• Title/Summary/Keyword: Air-Water Interface

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Electrical Properties by Effect of Metal Complex of G4-48PyP Dendritic Macromolcules Thin Films (G4-48PyP 덴드리틱 거대분자 박막의 금속이온 착체에 의한 전기적 특성)

  • Son, J.H.;Jung, S.B.;Kim, B.S.;Park, T.C.;Kwon, Y.S.
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.16-18
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    • 2002
  • We attempted to fabricate a dendrimer Langmuir-Blodgett(LB) films containing 48 pyridinepropanol functional end group. As the pyridinepropanol functional group could form a complex structure with metal ions. In this study the samples for electrical measurement were fabricated to two types metal complexes with $Pt^{4+}$ and $Fe^{2+}$ ions by LB method. And we have investigated the surface activity at the air-water interface as well as the electrical properties for the monolayers of pure G4-48PyP dendrimer and its complex with metal ions($Pt^{4+}$ and $Fe^{2+}$ ions). In the surface pressure-area($\pi-A$) isotherms of the dendrimers, the stable condensed films formed at the air-water interface and the metal ions effect showed the difference on molecular behavior. We have studied the electrical properties of the ultra thin dendrimer LB films investigated by the current-voltage(I-V) characteristics of metal/dendrimer LB films/metal(MIM) structure. In conclusion, it is demonstrated that the metal ion around G4-48PyP dendrimer can contribute to make formation of network structure among dendrimers and it result from the change of electrical properties.

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Experimental study on air-water countercurrent flow limitation in a vertical tube based on measurement of film thickness behavior

  • Wan, Jie;Sun, Wan;Deng, Jian;Pan, Liang-ming;Ding, Shu-hua
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1821-1833
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    • 2021
  • The gas-liquid counter-current flow limitation (CCFL) is closely related to efficient and safety operation of many equipment in industrial cycle. Air-water countercurrent flow experiments were performed in a tube with diameter of 25 mm to understand the triggering mechanism of CCFL. A parallel electrode probe was utilized to measure film thickness whereby the time domain and frequency domain characteristics of liquid film was obtained. The amplitude of the interface wave is small at low liquid flow rate while it becomes large at high liquid flow rate after being disturbed by the airflow. The spectral characteristic curve shows a peak-shaped distribution. The crest exists between 0 and 10 Hz and the amplitude decreases with the frequency increase. The analysis of visual observation and characteristic of film thickness indicate that two flooding mechanisms were identified at low and high liquid flow rate, respectively. At low liquid flow rate, the interfacial waves upward propagation is responsible for the formation of CCFL onset. While flooding at high liquid flow rate takes place as a direct consequence of the liquid bridging in tube due to the turbulent flow pattern. Moreover, it is believed that there is a transition region between the low and high liquid flow rate.

An Experimental Study of Water Vapor Pressure that occurs at the Interface of a Fluid-Applied Membrane and Concrete (콘크리트와 도막 방수층 계면에 발생되는 수증기압에 관한 실험적 연구)

  • Ko, Jin-Soo;Kim, Mun-Hee;Lee, Sung-Bok;Shin, Yun-Ho
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.147-150
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    • 2006
  • Of the total defects that have occurred recently in the Korean construction market, over 30% are caused by the construction of defective waterproofing, and the phenomenon of air pockets in the waterproofing layer, which is caused by the concrete vapor pressure, is known to be the primary cause of defective waterproofing. Accordingly, in this study the theory about the relationship between water pressure and temperature as well as the damp-proofing volume of concrete and, then, the change of vapor pressure volume was measured and analyzed by making a test sample after spraying a dampness remover and a waterproofing material to a prepared test body. As a result of measuring the water vapor pressure for the surface temperature of the waterproofing layer with the fluid-applied membrane temperature based on about $10^{\circ}C$, which is the average temperature of Seoul, it was found that first, the fluid-applied membrane elevated up to about $40^{\circ}C$, and the water vapor pressure generated from the fluid-applied membrane was about $0.3kgf/cm^2$ when the surface temperature of the waterproofing layer was raised up to about $80^{\circ}C$. Second, when the fluid-applied membrane temperature of the waterproofing layer was raised from $30^{\circ}C\;to\;35^{\circ}C,\;about\;0.1kgf/cm^2$ of water vapor pressure was generated, and when supplying a thermal source to raise the fluid-applied membrane temperature of the waterproofing layer from $35^{\circ}C\;to\;40^{\circ}C$, approximately $0.05kgf/cm^2$ of water vapor pressure was generated.

