• Title/Summary/Keyword: Al surface

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Study on the Oxidation Process of Potential Acid Sulfate Soil (잠재 산성황산염토양의 산화과정에 대한 연구)

  • Han, Kang-Wan;Chun, Jae-Chul;Cho, Jae-Young;Kim, Geum-Hee;Ann, Yeoul
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.3
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    • pp.243-248
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    • 1996
  • To find out the oxidation process of potential acid sulfate soil(PASS) along with time. the PASS were treated with lime and ammonia water to adjust soil pH in laboratory column condition. pH range of PASS showed 6.5 to 7.5. however, complete oxidized PASS by $H_2O_2$ showed 2.1 to 2.5. After pilling the PASS under the natural condition. oxidation occured slowly from surface of the pilled soil. The oxidation of PASS proceeded slowly when the soil was in submerged condition. but quickly in dried condition. The content of sulfide-sulfur in PASS sharply decreased after exposing to the air and the decreasing rate was greater in dried than in submerged condition. The content of sulfate-sulfur continuously decreased in submerged condition. but increased in dried condition. Contents of $Fe^{+{+}}$ and $Al^{+{+}}$ in PASS were generally increased with time and the increasing rate was greater in submerged than in dried condition. Liming to PASS was slowly acting to pH change and ammonia water caused fast pH change within a short period of time. The contents of sulfate-sulfur and exchangeable aluminum in drainage water decreased with time and the contents of sulfide-sulfur and ferrous iron were increased.

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Growth characteristics of titanium boride($\textrn{TiB}_{x}$) thin films deposited by dual-electron-beam evaporation (2원전자빔 증착법에 의한 티타늄붕화물($\textrn{TiB}_{x}$) 박막의 성장특성)

  • 이영기;이민상;임철민;김동건;진영철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.1
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    • pp.20-26
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    • 2001
  • Titanium boride ($\textrn{TiB}_{x}$) films were deposited on (100) silicon substrates at the substrate temperature of $500^{\circ}C$ by means of the co-evaporation of titanium and boron evaporants during deposition. The co-evaporation method makes it possible to deposit the non-stoichiometric films with different boron-to-titanium ratio($0{\le}B/Ti \le 2.5$). The resistivity increases linearly as the boron-to-titanium ratio in the as-deposited films is increased. The surface roughness of $\textrn{TiB}_{x}$ films is changed as a function of the boron-to-titanium ratio. The XRD spectrum for pure titanium film shows a highly (002) preferred orientation. For B/Ti=0.59 ratio only a single TiB phase that shows a (111) preferred orientation is observed. However, the $\textrn{TiB}_{x}$ phase with the hexagonal structure of the $AlB_2$(C32) type appears as the boron concentration increase, and only a single $\textrn{TiB}_{x}$ phase is observed for $B/Ti \ge 2.0$ ratio. The $\textrn{TiB}_{x}$/Si samples reveal a tensile stress (3~$20{\times}^9$dyn/$\textrm{cm}^2$) in the overall composition of the films, although the magnitude of the residual stresses is depended on the nominal B/Ti ratio.

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Development of the Algorithm for On-line Dosimetry System for High Energy Radiation Treatment (고에너지 방사선치료용 on-line 선량측정시스템을 위한 알고리즘의 개발)

  • Wu, Hong-Hyun;Ha, Sung-Whan
    • Journal of Radiation Protection and Research
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    • v.22 no.3
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    • pp.207-218
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    • 1997
  • Purpose: The objective of this study is to develop an algorithm for estimation of tumor dose using measured transmission dose as a part of the development of on-line dosimetry system. Materials and Methods: Data of transmission dose were measured under various FS, Tp and PCD with a special water phantom for 6 MV and 10 MV X-ray. SCD (source-chamber distance) was set to 150 cm. Measurements were conducted with a 0.125 cc ion chamber. Results: Using measured data and regression analysis, two algorithms were developed for estimation of expected reading for measured data. Algorithm 1 consisted of the quadratic function of PCD and the tertiary function of AlP (area-perimeter ratio). Algorithm 2 consisted of the tertiary function of log(A/P)and the tertiary function of PCD. Algorithm 2 required less data set and was more accurate in comparing expected and observed dose. Conclusion: Using the algorithm developed, transmission dose can be estimated for any exposure condition, i.e. any given Tp, PCD and FS with high accuracy. To complete this algorithm, further developments are needed regarding the beam modifying device, the tissue inhomogeneity and the irregular body surface.

