• Title/Summary/Keyword: Al/alumina

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A Study on the Chemical Properties and Strength Development of Regional Hwangto (지역별 황토의 화학적 특성 및 강도발현에 관한 연구)

  • Hwang, Hey-Zoo;Kim, Jeong-Gyu;Yang, Jun-Hyuk
    • KIEAE Journal
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    • v.6 no.2
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    • pp.11-18
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    • 2006
  • In this research, Conducting an engineering properties experiment, this study examined basic properties of regional Hwangto. The results of experiments are as followings. 1) This study confirmed that a result of examining lime order for Hwangto and comparison of stimulants, this study confirmed that 28 day's strength promotion is found in case of calcium hydroxide(Ca(OH)2) and calcium chloride(CaCl2) stimulant. Finally, it is known the fact that lime highly improves the weak strength of Hwangtoh. 2) As XRD analysis for proving the strength manifestation principle of Hwangto by regions, CSH figure and CASH figure appeared in each regional Hwangto in all the strength areas. This result could be appeared through hydraulicity from reaction of alkali stimulant and water, and pozzolan reaction(CSH figure) and $Str{\ddot{a}}tlingite$ reaction(CASH figure) by silica (SiO2) ingredient and calcium hydroxide (Ca(OH)2) among ingredients of clay, and alumina(Al2O3). 3) In result of strength analysis, It is knowned that the Gyeongsangdo Hwangto is stronger than the Jeollado Hwangto in reactivity.

The Study of Opto-electric Properties in EL Device with PMN Dielectric Layer (PMN 계 유전체 적용 EL 소자의 광전특성 연구)

  • Kum, Jeong-Hun;Han, Da-Sol;Ahn, Sung-Il;Lee, Seong-Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.9
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    • pp.776-780
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    • 2009
  • In this study, the opto-electric properties of EL devices with PMN dielectric layer with variation of firing tempereature were investigated. For the PMN dielectric layer process, the paste was prepared by optimization of quantitative mixing of PMN powder, $BaTiO_3$, Glass Frit, $\alpha$-Terpineol and ethyl cellulose. The EL device stack consists of Alumina substrate ($Al_2O_3$), metallic electrode (Au), insulating layer (manufactured PMN paste), phosphor layer (ELPP- 030, ELK) and transparent electrode (ITO), which is well structure as a thick film EL device. The phase transformation properties of PMN dielectric with various firing temperatures of $150^{\circ}C$ to $850^{\circ}C$ was characterized by XRD. Also the opto-electric properties of EL devices with different firing temperature were investigated by LCR meter and spectrometer. We found the best opto-electric property was obtained at the condition of $550^{\circ}C$ firing which is 3432.96 $cd/m^2$ at 1948.3 pF Capacitance, 40 kHz Frequency, 40% Duty, Vth+330 V voltage.

Material properties and machining performance of CNT and Graphene reinforced hybrid alumina composites for micro electrical discharge machining (탄소나노튜브와 그래핀 강화 하이브리드 알루미나 복합재료의 재료특성 및 마이크로방전가공 성능)

  • Sung, Jin-Woo;Kim, Nam-Kyung;Kang, Myung-Chang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.6
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    • pp.3-9
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    • 2013
  • Aluminum Oxide($Al_2O_3$) ceramics are excellent candidates for such applications due to their outstanding mechanical, thermal, and tribological properties. However, they are difficult to machine using conventional mechanical methods. Carbon fillers, such as carbon nanotubes(CNT) and graphene nanoplatelets(GNP)can be dispersed in a ceramic matrix to improve the mechanical and electrical properties. In this study, CNT and Graphene reinforced hybrid ceramic composites were fabricated using the spark plasma sintering method at a temperature of $1,500^{\circ}C$, pressure of 40 MPa, and soaking time of 10min. Besides this, the material properties such as microstructure, crystal structure, hardness, and electrical conductivity were analyzed using FE-SEM, XRD, Vickers, and the 4-point probe method. A micro machining test was carried out to compare the effects of the material properties and the machining performance for CNT and Graphene reinforced ceramic composites.