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Numerical Simulation of 3D Free-Surface Flows by Using CIP-based and FV-based Methods

  • Yang, Kyung-Kyu;Nam, Bo-Woo;Kim, Yong-Hwan
    • International Journal of Ocean System Engineering
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    • v.1 no.3
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    • pp.136-143
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    • 2011
  • In this paper, three-dimensional free-surface flows are simulated by using two different numerical methods, the constrained interpolation profile (CIP)-based and finite volume (FV)-based methods. In the CIP-based method, the governing equations are solved on stationary staggered Cartesian grids by a finite difference method, and an immersed boundary technique is applied to deal with wave-body interactions. In the FV-based method, the governing equations are solved by applying collocated finite volume discretization, and body-fitted meshes are used. A free-surface boundary is considered as the interface of the multi-phase flow with air and water, and a volumeof-fluid (VOF) approach is applied to trace the free surface. Among many variations of the VOF-type method, the tangent of hyperbola for interface capturing (THINC) and the compressive interface capturing scheme for arbitrary meshes (CICSAM) techniques are used in the CIP-based method and FV-based method, respectively. Numerical simulations have been carried out for dam-breaking and wave-body interaction problems. The computational results of the two methods are compared with experimental data and their differences are observed.

A Numerical Study to Evaluate the Resistance Performance of a Ro-Pax Hull Form in Shallow Water (Ro-Pax 선형의 천수역에서 조파저항성능 평가를 위한 수치적 연구)

  • Hong, Chun-Beom;Shin, Soo-Chul;Kim, Jung-Joong;Choi, Soon-Ho
    • Journal of the Society of Naval Architects of Korea
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    • v.42 no.4 s.142
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    • pp.315-321
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    • 2005
  • The effect of water depth on the wave making resistance performance is great where Froude number based on the water depth is close to one. The increase of wave making resistance due to the shallow water effect is evaluated by a numerical analysis in the present study. Three-dimensional Navier-Stokes and continuity equations are employed for the present study and the equations are discretized by finite difference method. The interface between water and air is determined by the level set method. In order to validate the numerical method, the change of resistance performance for Wigley hull according to the water depth is evaluated and the computed resistance coefficient is compared with measured one. The present numerical method is applied for the simulation of wave phenomena around a Ro-Pax hull form and the computed results are discussed in the resistance performance point of view.

Competitive Displacement of Methylcellulose from Oil-Water Interface by Various Emulsifiers (저분자량 유화제 첨가에 의한 계면 흡착 메칠셀룰로오스의 경쟁이탈 특성 연구)

  • Hong, Soon-Taek
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.10
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    • pp.1271-1277
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    • 2008
  • Competitive displacement of methylcellulose (MC) absorbed at the oil-water interface was investigated by interfacial composition, surface shear viscosity, or surface tension measurements. It was found that all emulsifiers could competitively displace the interfacial MC from the oil-water interface but their behaviors were different from each other. With Tween 20 added to MC emulsion (1 wt% MC, 10 wt% n-tetradecane, 20 mM bis-tris, pH 7), MC load was steadily decreased with increasing concentrations of the emulsifier, as confirmed by surface shear viscosity measurements; moreover, there was complete MC displacement from the emulsion droplet surface at high concentration (0.1 wt%). The oil-soluble Span 80 was found to show a synergism with MC at the interface, which resulted in higher MC load at relatively low emulsifier concentrations ($\leq$0.05 wt%). At a higher emulsifier concentration (0.1 wt%) limited MC displacement was observed. These results were well supported by surface shear viscosity measurements. With water-soluble SDS, MC load was decreased with increasing concentrations of the emulsifier. Unlike Tween 20, however, it was found that at high concentrations (> 0.1 wt%), there was still some MC remaining at the droplet surface. Surface tension measurements are suggestive of an interfacial complex between MC and SDS.