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Experimental Evaluation on Bond Strengths of Reinforcing Bar in Coils with Improved Machinability during Straightening Process (직선화 가공성을 고려한 코일철근의 실험적 부착강도 평가)

  • Chun, Sung-Chul;Choi, Oan-Chul;Jin, Jong-Min
    • Journal of the Korea Concrete Institute
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    • v.25 no.1
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    • pp.53-61
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    • 2013
  • A new deformation of reinforcing bar in coils was proposed to improve a machinability of straightening process, which has crescent-shaped transverse ribs with an inclination angle of 50 degrees, a crest width of $0.15d_b$, and a flank inclination of 55 degrees. The proposed deformation can increase contact area between a surface of re-bar and a groove of a roller during a straightening process and, therefore, it might reduce a damage of ribs, improve a final straightness, and enhance an efficiency of the straightening process. Splice tests were conducted to evaluate bond strengths of three types of re-bar in coils including the proposed re-bar, of which the inclination angles of transverse ribs were 50, 60, and 90 degrees, respectively. Test results show that the re-bars in coils have higher bond strengths than predicted strengths by equations of Orangun et al., ACI 408, and KCI by at least 10%. Correlation coefficients of bond strengths between a straight bar and re-bars in coils are 0.94 and more. Consequently, equations of the KCI code for determining development and splice lengths can be applied to the tested re-bars in coils.

Influence of nano-structured alumina coating treatment on shear bond strength between zirconia ceramic and resin cement (나노구조 알루미나 코팅 처리가 지르코니아 도재와 레진 시멘트 사이 전단 결합강도에 미치는 영향)

  • Kim, Dong-Woon;Lee, Jung-Jin;Kim, Kyoung-A;Seo, Jae-Min
    • The Journal of Korean Academy of Prosthodontics
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    • v.54 no.4
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    • pp.354-363
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    • 2016
  • Purpose: The aim of this study was to investigate whether the application of nano-structured alumina coating to the surface of Y-TZP could enhance the bond strength with resin cement. Materials and methods: A total of 80 zirconia plates were prepared and divided into four groups. : 1) airborne particle abrasion treatment (A) : 2) Rocatec treatment after airborne particle abrasion (R) : 3) nano-structured alumina coating treatment after polishing (PC) and 4) nano-structured alumina coating after airborne particle abrasion (AC). Alumina coating was formed by the hydrolysis of aluminium nitride (AlN) powder and heat treatment at $900^{\circ}C$. Coating patterns were observed with FE-SEM. Resin block was bonded to treated zirconia ceramics using resin cement. The shear bond strengths were measured before and after thermocycling. Results: The FE-SEM images show a dense and uniform nano-structured alumina coating structure, which enhances shear bond strength by increasing micro mechanical interlocking to resin cement. PC and AC groups showed higher shear bond strengths than A and R groups before and after thermocycling. A and R groups displayed significant drops in shear bond strength after thermocycling. However, PC and AC groups did not show any meaningful decreases in shear bond strength after thermocycling. Conclusion: Treatment of Y-TZP ceramics with nano-structured alumina coating could significantly increase their shear bond strength.

