, a second series (S2) with RS and SS2 and third series (S3) with RS and SS3 with a different blended ratios. The result shows a very significant influence of the blended sand on the AASC mortar properties. The compressive strength and drying shrinkage related with the particle sizes and blended ratios of sands are investigated considering blended sand properties like fineness modulus (FM) and relative specific surface. The type and blended ratio of sand seems to have very significant and important consequences for the mix design of the AASC mortar.

Effects of Basicity on the Carbonation Characteristics of Alkali-Activated Slag Mortar (염기도가 알칼리 활성고로슬래그 모르타르의 탄산화에 미치는 영향)

  • Song, Keum-Il;Lee, Bang-Yeon;Hong, Geon-Ho;Gong, Min-Ho;Song, Jin-Kyu
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.577-584
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    • 2012
  • Carbonation resistance is one of the most influencing factors on durability of concrete. Alkali activated slag (AAS) is known to have weaker resistance for carbonation than OPC due to the low calcium contents. In this paper, the carbonation characteristic of AAS mortar which is related to the basicity (CaO/$SiO_2$) was investigated. In order to give the various basicity conditions, SM (source material) was blended with quicklime (CaO) and silicon dioxide ($SiO_2$) by adopting mechano-chemical treatment method. Experiments including flow test, compressive strength test, carbonation depth test, together with XRD, FTIR and TGA were employed to evaluate the effects of basicity of SM on the carbonation characteristics. The test results showed that the carbonation resistance effectively increased with the increase of the basicity of SM.

Practical Application of GGBS-Based Alkali-Activated Binder to Secondary Products of Concrete (고로슬래그 기반 알카리 활성 결합재의 콘크리트 2차 제품 적용성 평가)

  • Sim, Jae-Il;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.5
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    • pp.37-44
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    • 2010
  • This study examined the practical application of ground granulated blast-furnace slag (GGBS) based alkali-activated (AA) binders for the development of cementless environmental-friendly secondary products of concrete, such as brick, shore protection blocks and interlocking blocks. The addition amount and type of alkaline ion to activate GGBS varied according to the diverse qualities of the secondary products of concrete required in Korean industrial standards (KS) and other specifications. Test results showed that the secondary products of concrete using GGBS-based AA binders surpassed the demanded capacities of KS and other specifications. In addition, shore protection block had a pH value close to neutral, enabling an advantageous environment for marine life. Therefore, the GGBS-based AA binders can be effectively applied to develop eco-friendly secondary products of concrete with reduced $CO_2$.

Effects of Alkali-Activated Soil Stabilizer Binder Based on Recycling BP By-Products on Soil Improvement (BP부산물을 재활용한 알칼리활성화 지반개량재의 지반개량효과에 관한 연구)

  • Lee, Yeong-Won;Kang, Suk-Pyo;Kim, Jae-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.158-165
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    • 2014
  • The enormous quantity of 'Bayer-Process by-products' (BP by-products) discharged by industries producing alumina from bauxite represents an environmental and economical problem. As it is mainly composed of $Fe_2O_3$, $Al_2O_3$, $SiO_2$, CaO and $Na_2O$, it is thought that using BP by-products as a construction material is an effective way to consume such a large quantity of alkaline waste. In this study, This study evaluates the effect of alkali-activated binder based on recycling BP by-products on soil improvement through the evaluation of slope stability and seepage flow numerical analysis. The results of analysis of ground slope safety at dry season and wet season meet standard (Ministry of Land, Infrastructure and Transport, 2006) Especially, when wet season, the ground used soil improving material meet standard, while the ground used soil-nailing method doesn't. Also, permeability coefficient of improved soil is smaller than that of natural soil and saturation depth of reinforced ground surface with improve soil is lower than that of natural soil.

