• Title/Summary/Keyword: Al203

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Effect of In Situ YAG on Microstructure and Properties of the Pressureless-Sintered $SiC-ZrB_2$ Electroconductive Ceramic Composites (상압소결(常壓燒結)한 $SiC-ZrB_2$ 전도성(電導性) 복합체(複合體)의 미세구조(微細構造)와 특성(特性)에 미치는 In Situ YAG의 영향(影響))

  • Shin, Yong-Deok;Ju, Jin-Young
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.11
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    • pp.505-513
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    • 2006
  • The present study investigated the influence of the content of $Al_2O_3+Y_2O_3$ sintering additives on the microstructure, mechanical and electrical properties of the pressureless-sintered $SiC-ZrB_2$ electroconductive ceramic composites. Phase analysis of composites by XRD revealed mostly of ${\alpha}-SiC(4H),\;ZrB_2,\;{\beta}-SiC(15R)$ and In Situ $YAG(Al_5Y_3O_{12})$. The relative density and the flexural strength showed the highest value of 86.8[%] and 203[Mpa] for $SiC-ZrB_2$ composite with an addition of 8[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid at room temperature respectively. Owing to crack deflection and crack bridging of fracture toughness mechanism, the fracture toughness showed 3.7 and $3.6[MPa{\cdot}m^{1/2}]\;for\;SiC-ZrB_2$ composites with an addition of 8 and 12[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid at room temperature respectively. Abnormal grain growth takes place during phase transformation from ${\beta}-SiC\;into\;{\alpha}-SiC$ was correlated with In Situ YAG phase by reaction between $Al_2O_3\;and\;Y_2O_3$ additives during sintering. The electrical resistivity showed the lowest value of $6.5{\times}10^{-3}[({\Omega}{\cdot}cm]$ for the $SiC-ZrB_2$ composite with an addition of 8[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid at room temperature. The electrical resistivity of the $SiC-ZrB_2$ composites was all positive temperature coefficient(PTCR) in the temperature ranges from $25[^{\circ}C]\;to\;700[^{\circ}C]$. The resistance temperature coefficient showed the highest value of $3.53{\times}10^{-3}/[^{\circ}C]\;for\;SiC-ZrB_2$ composite with an addition of 8[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid in the temperature ranges from $25[^{\circ}C]\;to\;700[^{\circ}C]$. In this paper, it is convinced that ${\beta}-SiC$ based electroconductive ceramic composites for heaters or ignitors can be manufactured by pressureless sintering.

Effect of Si Particle Size on the Thermal Properties of Hyper-eutectic Al-Si Alloys (과공정 Al-Si 합금의 열팽창 특성에 미치는 Si 입자 크기의 영향)

  • Kim, Chul-Hyun;Joo, Dae-Heon;Kim, Myung-Ho;Yoon, Eui- Pak;Yoon, Woo-Young;Kim, Kwon-Hee
    • Journal of Korea Foundry Society
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    • v.23 no.4
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    • pp.195-203
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    • 2003
  • Hyper-eutectic Al-Si alloy is used much to automatic parts and material for the electronic parts because of the low coefficient of thermal expansion, superior thermal stability and superior wear resistance. In this work, A390 alloy specimens were fabricated for control of the Si particle size by various processes, such as spray-casting, permanent mold-casting and squeeze-casting. To minimize the effect of microporosity of the specimens, hot extrusion was carried out under equal condition. Each specimens were evaluated tensile properties at room temperature and thermal expansion properties in the range from room temperature to 400$^{\circ}C$. Ultimate tensile strength and elongation of the spray-cast and extruded specimens which have fine and well distributed Si particles were improved greatly compare to the permanent mold-cast and extruded ones. Specimens which have finer Si particles showed higher ultimate tensile strength and elongation than those having large Si particle size, and coefficient of thermal expansion of the specimens increased linearly with Si particle size. In case of the repeated high temperature exposures, thermal expansion properties of the spray-cast and extruded specimens were found to be more stable than those of the others due to the effect of fine and well distributed Si particles.

Effect of Alkali and Heat Treatments of Ti-6Al-4V Alloy on the Precipitation of Calcium Phosphate (Ti-6Al-4V 합금의 알칼리 및 열처리가 인산칼슘 침착에 미치는 영향)