An Experimental Study on the Reduction of Nitric Oxides from the Diesel Engine Exhaust Gas with Metal Supported Oxides Catalysts (디젤엔진 배기가스중 질소산화물 저감을 위한 금속 산화물 촉매를 이용한 실험적 연구)

  • Chae, Jae-Ou;Hwang, Jae-Won;Jung, Jee-Yong;Han, Jung-Hee;Hwang, Hwa-Ja;Kim, Seok;Eduard, Mikholap
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.3
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    • pp.68-75
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    • 2001
  • In this paper, a number of supported metal oxides and perovskite type catalysts were investigated for the NOx reduction from the diesel engine exhaust gas. All catalysts were made into pellets type with diameter of 3-4 mm alumina(Al$_2$O$_3$) as a supporter. These samples were tested by real diesel exhaust gas which contains CO, hydrocarbons and soot in the temperature range of 150~55$0^{\circ}C$ with the $3300h^{-1}$ space velocity (SV). Among the results, several promising catalysts showed NOx conversion above 50% in the temperature range of 150-35$0^{\circ}C$. From these results supported metal oxides catalysts and perovskite type could be recommended for the practical application to the automobile exhaust treatments.

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Characterization the surface of $TiO_2$ N-type semiconductor using the nanoporous alumina template (나노기공 알루미나 주형을 이용한 $TiO_2$ N-type 반도체 계면에 관한 연구)

  • Her, Hyun-Jung;Kim, Jung-Min;Park, Sung-Hwak;Choi, Y.J.;Kim, Jae-Wan;Kang, C.J.;Kim, Han-Soo;Kim, Yong-Sang
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1364-1365
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    • 2006
  • 본 논문에서는 두께 0.25 mm의 알루미늄 포일 (foil)을 이용해 나노기공 알루미나 주형을 만들었다. 우선 알루미늄 포일 표면의 유기물을 제거한 후, 전해연마 방법을 이용하여 표면을 매끄럽게 하였다. 또, 양극산화를 통해 알루미늄 표면에 나노기공을 형성하였다. 나노기공 알루미나($Al_{2}O_{3}$) 주형 위에 Polymethyl methacrylate (PMMA)를 얇게 도포하여 나노기공 사이로 침투시킨 후 주형을 제거하여 나노기둥인 PMMA를 얻었다. 이것을 나노임프린트 리소그라피 기법을 이용하여 태양전지의 N-type 물질로 맏이 사용되는 티타니아 ($TiO_2$)의 면적을 넓게 할 수 있다.

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Improved hydrogen sensing characteristics of flat type catalytic combustible hydrogen gas sensor of micro-structure (평판형 접촉연소식 마이크로 수소센서의 감지특성 향상)

  • Kim, Chan-Woo;Gwak, Ji-Hye;Chun, Il-Su;Han, Sang-Do;Choi, Sie-Young
    • Journal of Sensor Science and Technology
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    • v.18 no.3
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    • pp.202-206
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    • 2009
  • Flat type catalytic combustible hydrogen sensors were fabricated using platinum micro-heaters and sensing material pastes. The platinum micro-heater was formed on an alumina substrate by sputtering method. The paste for the sensing materials was prepared using ${\gamma}-Al_2O_3$ 30 wt%, $SnO_2$ 35 wt%, and Pd/Pt 30 wt% and coated on the platinum micro-heater. The sensing performances were tested for the prepared sensors with different substrate sizes. The micro catalytic combustible hydrogen sensors showed quick response time, high reliability, and good selectivity against various gases(CO, $C_3H_8,\;CH_4$) at low operating temperature of $156^{\circ}\C$.

Effects of Oxygen Partial Pressure and Post-Annealing Temperature on Structure of ZnO Thin Film Prepared by Pulsed Laser Deposition (PLD를 이용한 ZnO 박막의 구조에 산소 분압 및 후열처리 온도가 미치는 영향)

  • Cho, Dae-Hyung;Kim, Ji-Hong;Koo, Sang-Mo;Moon, Byung-Moo
    • Proceedings of the KIEE Conference
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    • 2007.11a
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    • pp.88-89
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    • 2007
  • ZnO thin films were deposited on $Al_2O_3$ (alumina) substrates by pulsed laser deposition (PLD) using Nd:YAG laser with a wavelength of 355nm, at room temperature and oxygen partial pressure of 1, 10, 30, 50, 100, and 200m Torr. Furthermore, deposited ZnO thin films were post-annealed at 400, 550, $600^{\circ}C$. The effects of oxygen partial pressure and post-annealing temperature on structural properties of the deposited films have been investigated by means of X-ray diffraction (XRD), and atomic force microscope (AFM), respectively. It has been found that ZnO thin films exhibit c-axis orientation, exhibiting an increased foil width at half maximum (FWHM) value of (002) diffraction peak at 30m Torr oxygen partial pressure and higher post-annealing temperature ($700^{\circ}C$).