Properties of Cold Recycled Asphalt Mixtures with Alkali-activated Filler according to Wasted Asphalt Aggregate Content (폐아스콘 순환골재 혼입율에 따른 알칼리활성화 채움재 상온 재생 아스팔트 혼합물의 특성)

  • Lee, Min-Hi;Kang, Suk-Pyo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.199-206
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    • 2018
  • Due to the advantages of less raw materials and fossil fuel consumption, lower carbon footprint, and the capability of pavement performance improvement, the recycling technology of asphalt is developed and applied for road rehabilitation and construction in the western countries over the past two decades. Cold recycled asphalt mixtures are bituminous materials normally made by mixing recycled aggregate from wasted asphalt with an asphalt emulsion and water at room temperature. This paper aims at investigating the properties of cold recycled asphalt mixture with alkali-activated filler according to wasted asphalt aggregate content. As a result, as the content of wasted asphalt aggregate increased, the marshall stability of cold recycled asphalt mixture decreased and void ratio increased. Also, grading curves for cold recycled asphalt mixture as specified in GR criteria were satisfied in all aggregate mixing conditions regardless of the wasted asphalt aggregate content.

Properties of the Alkali Activated Mortar According to Metakaolin Replacement Ratio (알칼리 활성화 모르타르의 메타카올린 치환율에 따른 특성)

  • Seo, Dong-Hyeon;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.313-320
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    • 2016
  • The aim of this study is to look into the metakaolin replacement ratio of blast furnace slag based alkali activated slag mortar and its mechanical characteristics according to changes in stimulant concentration. Metakaolin has high fineness, and therefore the fluidity becomes lower as the replacement ratio becomes higher. So in this study, a sufficient value of mixing water was provided to secure fluidity for the characteristic experiment, and a different W/B was derived for each specimen in order to make the fluidity identical. A characteristic experiment was conducted according to the mol concentration of NaOH, which was used as the mixing water that affects fluidity. Additionally, compressive strength measurement, observation of inner microstructure through SEM, acid resistance experiment, and neutralization resistance was conducted. The results of this study revealed that for a high concentration NaOH solution to have even fluidity, a high W/B is necessary, and the functions were enhanced, not degraded.

Compressive Strength and Tensile Behavior of Ultra-High Performance Concrete and High-Ductile Cementless Composite (초고성능 콘크리트와 고연성 무시멘트 복합재료의 압축 및 인장성능)

  • Choi, Jeong-Il;Park, Se Eon;Lee, Bang Yeon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.69-75
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    • 2017
  • Ultra-high performance concrete and high ductile cementless composite are considered as promising construction materials because those exhibits higher performance in terms of high strength and high ductility. The purpose of this study is to investigate experimentally the compressive strength and tensile behavior of ultra-high performance concrete and high ductile cementless composite. A series of experiments including density, compressive strength, and uniaxial tension tests were performed. Test results showed that the compressive strength and tensile strength of alkali-activated slag based high ductile cementless composite were lower than those of ultra-high performance concrete. However, the tensile strain capacity and toughness of alkali-activated slag based high ductile cementless composite were higher than those of ultra-high performance concrete. And it was exhibited that a high ductility up to 7.89% can be attainable by incorporating polyethylene fiber into the alkali-activated slag based cementless paste.

Analytical Study on Flexural Behavior of Alkali-Activated Slag-Based Ultra-High-Ductile Composite (알칼리활성 슬래그 기반 초고연성 복합재료의 휨거동 해석)

  • Lee, Bang Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.158-165
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    • 2019
  • The purpose of this study is to investigate analytically the flexural behavior of beam reinforced by an alkali-activated slag-based fiber-reinforced composite. The materials and mixture proportion were selected to manufacture an alkali-activated slag-based fiber-reinforced composite with high tensile strain capacity over 7% and compressive strength and tension tests were performed. The composite showed a compressive strength of 32.7MPa, a tensile strength of 8.43MPa, and a tensile strain capacity of 7.52%. In order to analyze the flexural behavior of beams reinforced by ultra-high-ductile composite, nonlinear sectional analysis was peformed for four types of beams. Analysis showed that the flexural strength of beam reinforced partially by ultra-high-ductile composite increased by 8.0%, and the flexural strength of beam reinforced fully by ultra-high-ductile composite increased by 24.7%. It was found that the main reason of low improvement in flexural strength is the low tensile strain at the bottom of beam. The tensile strain at bottom corresponding to the flexural strength was 1.38% which was 18.4% of tensile strain capacity of the composite.