• Clean Technology
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• v.26 no.4
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• pp.239-250
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• 2020

Biomass is an abundant renewable energy resource that can replace fossil fuels for the reduction of greenhouse gas (GHG). Indonesia has a large number of cheap biomass feedstocks, such as reforestation (waste wood) and palm residues (empty fruit bunch or EFB). In general, raw biomass contains more than 20% moisture and lacks calorific value, energy density, grindability, and combustion efficiency. Those properties are not acceptable fuel attributes as the conditions currently stand. Recently, torrefaction facilities, especially in European countries, have been built to upgrade raw biomass to solid fuel with high quality. In Korea, there is no significant market for torrefied solid fuel (co-firing) made of biomass residues, and only the wood pellet market presently thrives (~ 2 million ton yr-1). However, increasing demand for an upgraded solid fuel exists. In Indonesia, torrefied woody residues as co-firing fuel are economically feasible under the governmental promotion of renewable energy such as in feed-in-tariff (FIT). EFB, one of the chief palm residues, could replace coal in cement kiln when the emission trading system (ETS) and clean development mechanism (CDM) system are implemented. However, technical issues such as slagging (alkali metal) and corrosion (chlorine) should be addressed to utilize torrefied EFB at a pulverized coal boiler.

• Clean Technology
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• v.27 no.2
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• pp.168-173
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• 2021

The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.2
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• pp.133-142
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• 2022

The purpose of this study is to develop an impact crusher with a radial rotating plate installed at the bottom, which is a shock absorber that can produce high-quality recycled coarse aggregate for concrete and to verify the effect of improving the quality performance of recycled coarse aggregate and its applicability through concrete tests. As a result, it showed improved quality in all items such as absolute dry density, absorption rate, abrasion resistance, Particle shape judgment rate, amount lost in the 0.08 mm sieve passing test, alkali aggregate reaction, clay mass, stability, and impurity content, and it was found to meet the criteria of recycled aggregate quality standards. In addition, the air volume and slump of concrete to which recycled coarse aggregate is applied meet all domestic standards. According to the test results of the compressive strength characteristics by age of concrete according to the mixing ratio of the recycled coarse aggregate, it was confirmed that the mixing ratio of the recycled coarse aggregate was applicable up to 60 %.

• Journal of the Korean Wood Science and Technology
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• v.32 no.1
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• pp.28-34
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• 2004

This study was performed to evaluate the characteristics of the carboxymethylated substrate from high reactive autohydrolyzed cellulose (HRC) and those of commercial α-cellulose (CAC) and refiner mechanical pulp (RMP). Saccharification rates of HRC substrate were achieved over 70% with 12 hr hydrolysis, about 90% with 24 hr, and 99.5% with 72 hr. CMCase and avicelase activities of cellulase onozuka were 4.09 ㎛ G/mg·min and 14.0 ㎛ G/mg·min, respectively. There were no any significant changes in cellulase activities with this substrate. The saccharification rates of CAC and RMP were very low, 57% and 38% with 72 hr, respectively. Those lignin-zero autohydrolyzed substrates, HRC and CAC, were highly carboxymethylated at the high alkali concentration, near 30%, for 3 hr. reaction, and resulted in 1.13-1.15 of D.S., besides 0.85 of D.S. from RMP. Water solubilities of carboxymethylated substrates were increased with an increase of D.S., 98-98.5% from HRC and CAC and 31.5% from RMP. RMP which has low specific surface area showed lower water retention values, compared to high values of 435 and 321% from CAC and HRC, respectively. There were no direct relationship between surface area and swelling ratio of the substrates.

• The Journal of Engineering Geology
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• v.31 no.1
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• pp.67-81
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• 2021

Grouting is used for reinforcement and waterproofing of soft ground to increase its bearing capacity, reduce the impacts of rising or lowering groundwater levels, and reduce subsidence due to vibration and general causes. This study investigated the enhancement of grout strength and hardening time by the addition of reinforcing fibers, and the development of non-cement grouting materials from blast furnace slag. An experiment was performed to measure the increase in grout strength resulting from the addition of 0.5% increments of aramid and carbon reinforcing fibers. The results show that the uniaxial compressive strength of grout increases with increasing content of reinforcing fiber. Comparison of three admixtures of finely powdered blast furnace slag and 10%, 20%, and 30% calcium hydroxide stimulating agent showed that the uniaxial compressive strength of the mixture increases with increasing content of alkaline stimulant; however, the strength was lower than for 100% pure cement. The reaction of calcium hydroxide with blast furnace slag powder, which increases the strength of the grout, is more effective if injected as a solution rather than a powder.

