• Title/Summary/Keyword: Alkali

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Geochemistry and Metamorphism of the Gneisses in Gwangyang-Hadong Area (광양-하동지역에 분포하는 편마암류의 지구화학 및 변성작용)

  • Park, Bae-Young;Suh, Gu-Won
    • Journal of the Korean earth science society
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    • v.29 no.3
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    • pp.221-245
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    • 2008
  • The precambrian granitic gneiss and porphyroblastic gneiss are widely distributed in the Gwangyang-Hadong area of Korea. This study focuses on the geochemical properties and metamorphic P-T conditions of these gneisses. These gneisses are plotted according to granodiorite domain on an IUGS silica-alkali diagram. Geochemical properties of major elements suggest that these rocks are of the sub-alkalic rock series, and were farmed from S-type magmas which were generated in a syn-collision tectonic environment. The amounts of trace elements (Zn, Sc, Sr, V, etc.) decreased as $SiO_2$ concentrations increased. Almandine and spessartine mol%'s and XFe are higher in garnet rims, while pyrope mol%'s are higher in the garnet cores. This seems to be the result of garnet growth and retrogressive metamorphism. Metamorphic zones are divided into sillimanite-cordierite, sillimanite, garnet, and biotite zones. Metamorphic P-T conditions estimated from the gneisses indicate high temperature and low to medium pressure metamorphism (689-757$^{\circ}C$, 5.0-5.6 kbar), followed by medium temperature, low pressure retrorade metamorphism (579-628$^{\circ}C$, 3.1-4.5 kbar), and overprinted retrogade metamorphism (502-558$^{\circ}C$, 1.6-2.3 kbar).

Synthesis of Mesoporous Silica Using Municipal Solid Waste Incinerator Ash Slag : Influence of NaOH Concentration (생활(生活) 폐기물(廢棄物) 소각재(燒却材) 슬래그를 이용(利用)한 메조포러스 실리카 합성(合成) : NaOH 농도(濃度)의 영향(影響))

  • Han, Yo-Sep;Jung, Jong-Hoon;Park, Jai-Koo
    • Resources Recycling
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    • v.19 no.1
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    • pp.40-48
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    • 2010
  • It was investigated that effects of NaOH concentration on synthesis of mesoporous materials using municipal solid waste incinerator ash slag (MSWI-ash slag). In order to increase the purity and maximize the amount of extracted Si content the raw MSWI-ash slag was mechanically activated. Extraction of Si from the MSWI-ash slag was carried out by alkali treatment using concentrated NaOH solution, which varied from 1M to 4M. Physical properties (i.e., pore size, specific surface area and total pore volume) of the synthesized mesoporous silica were also evaluated as a function of NaOH concentration via BET, SEM, TEM and small-angle X-ray scattering analyses. Over the entire range of NaOH concentration investigated (i.e., 1-4M), the synthesized mesoporous materials were determined to be SBA-15, which exhibited a hexagonal structure with the pore size of approximately 7 nm. On the other hand, specific surface area and total pore volume increased with NaOH concentration up to 3M while the values decreased at 4M, indicating that the optimal NaOH concentration for the synthesized mesoporous silica was approximately 3M. Further comparison analysis between two conditions (3M versus 4M) showed that the decrease in two physical properties at 4M NaOH concentration was likely due to the potential inhibition by excess Na ions on the formation of mesophase and the consequent increase of pore wall thickness by remaining Si ions.

Physical and Chemical Properties of Chlorine Bypass System-Dust from Cement Manufacturing (시멘트 생산 시 발생하는 Chlorine Bypass System-dust의 물리 및 화학적 특성)

  • Han, Min-Cheol;Lee, Dong-Joo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.310-315
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    • 2019
  • This study conducted a series of studies to find alternative ways to use Chlorine Bypass System-dust(CBS-dust) in cement production. The results of engineering characteristics of CBS-dust are summarized as follows. First of all, the density of CBS-dust is 2.40, lighter than cement and the pH was 12.50 which was strong alkaline. In terms of particle size, it was 11.70 ㎛ which was finer than cement. With chemical properties, calcium oxide(CaO) was the highest as 35.10%, potassium oxide(K2O) was 32.43%, potassium chloride(KCl) was 19.46%, sulfur oxide(SO3) was 6.81%, and the remaining chemical components are SiO2, Fe2O3, Al2O3, MgO, and the like. Therefore, if CBS-dust is used as early-strength chemical admixtures in the concrete secondary products that use a large amount of mineral admixtures without rebar, it can be an effective method for increasing the strength of concrete as an alkali activator and preventing early-frost damage of Cold Weather Concrete.

