• 제목/요약/키워드: Air-Water Interface

검색결과 282건 처리시간 0.02초

G4-48PyP 덴드리틱 거대분자 박막의 금속이온 착체에 의한 전기적 특성 (Electrical Properties by Effect of Metal Complex of G4-48PyP Dendritic Macromolcules Thin Films)

  • 손정호;정상범;김병상;박재철;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.16-18
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    • 2002
  • We attempted to fabricate a dendrimer Langmuir-Blodgett(LB) films containing 48 pyridinepropanol functional end group. As the pyridinepropanol functional group could form a complex structure with metal ions. In this study the samples for electrical measurement were fabricated to two types metal complexes with $Pt^{4+}$ and $Fe^{2+}$ ions by LB method. And we have investigated the surface activity at the air-water interface as well as the electrical properties for the monolayers of pure G4-48PyP dendrimer and its complex with metal ions($Pt^{4+}$ and $Fe^{2+}$ ions). In the surface pressure-area($\pi-A$) isotherms of the dendrimers, the stable condensed films formed at the air-water interface and the metal ions effect showed the difference on molecular behavior. We have studied the electrical properties of the ultra thin dendrimer LB films investigated by the current-voltage(I-V) characteristics of metal/dendrimer LB films/metal(MIM) structure. In conclusion, it is demonstrated that the metal ion around G4-48PyP dendrimer can contribute to make formation of network structure among dendrimers and it result from the change of electrical properties.

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Experimental study on air-water countercurrent flow limitation in a vertical tube based on measurement of film thickness behavior

  • Wan, Jie;Sun, Wan;Deng, Jian;Pan, Liang-ming;Ding, Shu-hua
    • Nuclear Engineering and Technology
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    • 제53권6호
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    • pp.1821-1833
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    • 2021
  • The gas-liquid counter-current flow limitation (CCFL) is closely related to efficient and safety operation of many equipment in industrial cycle. Air-water countercurrent flow experiments were performed in a tube with diameter of 25 mm to understand the triggering mechanism of CCFL. A parallel electrode probe was utilized to measure film thickness whereby the time domain and frequency domain characteristics of liquid film was obtained. The amplitude of the interface wave is small at low liquid flow rate while it becomes large at high liquid flow rate after being disturbed by the airflow. The spectral characteristic curve shows a peak-shaped distribution. The crest exists between 0 and 10 Hz and the amplitude decreases with the frequency increase. The analysis of visual observation and characteristic of film thickness indicate that two flooding mechanisms were identified at low and high liquid flow rate, respectively. At low liquid flow rate, the interfacial waves upward propagation is responsible for the formation of CCFL onset. While flooding at high liquid flow rate takes place as a direct consequence of the liquid bridging in tube due to the turbulent flow pattern. Moreover, it is believed that there is a transition region between the low and high liquid flow rate.

콘크리트와 도막 방수층 계면에 발생되는 수증기압에 관한 실험적 연구 (An Experimental Study of Water Vapor Pressure that occurs at the Interface of a Fluid-Applied Membrane and Concrete)

  • 고진수;김문희;이성복;신윤호
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2006년도 추계 학술논문 발표대회 논문집
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    • pp.147-150
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    • 2006
  • Of the total defects that have occurred recently in the Korean construction market, over 30% are caused by the construction of defective waterproofing, and the phenomenon of air pockets in the waterproofing layer, which is caused by the concrete vapor pressure, is known to be the primary cause of defective waterproofing. Accordingly, in this study the theory about the relationship between water pressure and temperature as well as the damp-proofing volume of concrete and, then, the change of vapor pressure volume was measured and analyzed by making a test sample after spraying a dampness remover and a waterproofing material to a prepared test body. As a result of measuring the water vapor pressure for the surface temperature of the waterproofing layer with the fluid-applied membrane temperature based on about $10^{\circ}C$, which is the average temperature of Seoul, it was found that first, the fluid-applied membrane elevated up to about $40^{\circ}C$, and the water vapor pressure generated from the fluid-applied membrane was about $0.3kgf/cm^2$ when the surface temperature of the waterproofing layer was raised up to about $80^{\circ}C$. Second, when the fluid-applied membrane temperature of the waterproofing layer was raised from $30^{\circ}C\;to\;35^{\circ}C,\;about\;0.1kgf/cm^2$ of water vapor pressure was generated, and when supplying a thermal source to raise the fluid-applied membrane temperature of the waterproofing layer from $35^{\circ}C\;to\;40^{\circ}C$, approximately $0.05kgf/cm^2$ of water vapor pressure was generated.