  • Park, Jae-Han;Lim, Ki-Jung;Kim, Sang-Mok;Kim, Byung-Ock;Han, Kyung-Yoon
    • Journal of Periodontal and Implant Science
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    • v.30 no.1
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    • pp.187-203
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    • 2000
  • The precipitation of calcium phosphate on implant surface has been known to accelerate osseointegration and to enhance osseous adaptation. The present study was performed to examine whether the precipitation of calcium phosphate on Ti-6Al-4V alloy could be affected by the immersion in NaOH solution and heat treatment. Ti-6Al-4V alloy plates of $15{\times}3.5{\times}1mm$ in dimension were polished sequentially from #240 to #2,000 emery paper and one surface of each specimen was additionally polished with $0.1{\mu}m$ alumina paste. Polished specimens were soaked in various concentrations of NaOH solution(0.1, 1.0, 3.0, 5.0, 7.0, 10.0 M) at $60^{\circ}C$ for 24 hours for alkali treatment, and 5.0 M NaOH treated specimens were heated for 1 hour at each temperature of 400, 500, 600, 700, $800^{\circ}C$. After the alkali and heat treatments, specimens were soaked in the Hank's solution with pH 7.4 at $36.5^{\circ}C$ for 30days.The surface ingredient change of Ti-6Al-4V alloy was evaluated by thin-film X-ray diffractometer(TF-XRD) and the surface microstructure was observed by scanning electron microscope(SEM), and the elements of surface were analyzed by X-ray photoelectron spectroscopy(XPS). The results were obtained as follows ; 1. The precipitation of calcium phosphate on Ti-6Al-4V alloy was accelerated by the immersion in NaOH solution and heat treatment. 2. In Alkali treatment for the precipitation of calcium phosphate on Ti-6Al-4V alloy, the optimal concentration of NaOH solution was 5.0 M. 3. In heat treatment after alkali treatment in 5.0 M NaOH solution, the crystal formation on alloy surface was enhanced by increasing temperature. In heat treated alloys at $600^{\circ}C$, latticed structure and prominences of calcium phosphate layer were most dense. On heat treated alloy surface at the higher temperature(${\geq}700^{\circ}C$), main crystal form was titanium oxide rather than apatite. The above results suggested that the precipitation of calcium phosphate on the surface of Ti-6Al-4V alloy could be induced by alkali treatment in 5.0 M-NaOH solution and by heat treatment at $600^{\circ}C$.

Preparation of Polymer Light Emitting Diodes with PVK:Ir(ppy)$_3$ Emission Layer (PVK:Ir(ppy)$_3$ 발광층을 가지는 고분자 발광다이오드의 제작)

  • Lee, Hak-Min;Gong, Su-Cheol;Choi, Jin-Eun;Chang, Ho-Jung
    • Proceedings of the KAIS Fall Conference
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    • 2008.11a
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    • pp.201-203
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    • 2008
  • ITO 투명전극을 양극으로 사용하고 PEDOT:PSS 고분자 물질위에 PVK와 Ir(ppy)3를 각각 host와 dopant로 사용하여 고분자 발광다이오드를 제작하였다. 전자 수송층의 역할로 TPBI, 음극으로 Al을 증착하여 최종적으로 ITO/PEDOT:PSS/PVK:Ir(ppy)3/TPBI/LiF/Al 구조를 갖는 녹색 인광 고분자 유기발광소자(PhPLED)를 제작하였다. 제작 된 소자의 발광부 dopant인 Ir(ppy)3도핑 농도에 따른 전기적 광학적 특성을 평가하였다. PVK:Ir(ppy)3를 host와 dopant system으로 dopant Ir(ppy)3의 도핑 양을 0.5 wt%에서2.5 wt%까지 씩 변화시키면서 최적의 농도를 찾고자 하였다. TPBI를 전자 수송층으로 사용 하였을 경우 최대 휘도는 약 8600 cd/$m^2$ (at 8V)이고, 전류밀도는 337mA/$cm^2$ 를 나타내었다.

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A Finite Element Model of Melt Pool for the Evaluation of Selective Laser Melting Process Parameters (선택적 레이저 용융 공정의 공정변수 평가를 위한 용융풀 유한요소 모델)

  • Lee, Kanghyun;Yun, Gun Jin
    • Journal of the Korea Institute of Military Science and Technology
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    • v.23 no.3
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    • pp.195-203
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    • 2020
  • Selective laser melting(SLM) is one of the powder bed fusion(PBF) processes, which enables quicker production of nearly fully dense metal parts with a complex geometry at a moderate cost. However, the process still lacks knowledge and the experimental evaluation of possible process parameter sets is costly. Thus, this study presents a finite element analysis model of the SLM process to predict the melt pool characteristics. The physical phenomena including the phase transformation and the degree of consolidation are considered in the model with the effective method to model the volume shrinkage and the evaporated material removal. The proposed model is used to predict the melt pool dimensions and validated with the experimental results from single track scanning process of Ti-6Al-4V. The analysis result agrees with the measured data with a reasonable accuracy and the result is then used to evaluated each of the process parameter set.

Comparison of Adsorption Properties of Adsorbates on Pt(111) and Pt(111)/$\gamma-Al_2O_3$ Surface in the Ethylene Hydrogenation Reaction : MO-Theory

  • 조상준;박상문;박동호;허도성
    • Bulletin of the Korean Chemical Society
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    • v.19 no.7
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    • pp.733-737
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    • 1998
  • Using an atom superposition and electron delocalization molecular orbital (ASED-MO) method, we have compared adsorption properties of adsorbates on the Pt(Ill) surface with the Pt(lll)/γ-Al203 surface in the ethylene hydrogenation reaction. In two-layer thick model systems, the calculated activation energy of the hydrogenation by the surface platinum hydride is equal to the energy by the hydride over supported platinum/γ-alumina. The transition structure on platinum is very close to the structure on the supported platinum/γ-alumina surface. Hydrogenation by the surface hydride on platinum can take place easily because the activation energy is about 0.5 eV less than hydrogenation by ethylidene. On supported platinum/,y-alumina the activation energy of the hydride mechanism is about 0.61 eV less than that of ethylidene mechanism. In one-layer thick model systems, the activation energy of hydrogenation by ethylidene is about 0.13 eV less than the activation energy of hydride reaction. The calculated activation energy by the hydride over the supported platinum y-alumina is 0. 24 eV higher than the platinum surface. We have found from this result that the catalytic properties of one-layer thick model systems have been influenced by the support but the two-layer thick model systems have not been influenced by the support.