Quantitative Deterioration Assessment and Microclimatic Analysis of the Gyeongju Seokbinggo (Ice-storing Stone Warehouse), Korea (경주석빙고의 정량적 훼손도 평가와 미기후환경 분석)

  • Kim, Ji-Young;Lee, Chan-Hee;Lee, Myeong-Seong
    • Journal of Conservation Science
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    • v.25 no.1
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    • pp.25-38
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    • 2009
  • The Gyeongju Seokbinggo (Treasure No. 66) is an ice-storing stone warehouse, consisting mainly of alkaligranite which shows milky white color and medium-grained textures with drusy cavities. As results of deterioration assessment, the deterioration rates were determined as crack (12.5%), disjoining (6.7%), breaking-out (25.1%), exfoliation (20.9%), efflorescence (6.5%), brown discoloration (9.8%), darkgray discoloration (2.0%) and biological discoloration (36.5%). Comprehensive physical deterioration rate and discoloration rate were calculated as 43.7% and 68.7%, respectively, that indicates the Seokbinggo has been severely weathered. Indoor relative humidity was above 90% except in winter season. Indoor microclimate was hardly fluctuating although indoor microclimate was dependent on the outdoor climate. The main cause of deterioration was high relative humidity and a long time of wetness due to penetration of rain, underground water and condensation. It was identified that the water brought out biological discoloration, dissolution of minerals, structural movement and efflorescence, and the dust from the ground soil in front of the entrance accelerated brown and dark gray discoloration on the stone surface.

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Changes in Contents of Nutritional Components and Eating Quality of Brown Rice by Pericarp Milling (과피층 제거에 따른 현미의 이화학특성 및 현미밥의 식감변화)

  • Kim, Hye-Won;Oh, Sea-Kwan;Kim, Dae-Jung;Yoon, Mi-Ra;Lee, Jeong-Heui;Choi, Im-Soo;Kim, Yeon-Gyu;Cha, Kil-Nam
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.1
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    • pp.35-40
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    • 2012
  • In this study, the effect of degree of milled wax layer on compositions (protein and total dietary fiber content), Alkali Digestion Value (ADV), and texture (hardness, stickiness, toughness, and adhesiveness) with brown rice was investigated. For all the rice cultivars, $Baegjinju$, $Keunnun$, $Samkwang$, and $Seolgaeng$, protein content decreased significantly as the degree of pericarp milling increased ($p$<0.05). Total dietary fiber (TDF) content for $Keunnun$ (9.56%${\rightarrow}$8.09%) and $Samkwang$ (8.05%${\rightarrow}$7.06%) significantly decreased with the degree of removed wax layer. ADV was not affected by being removed wax layer, but ADV of $Samkwang$ was increased from 3.56 to 6.78. As the degree of removed wax layer increased (0%${\rightarrow}$10%), hardness and toughness of cooked brown rice were decreased but stickiness and adhesiveness was increased. The ratio of adhesiveness to hardness was increased with decreased wax layer of brown rice. Accordingly, It suggests that the regulation of the wax layer with brown rice was effected texture of cooked brown rice. The milling technology in wax layer of brown rice is that might be thought to be very useful in rice processing industry.