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Numerical Simulation of 3D Free-Surface Flows by Using CIP-based and FV-based Methods

  • Yang, Kyung-Kyu;Nam, Bo-Woo;Kim, Yong-Hwan
    • International Journal of Ocean System Engineering
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    • 제1권3호
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    • pp.136-143
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    • 2011
  • In this paper, three-dimensional free-surface flows are simulated by using two different numerical methods, the constrained interpolation profile (CIP)-based and finite volume (FV)-based methods. In the CIP-based method, the governing equations are solved on stationary staggered Cartesian grids by a finite difference method, and an immersed boundary technique is applied to deal with wave-body interactions. In the FV-based method, the governing equations are solved by applying collocated finite volume discretization, and body-fitted meshes are used. A free-surface boundary is considered as the interface of the multi-phase flow with air and water, and a volumeof-fluid (VOF) approach is applied to trace the free surface. Among many variations of the VOF-type method, the tangent of hyperbola for interface capturing (THINC) and the compressive interface capturing scheme for arbitrary meshes (CICSAM) techniques are used in the CIP-based method and FV-based method, respectively. Numerical simulations have been carried out for dam-breaking and wave-body interaction problems. The computational results of the two methods are compared with experimental data and their differences are observed.

Ro-Pax 선형의 천수역에서 조파저항성능 평가를 위한 수치적 연구 (A Numerical Study to Evaluate the Resistance Performance of a Ro-Pax Hull Form in Shallow Water)

  • 홍춘범;신수철;김정중;최순호
    • 대한조선학회논문집
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    • 제42권4호
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    • pp.315-321
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    • 2005
  • The effect of water depth on the wave making resistance performance is great where Froude number based on the water depth is close to one. The increase of wave making resistance due to the shallow water effect is evaluated by a numerical analysis in the present study. Three-dimensional Navier-Stokes and continuity equations are employed for the present study and the equations are discretized by finite difference method. The interface between water and air is determined by the level set method. In order to validate the numerical method, the change of resistance performance for Wigley hull according to the water depth is evaluated and the computed resistance coefficient is compared with measured one. The present numerical method is applied for the simulation of wave phenomena around a Ro-Pax hull form and the computed results are discussed in the resistance performance point of view.

저분자량 유화제 첨가에 의한 계면 흡착 메칠셀룰로오스의 경쟁이탈 특성 연구 (Competitive Displacement of Methylcellulose from Oil-Water Interface by Various Emulsifiers)

  • 홍순택
    • 한국식품영양과학회지
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    • 제37권10호
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    • pp.1271-1277
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    • 2008
  • 본 연구는 MC를 함유하는 유화식품 제조에 필요한 기초 자료를 얻고자 물/기름 계면에서 저분자량 유화제와 계면 흡착 MC와의 경쟁이탈(혹은 흡착) 현상을 구명하고자 수행 하였다. 경쟁이탈 특성 변화는 계면막 조성 분석, 표면 전단 점도 측정 혹은 표면 장력을 측정하여 분석하였다. MC 유화액(1 wt% MC, 10 wt% n-tetradecane, 20 mM bis-tris, pH7)에 수용성 Tween 20을 첨가할 경우 첨가 농도의 증가에 따라 MC 흡착량이 감소하여 0.1 wt% 첨가 농도에서 모든 계면에 흡착된 MC가 수용액으로 이탈되었으며, 표면 전단 점도를 측정 결과도 이와 잘 일치하였다. 지용성 Span 80을 첨가할 경우 낮은 농도에서($\leq$0.05 wt%) 유화제를 첨가하지 않은 경우와 비교하여 MC load가 약 10$\sim$25% 증가하였고 (상승작용), 농도의 증가와 더불어 흡착량은 감소하였으나 고농도(0.1 wt%)에서 MC 분자의 완전한 경쟁 이탈은 관찰되지 않았다. 또한, 표면 전단 점도 측정을 통하여 물/기름 계면에서 MC와 Span 80 간의 상승작용을 확인할 수 있었다. 수용성 SDS 첨가할 경우 경쟁 이탈 현상은 Tween 20의 경우와 비교하여 다소 다른 형태를 나타내었다. 즉 SDS 첨가 농도의 증가와 더불어 MC load는 점차로 감소하는 경향을 보였으나 Tween 20 첨가의 경우와 달리 높은 SDS농도(> 0.1 wt%)에서도 유화 지방구 표면에는 약간의 MC가 존재하고 있는 것으로 분석되었고, 이를 SDS와 MC 분자간의 경쟁 이탈 현상 혹은 복합체 형성을 시사하는 것으로 추정하였으며, air-water 표면 장력의 변화도 이와 잘 일치하고 있었다. 결론적으로 계면에 흡착된 MC는 저분자량 유화제에 의하여 수용액 상으로 경쟁이탈(competitive displacement) 되었으며, 그 형태는 유화제 종류에 따라 다르게 나타난 것으로 관찰되었다.