• Journal of Conservation Science
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• v.37 no.2
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• pp.77-89
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• 2021

In this study, materials and color formation techniques were assessed for black potteries excavated from the Janghyeon-dong, Jungsan-dong and Gyodong-ri sites during the Proto-Three Kingdoms period in Ulsan, Korea. Although the black potteries were black superficially, the inner cores were either black or reddish yellow. Microscopy analysis identified that body clay was used for reddish iron oxide rich soils with quartz, alkali feldspar and mica, along with grains of myrmechite texture. Additionally, as marginal differences exist in the contents of SiO₂, Fe₂O₃ and CaO, the composition of the host rock and clay distributed around the sites was affected. Thus, we can deduce that pottery was made by soiling at a short distance. Raman spectroscopy results revealed that the black layer of the black pottery was used as amorphous combustion carbon. In addition, as a transparent layer of brown lacquer was observed on the substrate that was in contact with the surface layer, the black layer of the pottery induced black color development by a combination of combustion carbon and lacquer. Based on the mineral composition and microtexture of the body clay, the firing temperature of the potteries seemed to range from 750 to 850℃, whereas the lacquer layer was pyrolyzed at 468℃ by thermal analysis. Therefore, a combined layer of combustion carbon and lacquer, which formed the black color, was painted after the body clay was fired.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.4
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• pp.457-467
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• 2022

Electron bombardment to silicate glass during electron probe microanalysis (EPMA) causes outward migration of Na from the excitation volume and subsequent decrease in the measured X-ray count rates of Na. To acquire precise Na₂O content of silicate glass, one should use proper analytical technique to avoid or minimize Na migration effect or should correct for decreases in the measured Na X-ray counts. In this study, we analyzed 8 silicate glass standard samples using automated Time Dependent Intensity (TDI) correction method of Probe for EPMA software that can calculate zero-time intercept by extrapolating X-ray count changes over analysis time. We evaluated an accuracy of TDI correction for Na measurements of silicate glasses with EPMA at 15 kV acceleration voltage and 20 nA probe current electron beam, which is commonly utilized analytical condition for geological samples. Results show that Na loss can be avoided with 20 ㎛-sized large beam (<0.1 nA/㎛²), thus silicate glasses can be analyzed without TDI correction. When the beam size is smaller than 10 ㎛, Na loss results in large relative errors up to -55% of Na₂O values without correction. By applying TDI corrections, we can acquire Na₂O values close to the reference values with relative errors of ~ ±10%. Use of weighted linear-fit can reduce relative errors down to ±6%. Thus, quantitative analysis of silicate glasses with EPMA is required for TDI correction for alkali elements such as Na and K.

• Journal of the Korean Wood Science and Technology
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• v.32 no.5
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• pp.75-85
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• 2004

The natural dyes from Gardenia jasminoides, Carthamus tinctorius L., Rhus javanica, Lithospermum erythrorhizon, Caesalpinia sappan L., and Castanea crenata were extracted under different pH in distilled water, As the pH in distilled water went from acid to alkali, the much deeper colors in the same color tone were generated from the individual plant species. Before dyeing, wood species were treated by different mordants including AI, Cu, Cr and Fe for color-fixing between wood and the natural dyes. Each mordant could develop independent color on the surface of the woods. The wood species dyed by the natural dyes created deep-tone colors according to higher pH and temperature of the dyeing solution, leading to deeper penetration of the dyes into the wood tissues. Finally through the computer modelling of natural-dyed wood furniture, it was confirmed that the colored furniture can adequately be compatible with the current interior spaces of diverse colors.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.377-386
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• 2022

In addition to anthropogenic origins, fluorine (F) is naturally enriched in rocks due to geological events, such as magma dissemination, hydrothermal alteration, mineralization, and fault activities. Generally, it has been well known that F is chiefly enriched in the region of igneous and metamorphic rocks, and biotite granite was mostly distributed in the study area. The F enrichment mechanism was not sufficiently elucidated in the previous studies, and the study on a fault zone was conducted to reveal it more precisely. The mineral composition of the fault zone was identical to that of the Eulwangsan biotite granite (EBG), but they were quantitatively different between the two areas. Compared with the EBG, the fault zone showed relatively higher contents of quartz and F-bearing minerals (fluorite, sericite) but lower contents of plagioclase and alkali feldspar. This difference was likely due to hydrothermal mineral alterations. The results of microscopic observations supported this, and the generation of F-bearing minerals by hydrothermal alterations was recognized in most samples. Accordingly, it might be interpreted that the mineralogical and petrological differences observed in the same-age biotite granite widely distributed in the Yongyudo was caused by the hydrothermal alterations due to small-scale geological events.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.39 no.1
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• pp.92-97
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• 1994

The reports on the chemical composition of developing job's tears seeds is very insufficient by this time. The purpose of this study was to obtain the fundamental information on chemical component of the developing job's tears seed, including starch, sugar, oil, protein, fatty acid, Alkali Digestibility Value(ADV), 100-grain weight. Two job's tears varieties in different by maturity types were analyzed for those components from 10 days after heading to maturity, with 5-day intervals. Total sugar content in seeds followed a pattern of linear increase after heading, but it started to decreased around 15 days after heading. On the other hand, starch content continued to increased until maturity and the highest increasing occurred between 15 and 20 days after heading. The protein content of seeds was decreased, while oil content was increased through the ripening process. Starch content showed a positive correlation with 100-grain weight, ADV, oil and germination percent, but it had negative correlation between total sugar and protein contents in ripening process. Maximum starch content, 100 grain weight, and germination percent obtained by quadratic equation were attained 38 to 43 days after heading. So that the physiological maturity of job's tears seeds was considered to be 40 days after heading.