Petrology of Jurassic Granitoids in the Hamyang-Geochang Area, Korea (함양(咸陽)-거창(居昌) 지역(地域), 쥬라기 화강암류(花崗岩類)의 암석학적(岩石學的) 연구(硏究))

  • Lee, Cheol-Lag;Lee, Yoon-Jong;Hayashi, Masao
    • Economic and Environmental Geology
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    • v.25 no.4
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    • pp.447-461
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    • 1992
  • The Jurassic granitoids in the study area are divided into the "Gneissose granodiorite" and the "Daebo granodiorite" (1 : 250,000 Jeonju Geological map, 1973). The term of Geochang granodiorite was used in this study instead of "Daebo granodiorite". These granitoids were studied in terms of microscopic observation, petrochemistry, and zircon morphology. The granitoids are mostly granodiorite. Two kinds of progressive variation can also be recognized in the modal quartz~alkali feldspar~plagioclase triangular diagram; the Gneissose granodiorite is in accordance with the trondhjemitic (low k) trend, and the Geochang granodiorite with the granodioritic trend (medium k). The granitoids belong to the calc-alkaline series, and are classified into the I-type (magnetite series). Plagioclase ($An_{25.1}{\sim}An_{30.9}$) in the granitoids shows generally an oligoclase composition. Biotite has a wider range in (Si, Al) solution than in (Fe, Mg) solid solution. Hornblende occurs in a few thin sections of the Geochang granodiorite, and is plotted in the tschermakite field. The zircon prism shows a long variation between the {110} dominant type and the {100} dominant type in the Geochang granodiorite, but only the {110}={100} type in the Gneissose granodiorite. However, zircon crystals in the granitoids are mostly crystallized in a low-to-medium temperature magma. In the PPEF (Prism- Pyramid-Elongation-Flatness) diagram, the Gneissose granodiorite shows a closed scissors type, the Geochang granodiorite, a opened scissors type. It indicates that the Geochang granodiorite might originate from the mixed magma with crustal materials or pre-existed residual magma which had formed the Gneissose granodiorite.

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Safe and easy disposal of prochloraz wastewaters after used as rice seed disinfectant (벼 종자소독 후 prochloraz 폐액의 안전 폐기 방법)

  • Park, Byung-Jun;Choi, Ju-Hyeon;Kim, Chan-Sub;Lee, Byung-Moo;Ihm, Yang-Bin;Cho, Il-Kyu
    • The Korean Journal of Pesticide Science
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    • v.7 no.3
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    • pp.169-175
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    • 2003
  • For safe and easy disposal of prochloraz wastewaters after used as rice seed disinfectant in Korean farms, this experiment was carried out. By addition of several agricultural materials commonly utilizing in farmers, removal effect of prochloraz from waste solution was also investigated. When rice seeds after soaking in diluted prochloraz solution were rinsed with water several times, prochloraz was removed $9.2\sim10.6%$ at the first rinse and less than 3 % at the fourth rinse. A half life of prochloraz was $4\sim5$ days in aqueous system. Hydrolysis of prochloraz was more rapidly in alkali solution than neutral and acidic one at $25^{\circ}C$ and $35^{\circ}C$. By the irradiation under $5530J/cm^2$ using xenone lamp, prochloraz was photo-degraded to 87.7% in aqueous system. The removal efficiency of prochloraz by addition of several agricultural materials were as follows: 93.6% by lime, 90.7% by composed pig manure, 89.4% by activated charcoal, 78.0% by straw ash, 70.3% by sandy loam soil, 47.0% by zeolite and 24.1 % by rice straw. When prochloraz solution was sprayed on the field soil, it was dissipated upto 90% within 35 days.

A Study on the Strength Property of Recycled Fine Aggregate (Wet Type) Mortar with Blast Furnace Slag (고로슬래그를 사용한 습식 순환 잔골재 모르타르의 강도 특성에 관한 연구)