대체냉매의 2중관 응축기 열 및 물질전달과 성능평가 (Heat and Mass Transfer Characteristics and Performance Evaluation of a Double-Tube Condenser for an Alternative Refrigerant)

  • 이상무;박병덕;소산번
    • 설비공학논문집
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    • 제14권6호
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    • pp.468-476
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    • 2002
  • This paper deals with heat and mass transfer characteristics and performance evaluation of a counter flow double-tube condenser for a multi-component refrigerant mixture. The local heat and mass transfer characteristics of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a are evaluated for a counter flow double-tube condenser cooled by water. Then, the local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, heat flux and condensation mass flux are obtained. The heat exchange performance for ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a on the total pressure drop and the heat transfer characteristics are also compared with those for R404A, R410A, R502, R22, R32, Rl23 and R134a.

작은 수직관을 흐르는 슬러그 유동의 물질전달 특성에 대한 반경험적 해석 (Semi-Empirical Analysis of the Mass Transfer Characteristics of the Slug Flow in Vertical Mesoscale Tubes)

  • 김동선
    • 설비공학논문집
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    • 제26권8호
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    • pp.366-374
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    • 2014
  • Experimental mass transfer data, which were obtained for the $CO_2$-water slug flows in vertical tubes with 2, 5, and 8mm diameters, were analyzed in comparison with the penetration theory. It was found that a penetration model with molecular diffusion coefficient cannot predict the experimental data accurately. An effective diffusion coefficient, which considers enhancement effect of interfacial waves, was suggested to improve prediction. Another empirical factor was also suggested to consider the effect of non-uniform interface velocity. A modified penetration model was found to be capable of predicting the experimental data reasonably well.

기후변화가 주암호 수온성층구조에 미치는 영향 예측 (Projection of the Climate Change Effects on the Vertical Thermal Structure of Juam Reservoir)

  • 윤성완;박관영;정세웅;강부식
    • 한국물환경학회지
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    • 제30권5호
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    • pp.491-502
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    • 2014
  • As meteorology is the driving force for lake thermodynamics and mixing processes, the effects of climate change on the physical limnology and associated ecosystem are emerging issues. The potential impacts of climate change on the physical features of a reservoir include the heat budget and thermodynamic balance across the air-water interface, formation and stability of the thermal stratification, and the timing of turn over. In addition, the changed physical processes may result in alteration of materials and energy flow because the biogeochemical processes of a stratified waterbody is strongly associated with the thermal stability. In this study, a novel modeling framework that consists of an artificial neural network (ANN), a watershed model (SWAT), a reservoir operation model(HEC-ResSim) and a hydrodynamic and water quality model (CE-QUAL-W2) is developed for projecting the effects of climate change on the reservoir water temperature and thermal stability. The results showed that increasing air temperature will cause higher epilimnion temperatures, earlier and more persistent thermal stratification, and increased thermal stability in the future. The Schmidt stability index used to evaluate the stratification strength showed tendency to increase, implying that the climate change may have considerable impacts on the water quality and ecosystem through changing the vertical mixing characteristics of the reservoir.

Comparison of Potential and Viscous Codes for Water Entry Problem

  • Kwon, Sun-Hong;Park, Chang-Woo;Shin, Jae-Young
    • International Journal of Ocean System Engineering
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    • 제2권1호
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    • pp.32-36
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    • 2012
  • This paper presents a comparison of potential and viscous computational codes for the water entry problem. A po-tential code was developed which adopted the boundary element method to solve the problem. A nonlinear free surface boundary condition was integrated to find new locations of free surface. The dynamic boundary condition was simplified by taking constant potential values for every time steps. The simplified dynamic boundary condition was applied in the new position of the free surface not at the mean level, which is the usual practice for linearized theory. The commercial code FLUENT was used to solve the water entry problem from the viscosity point of view. The movement of the air-liquid interface is traced by distribution of the volume fraction of water in a computational cell. The pressure coefficients were compared with each other, while experimental results published by other researchers were also examined. The characteristics of each method were discussed to clarify merits and limitations when they were applied to the water entry problems.