Salt tolerant rice cv Nona Bokra chromosome segments introgressed into cv Koshihikari improved its yield under salinity through retained grain filling

  • Mitsuya, Shiro;Murakami, Norifumi;Sato, Tadashi;Kano-Nakata, Mana;Yamauchi, Akira
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.238-238
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    • 2017
  • Salt stress is one of the deteriorating abiotic stresses due to the climate change, which causes over-accumulation of $Na^+$ and $Cl^-$ ions in plants and inhibits the growth and yield of rice especially in coastal Southeastern Asia. The yield components of rice plant (panicle number, spikelet number per panicle, 1000-grain weight, % of ripened grains) that are majorly affected by salt stress vary with growth stages at which the plant is subjected to the stress. In addition, the salt sensitivity of each yield component differs among rice varieties even when the salt-affected growth stage was same, which indicates that the physiological mechanism to maintain each yield component is different from each other. Therefore, we hypothesized that rice plant has different genes/QTLs that contribute to the maintenance of each yield component. Using a Japanese leading rice cultivar, Koshihikari, and salt-tolerant Nona bokra's chromosome segment substitution lines (CSSLs) with the genetic background of Koshihikari (44 lines in total) (Takai et al. 2007), we screened higher yielding CSSLs under salinity in comparison to Koshihikari and identified the yield components that were improved by the introgression of chromosome segment(s) of Nona bokra. The experiment was conducted in a salinized paddy field. One-month-old seedlings were transplanted into a paddy field without salinity. These were allowed to establish for one month, and then the field was salinized by introducing saline water to maintain the surface water at 0.4% salinity until harvest. The experiments were done twice in 2015 and 2016. Although all the CSSLs and Koshihikari decreased their yield under salinity, some CSSLs showed relatively higher yield compared with Koshihikari. In Koshihikari, all the yield components except panicle number were decreased by salinity and % of ripened grains was mostly reduced, followed by spikelet number per panicle and 1000-grain weight. When compared with Koshihikari, keeping a higher % of ripened grains under salinity attributed to the significantly greater yield in one CSSL. This indicated that the % of ripened grains is the most sensitive to salt stress among the yield components of Koshihikari and that the Nona bokra chromosome segments that maintained it contributed to increased yield under salt stress. In addition, growth analyses showed that maintaining relative growth rate in the late grain filling stage led to the increased yield under salt stress but not in earlier stages.

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Characterization of carbon microspheres grown by HVPE (HVPE 방법에 의해 성장된 탄소 마이크로구의 특성)

  • Lee, Chanmi;Jeon, Hunsoo;Park, Minah;Lee, Chanbin;Yang, Min;Yi, Sam Nyung;Ahn, Hyung Soo;Kim, Suck-Whan;Yu, Young Moon;Shin, Keesam;Bae, Jong Seong;Lee, Hyo Suk;Sawaki, Nobuhiko
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.2
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    • pp.62-67
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    • 2015
  • The carbon microspheres of a core-shell type were grown by the method of mixed-source hydride vapor phase epitaxy (HVPE). The surface and the cross section of the carbon microsphere grown by a new method were observed by scanning electron microscope (SEM). The characteristics of the carbon microsphere were investigated by X-ray photoelectron spectroscopy (XPS) and a high resolution-transmission electron microscope (HR-TEM). From these measurements, the diameters of carbon sphere were about few hundred micrometers. Furthermore, we show that the carbon microsphere of the core-shell type by mixed-source HVPE method can be grown successfully with the larger size than those of the existing one. This mixed-source HVPE method is proposed a new method for making of carbon microsphere.

Synthesis and luminescence characteristics of nano-sized YAG : Ce phosphors by homogeneous precipitation method (Homogeneous precipitation method를 통한 나노 YAG : Ce 형광체 합성과 광학 특성)

  • Lee, Chul Woo;Kwon, Seok Bin;Ji, Eun Kyung;Song, Young Hyun;Jeong, Byung Woo;Kim, Eun Young;Jung, Mong Kwon;Yoon, Dae-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.1
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    • pp.18-21
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    • 2017
  • In this study, spherical monodispersed cerium-doped yttrium aluminum garnet (YAG : $Ce^{3+}$) phosphor particles were synthesized via homogeneous precipitation method using the mixed solution of yttrium nitrate, cerium nitrate, aluminum nitrate, ammonium aluminum sulfate, and urea as a precipitant. During the process of precursors of monodispersed YAG : $Ce^{3+}$, aluminum ions which form spherical aluminum compounds precipitated first and yttrium compounds precipitated onto the surface of the existing spherical aluminum compounds. Drying process using lyophilization could obtain monodispered spherical YAG : $Ce^{3+}$ particles compare to using oven. The thermal calcination process of YAG : $Ce^{3+}$ precursors under the temperature of $1200^{\circ}C$ for 6 h was enough to obtain 400~500 nm sized YAG particles with pure YAG phase.