  • Shim, Jong-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.5
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    • pp.153-160
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    • 2010
  • This study aims to obtain technical data for improvement of utilization of Blast Furnace Slag(BFS), recycled aggregate in the future by complementing fundamental problems of BFS such as manifestation of initial strength and excessive alkali quantity as well as weakness of recycled fine aggregate through manufacturing of recycled fine aggregate mortar using BFS. The recycled aggregate includes the cement paste hardened as the surface and the type of the aggregate, which contains plenty of calcium hydroxide($Ca(OH)_2$) as well as the unhydrated cement. Accordingly, the objectives of this study are to inspect the manufacturing the recycled fine aggregate mortar used with blast furnace slag, to consider the effects of the recycled aggregate on the strength development of ground granulated blast furnace slag, and then to acquire the technical data to take into consideration the further usages of the recycled aggregate and blast furnace slag. In eluted ions from recycled aggregate, it showed that there were natrium($Na^+$) and kalium($K^+$), expected to be flown out of unhydrated cement, as well as calcium hydroxide($Ca(OH)_2$). Application of this water to mix cement mortar with ground granulated blast furnace slag was observed to expedite hydration as calcium hydroxide($Ca(OH)_2$) and unhydrated cement component were expressed to give stimuli effects on ground granulated blast furnace slag. The results of the experiment show that the recycled aggregate mixed with blast furnace slag has comparatively higher hydration activity in 7 day than the mortar not mixed with one in 3 day mortar does, causing the calcium hydroxide in the recycled fine aggregate to work on as a stimulus to the hydration of ground granulated blast furnace slag.

Geochemical Experiment for Effective Treatment of Abandoned Mine Wastes (광산폐석의 효과적 처리를 위한 지화학적 연구)

  • 이진국;이재영
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.31-44
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    • 1998
  • The geochemical experiments were carried out to investigate a removal effect of heavy metals in abdndoned metallic mine wastes, and to conceive a treatment techniques of them. In order to prevent contamination, experiment appature was made of acrylic acid resin and polyethylene which resist to acid and alkali. Experiment models are devided into four groups based on the system environments, distribution patterns and a kind of filling materials. The first group is background model(model I ) which is filled with waste only and opened to air. The second one is four layer group which is subdivided into two models, opened and closed systems, and the third mix group which is subdivided into three models based on mixing ratio of filling materials and system environment like a layered group. The forth is composed of two layer model, lower one composed of waste and upper one limestone chips. Solution drained from Model Ishows a high contents of heavy metals on the all terms of experiments. Among the models, however, the closed mix model V and Ⅶ show the most effective removal of heavy metals liberated from wastes. Models having different mixing ratios of filling materials on closed systems does not affect in heavy metal removal effect. But, the distribution patterns of filling materials affect very much on removal effect of heavy metals. The closed models with same constitution ratios and distribution patterns of filling materials show more and less effective removal to the open models.

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Application Evaluation of Physical and Strength Properties of Paperboard by Kraft Pulp Mixing Made from Agricultural Byproducts (농업부산물 크라프트펄프의 혼합에 따른 판지의 물성변화)

  • Lee, Ji-Young;Lim, Gi-Baek;Kim, Sun-Young;Park, Jong-Hye;Kim, Eun-Hea;Sung, Yong Joo;Heo, Young-Jun;Kim, Young-Hun;Kim, Youn-Ho;Lee, Se-Ran
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.43-50
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    • 2014
  • The cultivation of agricultural crops results in the generation of agricultural byproducts. Researchers have reported that these materials can be useful in a variety of applications. However, over 50% of them are currently discarded because of the lack of specific technologies in industrial applications. Therefore, effective and specific applications must be developed in order to manufacture high-quality materials using discarded lignocellulosic resources. In this study, we determined the possibility of using kraft pulp from major agricultural byproducts as a raw material for the manufacture of paperboard. Rice husks, peanut husks, and garlic stems were obtained and used to prepare many kinds of kraft pulps by controlling the active alkali, sulfidity, reaction time, and liquor ratio. After the production of these kraft pulps, handsheets were manufactured by mixing them with KOCC. After preconditioning, the physical properties and strengths of the handsheets were measured according to the TAPPI test methods. The shapes, lengths, and widths of the pulp fibers varied according to the type of agricultural byproduct and the kraft pulping conditions. Rice husk and garlic stem pulps manufactured under mild pulping conditions resulted in handsheets of higher bulk than other pulps. Garlic stem pulps manufactured under mild pulping conditions were stronger than rice husk pulps and peanut husk pulps.