Exploring Ways to Improve the Predictability of Flowering Time and Potential Yield of Soybean in the Crop Model Simulation (작물모형의 생물계절 및 잠재수량 예측력 개선 방법 탐색: I. 유전 모수 정보 향상으로 콩의 개화시기 및 잠재수량 예측력 향상이 가능한가?)

  • Chung, Uran;Shin, Pyeong;Seo, Myung-Chul
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.19 no.4
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    • pp.203-214
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    • 2017
  • There are two references of genetic information in Korean soybean cultivar. This study suggested that the new seven genetic information to supplement the uncertainty on prediction of potential yield of two references in soybean, and assessed the availability of two references and seven genetic information for future research. We carried out evaluate the prediction on flowering time and potential yield of the two references of genetic parameters and the new seven genetic parameters (New1~New7); the new seven genetic parameters were calibrated in Jinju, Suwon, Chuncheon during 2003-2006. As a result, in the individual and regional combination genetic parameters, the statistical indicators of the genetic parameters of the each site or the genetic parameters of the participating stations showed improved results, but did not significant. In Daegu, Miryang, and Jeonju, the predictability on flowering time of genetic parameters of New7 was not improved than that of two references. However, the genetic parameters of New7 showed improvement of predictability on potential yield. No predictability on flowering time of genetic parameters of two references as having the coefficient of determination ($R^2$) on flowering time respectively, at 0.00 and 0.01, but the predictability of genetic parameter of New7 was improved as $R^2$ on flowering time of New7 was 0.31 in Miryang. On the other hand, $R^2$ on potential yield of genetic parameters of two references were respectively 0.66 and 0.41, but no predictability on potential yield of genetic parameter of New7 as $R^2$ of New7 showed 0.00 in Jeonju. However, it is expected that the regional combination genetic parameters with the good evaluation can be utilized to predict the flowering timing and potential yields of other regions. Although it is necessary to analyze further whether or not the input data is uncertain.

Efficient Serial Gaussian Normal Basis Multipliers over Binary Extension Fields

  • Kim, Yong-Tae
    • The Journal of the Korea institute of electronic communication sciences
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    • v.4 no.3
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    • pp.197-203
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    • 2009
  • Finite field arithmetic is very important in the area of cryptographic applications and coding theory, and it is efficient to use normal bases in hardware implementation. Using the fact that $GF(2^{mk})$ having a type-I optimal normal basis becomes the extension field of $GF(2^m)$, we, in this paper, propose a new serial multiplier which reduce the critical XOR path delay of the best known Reyhani-Masoleh and Hasan's serial multiplier by 25% and the number of XOR gates of Kwon et al.'s multiplier by 2 based on the Reyhani-Masoleh and Hasan's serial multiplier for type-I optimal normal basis.

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Effect of Mechanical Grinding on the superconducting Characteristics in the Bi(Pb)SrCaCuO System (Grinding 조건이 Bi(Pb)SrCaCuO 계(系) 초전도체의 상변이에 미치는 영향)

  • Cho, H.D.;Jang, K.W.;Park, Y.P.;Lee, J.U.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.201-203
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    • 1991
  • T. Kanal et al, were studied the superconducting properties in Bi system by mechanical grinding, in which the authors found that the samples ground degraded from the superconducting phases to nonsuperconducting phases. To obtain more information of the practical application in Bi system with high-Tc phase in this paper, these samples mechanically ground and the high-Tc phase properties of grinding powder samples were investigated.

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A Preliminary Study on a Method for the Morphological and Quantitative Analyses of Individual Snow Crystals and Its Application for Field Measurement

  • Ma, Chang-Jin
    • Asian Journal of Atmospheric Environment
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    • v.5 no.3
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    • pp.196-203
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    • 2011
  • The main aim of this study is to establish methods of morphological preservation and elemental quantification for individual snow crystals. Individual snow crystals were collected at a height of 20 m above ground level. To stabilize and preserve the original morphologies of the snow crystals, cyanoacrylate, which has been used to fix liquid droplets, was applied (Kasahara et al., 2000). Several different kinds of snow crystals (dendrite, sectored plate, quasi-sectored plate, and hexagonal plate) were successively stabilized using this method. The stabilized snow crystals were pretreated with acetone, and then the elemental components contained in a whole snow crystal were quantified with the Particle Induced X-ray Emission (PIXE) analytical technique. The snow crystal residual composition determined in the present study was dominated by sulfur and mineral components, and the elemental mass showed an apparent crystal size dependence, where the elemental mass gradually decreased as the crystal size increased.