• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
• /
• pp.111-117
• /
• 1995

The alkali-aggregate reaction is a reaction between the alkali metals in the pore water of a concrete and an unstable mineral of the aggregate. There are three types of alkali-aggregate reation which causes deterioration of concrete, such as alkali-silicate reation, alkali-carbonate reaction and alkali-silica reation. Deterioration due to alkali-silica reation is more comon than that due to either the alkali-silicate or alkali-carbonate reaction. The alkali-silica reation is a reaction between the hydroxyl ions in the pore water of a concrete and silica which exists in signigicant quantities in the aggregate. In this PAPER, Alkali-aggregate reactions of mortar made with various abroad aggregate were investigated using XRD, microscope, chemical and physical tests. In additions, the effects of the texture of aggregate, Na, K, CI ion concentrations added to the mortar, on these reactions were studied.

• 한국작물학회지
• /
• 제24권3호
• /
• pp.1-6
• /
• 1979

미립의 Amylose 함량과 Alkali 붕괴성을 달리하는 품종 및 계통을 홍시하여 개화 10 일후부터 5일 간격으로 미립내 Amylose함량 및 Alkali 붕괴성을 검정하여 미립등숙과정에 따른 변이를 검토하였다. 1. 등숙 진전에 따른 미립내 Amylose함량과 Alkali 붕괴성은 최초에는 다소 낮았고 20일 후부터 거의 일정하게 나타났다. 2. 등숙기간중 어느 시기에서도 Amylose함량과 Alkali 붕괴성의 계통간 차이는 분명하였다. 3. 등열기간중의 기온와 Amylose함량 및 Alkali 붕괴성과에는 전반적으로 부의 상관경향을 보였으며 Amylose함량과 최고기온과는 해에 따라서는 유의한 상관을 나타내었다. 4. Amylose함량은 Alkali에 비하여 발육시기별 및 온도에 따른 변이의 건이 넓었다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 1993년도 가을 학술발표회 논문집
• /
• pp.108-112
• /
• 1993

The term Alkali-Silica Reaction (ASR) is used to describe a reaction between certain siliceous aggregates and hydroxyl ions present in the pore fluid of a concrete. The ASR is affected by the content of alkali, the particle size and the content of reactive aggregate, water-cement ratio, humidity, temperature and so on. In this paper, the fluence of alkali content and kind of added alkali to the ASR was studied. As a result, the more the content of alkali was increased, the more the mortar-bar was expand and the expansion of mortar-bar was showed differently with the added alkali kinds, The reaction products by ASR were observed by SEM(Scanning Electron Microscope) and analyzed by EDXA(Energy Dispersive X-ray Analysis) also and showed a gel composed of alkali(Na+, K+), silica and calcium.

• 한국세라믹학회지
• /
• 제13권4호
• /
• pp.15-19
• /
• 1976

Mutual interferences of alkali and alkali-earth metals in atomic absorption were examined. For determination of Na or K interfering elements increase the absorbancy, and for Ca or Mg decrease. Since influences of coexisting elements become nearly constant by addition of large amount of same coexisting element, could be use mixed standard solution for alkali or alkali-earth metal determination in the presence of other alkali and alkali-earth metals. The metals can be readily incorporated into scheme of rapid silicate analysis. Precision and accuracy are good.

• 한국세라믹학회지
• /
• 제22권2호
• /
• pp.25-32
• /
• 1985

Effect of alkali $SO_3$ and $C_2S$ content and cooling condition of clinker on the formation of unstable alkali and cooling condition of clinker on the formation of unstable alkali was investigated. As a result alkali and $SO_3$ content of clinker were the main factors of unstable alkali formation and equation (7) in which the two factors were the variables showed a good agreement with the observed results. Water soluble alkali content of sulphate was decreased with increase of $C_2S$ content of clinker resulted by the increase of solid solution rate of alkali to clinker minerals. But change of unsatble alkali content accordint to the increase of $C_2S$ content was slight. A increasing tendency of ignition loss of clinker with increase of unstable alkali content was found.

• 한국인쇄학회지
• /
• 제2권1호
• /
• pp.23-33
• /
• 1984

천연색 사진에서 전사과정중 발색화합물을 Polaroid 사 제품과 Kodak사 제품을 선정하여 고찰하였다. 이들 화합물은 초기에 Alkali 가동이거나 불가동이었다. Alkali 가동 화합물은 분해에 의하여 상적으로는 불가동화가 요구되며 Alkali0불가동 화합물은 상적으로 가동화가 요구된다. 고찰겨과 Polaroid사 제품은 Alkali 가동을 나타내며 Kodak제품은 Alkali불가동을 나타냇다.