Heat and Mass Transfer Characteristics and Performance Evaluation of a Double-Tube Condenser for an Alternative Refrigerant (대체냉매의 2중관 응축기 열 및 물질전달과 성능평가)

  • 이상무;박병덕;소산번
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.6
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    • pp.468-476
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    • 2002
  • This paper deals with heat and mass transfer characteristics and performance evaluation of a counter flow double-tube condenser for a multi-component refrigerant mixture. The local heat and mass transfer characteristics of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a are evaluated for a counter flow double-tube condenser cooled by water. Then, the local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, heat flux and condensation mass flux are obtained. The heat exchange performance for ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a on the total pressure drop and the heat transfer characteristics are also compared with those for R404A, R410A, R502, R22, R32, Rl23 and R134a.

Semi-Empirical Analysis of the Mass Transfer Characteristics of the Slug Flow in Vertical Mesoscale Tubes (작은 수직관을 흐르는 슬러그 유동의 물질전달 특성에 대한 반경험적 해석)

  • Kim, Dong-Seon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.26 no.8
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    • pp.366-374
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    • 2014
  • Experimental mass transfer data, which were obtained for the $CO_2$-water slug flows in vertical tubes with 2, 5, and 8mm diameters, were analyzed in comparison with the penetration theory. It was found that a penetration model with molecular diffusion coefficient cannot predict the experimental data accurately. An effective diffusion coefficient, which considers enhancement effect of interfacial waves, was suggested to improve prediction. Another empirical factor was also suggested to consider the effect of non-uniform interface velocity. A modified penetration model was found to be capable of predicting the experimental data reasonably well.

Projection of the Climate Change Effects on the Vertical Thermal Structure of Juam Reservoir (기후변화가 주암호 수온성층구조에 미치는 영향 예측)

  • Yoon, Sung Wan;Park, Gwan Yeong;Chung, Se Woong;Kang, Boo Sik
    • Journal of Korean Society on Water Environment
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    • v.30 no.5
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    • pp.491-502
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    • 2014
  • As meteorology is the driving force for lake thermodynamics and mixing processes, the effects of climate change on the physical limnology and associated ecosystem are emerging issues. The potential impacts of climate change on the physical features of a reservoir include the heat budget and thermodynamic balance across the air-water interface, formation and stability of the thermal stratification, and the timing of turn over. In addition, the changed physical processes may result in alteration of materials and energy flow because the biogeochemical processes of a stratified waterbody is strongly associated with the thermal stability. In this study, a novel modeling framework that consists of an artificial neural network (ANN), a watershed model (SWAT), a reservoir operation model(HEC-ResSim) and a hydrodynamic and water quality model (CE-QUAL-W2) is developed for projecting the effects of climate change on the reservoir water temperature and thermal stability. The results showed that increasing air temperature will cause higher epilimnion temperatures, earlier and more persistent thermal stratification, and increased thermal stability in the future. The Schmidt stability index used to evaluate the stratification strength showed tendency to increase, implying that the climate change may have considerable impacts on the water quality and ecosystem through changing the vertical mixing characteristics of the reservoir.

Comparison of Potential and Viscous Codes for Water Entry Problem

  • Kwon, Sun-Hong;Park, Chang-Woo;Shin, Jae-Young
    • International Journal of Ocean System Engineering
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    • v.2 no.1
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    • pp.32-36
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    • 2012
  • This paper presents a comparison of potential and viscous computational codes for the water entry problem. A po-tential code was developed which adopted the boundary element method to solve the problem. A nonlinear free surface boundary condition was integrated to find new locations of free surface. The dynamic boundary condition was simplified by taking constant potential values for every time steps. The simplified dynamic boundary condition was applied in the new position of the free surface not at the mean level, which is the usual practice for linearized theory. The commercial code FLUENT was used to solve the water entry problem from the viscosity point of view. The movement of the air-liquid interface is traced by distribution of the volume fraction of water in a computational cell. The pressure coefficients were compared with each other, while experimental results published by other researchers were also examined. The characteristics of each method were discussed to clarify merits and limitations when they were applied to the water entry problems.