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The Change of the Cyclic Aging Characteristics under Salt-fog/Heating on Silicone Rubber by ATH Additions (ATH 첨가에 의한 실리콘 고무의 염무/열 반복열화 특성 변화)

  • Lee, Chung;Kim, Ki-Yup;Kim, Gyu-Baek;Ryu, Boo-Hyung
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.58-63
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    • 2005
  • In this research, silicone rubber with additions of inorganic filler, alumina trihydrate$(Al(OH)_3\;:\;ATH)$, was aged acceleratedly and cyclically by the salt-fog and heating. The optimum amount of ATH addition to silicone rubber have been investigated by measurements of leakage current in the change of electrical properties and tensile strength, %elongation in mechanical properties and FT-IR, TG, SEM in the change of the chemical properties. With regard to un-aged silicone rubber, as the ATH addition amount increases, conductive path formation time was shortened in the electrical properties and tensile strength was increased, %elongation was decreased. In case of identical ATH addition amount, as cyclic aging increases, surface resistivity, tensile strength and %elongation were decreased. Considering the cyclic aging, the most effective amount of ATH addition was about 90phr.

Flexible poly(vinyl alcohol)-ceramic composite separators for supercapacitor applications

  • Bon, Chris Yeajoon;Mohammed, Latifatu;Kim, Sangjun;Manasi, Mwemezi;Isheunesu, Phiri;Lee, Kwang Se;Ko, Jang Myoun
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.173-179
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    • 2018
  • Electrochemical characterization was conducted on poly(vinyl alcohol) (PVA)-ceramic composite (PVA-CC) separators for supercapacitor applications. The PVA-CC separators were fabricated by mixing various ceramic particles including aluminum oxide ($Al_2O_3$), silicon dioxide ($SiO_2$), and titanium dioxide ($TiO_2$) into a PVA aqueous solution. These ceramic particles help to create amorphous regions in the crystalline structure of the polymer matrix to increase the ionic conductivity of PVA. Supercapacitors were assembled using PVA-CC separators with symmetric activated carbon electrodes and electrochemical characterization showed enhanced specific capacitance, rate capability, cycle life, and ionic conductivity. Supercapacitors using the $PVA-TiO_2$ composite separator showed particularly good electrochemical performance with a 14.4% specific capacitance increase over supercapacitors using the bare PVA separator after 1000 cycles. With regards to safety, PVA becomes plasticized when immersed in 6 M KOH aqueous solution, thus there was no appreciable loss in tear resistance when the ceramic particles were added to PVA. Thus, the enhanced electrochemical properties can be attained without reduction in safety making the addition of ceramic nanoparticles to PVA separators a cost-effective strategy for increasing the ionic conductivity of separator materials for supercapacitor applications.

Development of a PLD heater for continuous deposition and growth of superconducting layer

  • Jeongtae Kim;Insung Park;Gwantae Kim;Taekyu Kim;Hongsoo Ha
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.2
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    • pp.14-18
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    • 2023
  • Superconducting layers deposited on the metal substrate using the pulsed laser deposition process (PLD) play a crucial role in exploring new applications of superconducting wires and enhancing the performance of superconducting devices. In order to improve the superconducting property and increase the throughput of superconducting wire fabricated by pulsed laser deposition, high temperature heating device is needed that provides high temperature stability and strong durability in high oxygen partial pressure environments while minimizing performance degradation caused by surface contamination. In this study, new heating device have been developed for PLD process that deposit and growth the superconducting material continuously on substrate using reel-to-reel transportation apparatus. New heating device is designed and fabricated using iron-chromium-aluminum wire and alumina tube as a heating element and sheath materials, respectively. Heating temperature of the heater was reached over 850 ℃ under 700 mTorr of oxygen partial pressure and is kept for 5 hours. The experimental results confirm the effectiveness of the developed heating device system in maintaining a stable and consistent temperature in PLD. These research findings make significant contributions to the exploration of new applications for superconducting materials and the enhancement of superconducting device performance.