• 임산에너지
• /
• 제18권2호
• /
• pp.70-77
• /
• 1999

간벌 소경재의 새로운 용도개발을 위한 기초연구로서 국내산 주요 침·활엽수 4수종의 알칼리팽윤 특성을 조사하였다. 그 결과, 4수종 모두 알칼리 처리후 밀도가 증가하였으며 그 정도는 활엽수재가 더 크게 나타났다. 알칼리처리에 의해 접선방향의 팽윤이 현저한 반면 방사방향의 팽윤은 작았고, 섬유방향은 오히려 감소하는 경향이 있었다. 알칼리 팽윤후 수축율은 활엽수재가 더 컸으며, 특히 기건상태까지의 수축율은 방사방향과 접선방향간에 수축육의 차이가 거의 없이 등방적으로 수축하는 특징을 보여주었다.

• 한국도로학회논문집
• /
• 제14권6호
• /
• pp.37-43
• /
• 2012

PURPOSES : This study is to evaluate the feasibility of setting the standard of cement alkali content by using ASTM C 1260(accelerated mortar bar test) METHODS : This study analyzes the ASR(alkali silica reaction) expansion of cement mortar bar based on the changes in the aggregate type(fine, coarse), cement type(ordinary, low alkali), and replacement contents of fly ash. ASR tests were conducted according to ASTM C 1260. RESULTS : In this test results, There is no big difference in the ASR expansion between ordinary cement and low alkali cement. From this test results, it was found that the variation of cement alkali content did not have a effect on ASR expansion because mortar bar was placed in a container with sufficient alkali aqueous solution at high temperature during the test process of ASTM C 1260. CONCLUSIONS : It is evidently clear that the alkali content of cement have a effect on ASR. But ASTM C 1260 is difficult to assess this effect.

• 한국세라믹학회지
• /
• 제22권3호
• /
• pp.60-66
• /
• 1985

The formation mechanism of unstable alkali and its existing states in the clinker were studied. The relation of unstable alkali content vs. other water-soluble components porosity and the distributionof potassium were investigated. The results are as follows :1) Two states of unstable alkali seem to exist in clinker ie compounds of $K_2O-Al_2O_3$ system and free $K_2O$ 2) The content of water-soluble $Al_2O_3$ tends to increase with increase of unstable alkali content, 3) Most of alkalies in clinker are concentrated in liquid phase at high temperature. Therefore it is possible to make various $K_2O-Al_2O_3$ system compounds according to the content of $K_2O$ in the liquid phase of clinker. In this experiment we found out a $K_2O-Al_2O_3$ compound of high $Al_2O_3$ content (34%) and high $K_2O$ content (33%) in clinker with 1.09% unstable alkali. 4) The porosity of clinker tends to increase with increase of unstable alkali content. 5) The amount of trapped alkali vapor may increase in closed pore in the clinker with high alkali and low $SO_3$ condecent. Therefore free $K_2O$ is the condensed alkali on the wall of closed pore in the clinker.

• 한국의류산업학회지
• /
• 제13권6호
• /
• pp.972-982
• /
• 2011

The purpose of this study is to improve the method of color developing with alkali solution as a promotor of color developing for feasible use. Cotton fabric was dyed with persimmon extract ranged with 0~3% alkali component with 5 types of strong to mild alkali solution. Heat treatment for color developing was applied to fabric dyed with persimmon extract and alkali mixing solution. Tests were carried out to analyze the change of surface color, ${\Delta},Ea^*b^*$, and water repellent of the dyed cotton fabric. The alkali mixing sample showed higher ${\Delta},Ea^*b^*$ value than control one without alkali mixing on the base of dyed fabric due to high color developing by alkali in the initial step of dyeing process. As alkali concentration increased, deeper dark color appeared on the fabric. The fabric color was changed to more dark in the application of sodium hydroxide, sodium carbonate, potassium carbonate in the initial step of dyeing process but color was not changed by increased heating time. However, the fabric showed a slight dark color with sodium acetate and more color change than that of the fabric dyed with persimmon extract without alkali. Therefore, sodium acetate seemed to a suitable promotor for color developing in persimmon extract dyeing. Property of water repellent was showed after color developing by heating with low concentration of alkali treatment.