Extended Cartoon Rendering using 3D Texture (3차원 텍스처를 이용한 카툰 렌더링의 만화적 스타일 다양화)

  • Byun, Hae-Won;Jung, Hye-Moon
    • The Journal of the Korea Contents Association
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    • v.11 no.8
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    • pp.123-133
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    • 2011
  • In this paper, we propose a new method for toon shading using 3D texture which renders 3d objects in a cartoon style. The conventional toon shading using 1D texture displays shading tone by computing the relative position and orientation between a light vector and surface normal. The 1D texture alone has limits to express the various tone change according to any viewing condition. Therefore Barla et. al. replaces a 1D texture with a 2D texture whose the second dimension corresponds to the view-dependent effects such as level-of-abstraction, depthof-field. The proposed scheme extends 2D texture to 3D texture by adding one dimension with the geometric information of 3D objects such as curvature, saliency, and coordinates. This approach supports two kinds of extensions for cartoon style diversification. First, we support "shape exaggeration effect" to emphasize silhouette or highlight according to the geometric information of 3D objects. Second, we further incorporate "cartoon specific effect", which is examples of screen tone and out focusing frequently appeared in cartoons. We demonstrate the effectiveness of our approach through examples that include a number of 3d objects rendered in various cartoon style.

Seasonal Variations of Settling Particles and Metal Fluxes at a Nearshore Site of Marian Cove, King George Island, Antarctica (남극 킹조지섬 마리안소만에서 침강 입자와 금속 플럭스의 계절 변화)

  • Shim, Jeong-Hee;Kang, Young-Chul;Han, Myung-Woo;Kim, Dong-Seon;Chung, Ho-Sung;Lee, Sang-Hoon
    • Ocean and Polar Research
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    • v.24 no.2
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    • pp.123-134
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    • 2002
  • Seasonal variations of settling particles and metal fluxes were monitored at a nearshore site of Marian Cove, King Geroge Island, Antarctica from 28th February 1998 to 22nd January 2000. Near-bottom sediment traps were deployed at 30m water depth of the cove, and sampling bottles were recovered every month by SCUBA divers. Total particulate flux and metal concentrations were determined from the samples. Total particulate flux showed a distinct seasonality, high in austral summer and low in austral winter: the highest flux $(21.97g\;m^{-2}d^{-1})$ was found in February of 1999, and the lowest $(2.47g\;m^{-2}d^{-1})$ in September of 1998, when sea surface was frozen completely. Lithogenic particle flux accounted for 90% of the total flux, and showed a significantly negative correlation with the thickness of snow accumulation around the study site. It was suggested that the most of the lithogenic particles trapped in the bottles was transported by melt water stream from the surrounding land. Fluxes of Al, Fe, Ti, Mn, Zn, Cii, Co, Ni, Cr, Cd, and Pb showed similar seasonal variations with the total flux, and their averaged fluxes were 34000, 9000,960, 180, 13.8, 17.6, 3.0,2.1, 5.4, 0.02, and $1.5nmol\;m^{-2}d^{-1}$ respectively. Among the metals, Cu and Cd showed the most noticeable seasonal patterns. The Cd flux correlated positively with the fluxes of biogenic components while the Cu flux correlated with both the lithogenic and biogenic particle fluxes. The Cu flux peak in the late summer is likely related to a substantial amount of inflow of ice melt water laden with Cu-enriched lithogenic particles. On the other hands, the Cd flux peak in the early spring may be associated with the unusually early occurred phytoplankton bloom.