• 제목/요약/키워드: Air cell

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연료전지 내에서의 왕복유동을 이용한 확산증대 효과에 대한 연구 (Enhanced Diffusion in a Polymer Electrolyte Membrane Fuel Cell Using Pulsating Flow)

  • 황용신;최종원;이대영;김민수;이대흥;김서영;조성호;차석원
    • 대한기계학회논문집B
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    • 제34권2호
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    • pp.185-189
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    • 2010
  • 본 연구에서는 진동자를 이용하여 채널 내 공기 중 산소의 확산을 증대시키는 방법을 고안하였다. 왕복 유동 시 물질 전달을 지배하는 두 가지 요소인 왕복 유동 주파수와 왕복 유동 거리가 채널 내의 길이방향 확산에 어떤 영향을 미치는지에 대해 선행연구 결과를 이용한 이론적 해석을 통하여 보여주었으며, 이러한 채널내의 길이방향 확산 량의 증가가 스택 성능에 미치는 영향에 대해 알 수 있었다. 스택의 채널 내의 길이방향 확산량은 연료전지가 반응하는 반응량에 비례하게 되며, 따라서 스택내의 길이방향 확산 량을 늘려주는 만큼 연료전지의 최고 파워 밀도가 늘어나게 된다. 이러한 길이방향 확산 량을 증가시키기 위해서는 왕복 유동이 좋은 방법이 되며, 연료전지 운전 시 왕복 유동의 주파수를 증가시키게 되거나 왕복 유동의 거리를 증가시킬수록 채널 내의 길이방향으로 확산 량이 증대되게 된다.

연성 기판을 전류 집전체로 사용한 평판형 연료전지 스택 (Miniature planar stack using the flexible Printed Circuit Board as current collectors)

  • 김성한;차혜연;;차석원;장재혁
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.1-4
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    • 2008
  • Fuel cells have the potential of providing several times higher energy storage densities than those possible using current state-of-the-art lithium-ion batteries, but current energy density of fuel cell system is not better than that of lithium-ion batteries. To achieve the high energy density, volume and weight of fuel cell system need to be reduced by miniaturizing system components such as stack, fuel tank, and balance-of-plant. In this paper, the thin flexible PCB (Printed circuit board) is used as a current collector to reduce the stack volume. Two end plates are made from light weight aluminum alloy plate. The plate surface is wholly oxidized through the anodizing treatment for electrical insulation. The opening rate of cathode plate hole is optimized through unit cell performance measurement of various opening rates. The performances are measured at room temperature and ambient pressure condition without any repulsive air supply. The active area of MEA is 10.08 $cm^2$ and active area per a unit cell is 1.68 $cm^2$. The peak power density is about 210 mW/$cm^2$ and the air-breathing planar stack of 2 Wis achieved as a small volume of 18 cc.

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Enhanced Essential Oil Formation by Two-phase Culture of Mentha piperita Cells in Shake Flask and Air-lift Bioreactors

  • Kim, Teresa;Kim, Tae-Yong;Bae, Geun-Won;Chae, Young-Am;Lee, Hyong-Joo;Chung, In-Sik
    • Journal of Microbiology and Biotechnology
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    • 제5권6호
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    • pp.364-369
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    • 1995
  • Effect of two-phase culture on Mentha piperita cell growth and essential oil formation was investigated using shake flask and air-lift bioreactors. LiChroprep RP-B(RP-B) addition did not impair M. piperita cell growth, but resulted in stimulated formation of essential oils and increased ratios of extracellular oil to intracellular oil formation. However, the combined use of RP-B and chitosan elicitor was not synergistic. Volumetric productivity of essential oils in RP-B treated culture using cell-recycled air-lift bioreactor was $6.9\;\mu\textrm{g}/l{\cdot}day$ which was substantially higher than that obtainable from the control. Our results demonstrate the potential of a second phase to enhance overall productivity for M. piperita cell culture.

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배열을 이용한 연료전지 발전시스템 설계 (Design of Fuel Cell Power Generation System Using a Waste Heat)

  • 최영재;전재호;전중환
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.133-133
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    • 2009
  • 연료전지는 연료의 화학적 에너지를 전기화학 반응을 통하여 직접 전기로 변환하기 때문에 에너지 전환효율이 높고 공해물질을 배출하지 않는 환경친화적인 고효율 발전방식으로, 특히 용융탄산염 연료전지(MCFC) 및 고체산화물 연료전지(SOFC)같은 고온형 연료전지의 경우 분산전원이나 중앙집중발전 같은 발전용에 적합한 연료전지로 평가받고 있다. 현재 MCFC 및 SOFC등의 발전용 연료전지 시스템의 효율은 약 50% 정도이며, 시스템의 발전효율을 높이기 위한 여러 연구가 진행되고 있다. 그 중에서 고온의 배열을 이용하여 연료전지 발전시스템의 효율을 향상시키기 위해 FuelCell Energy, Ansaldo Fuel Cells 및 Simens Westinghouse 등에서 수백 kW급의 fuel cell - gas turbine hybrid system에 대한 상용화 수준의 실증연구가 진행되었다. 본 연구에서는 발전용 연료전지 시스템의 발전효율을 높이기 위한 방안 중 하나로 배열을 이용하여 steam을 발생시켜 air amplifier에 사용함으로써 연료전지 시스템의 MBOP(Mechanical Balance of Plant)중 전력을 소비하는 air blower를 대체하여, 시스템 효율을 향상시키고 시스템의 가용성을 높일 수 있는 설계안에 대하여 논하고자 한다.

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200 W급 휴대용 고분자 전해질막 연료전지 시스템 개발 (Development of a 200 W Portable PEM Fuel Cell System)

  • 한훈식;김윤호;조창환;김서영;현재민
    • 설비공학논문집
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    • 제24권2호
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    • pp.91-101
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    • 2012
  • A 200 W portable polymer electrolyte membrane fuel cell (PEMFC) system is developed. The PEMFC system consists of an air-cooled fuel cell stack module, a fuel supply subsystem, a power management subsystem, and a control electronics subsystem. The control logic is designed for the stable system operation. The system-level performance evaluation discloses that the present PEMFC system provides a rated power output of 200.5 W at 13.4 V with the maximum balance-of-plant (BOP) efficiency of 72%, and maximum system efficiency based on lower heating value (LHV) is 37% at 120.7 W system power output.

Influence of the cathode catalyst layer thickness on the behaviour of an air breathing PEM fuel cell

  • Ferreira-Aparicio, Paloma;Chaparro, Antonio M.
    • Advances in Energy Research
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    • 제2권2호
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    • pp.73-84
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    • 2014
  • Fuel cells of proton exchange membrane type (PEMFC) working with hydrogen in the anode and ambient air in the cathode ('air breathing') have been prepared and characterized. The cells have been studied with variable thickness of the cathode catalyst layer ($L_{CL}$), maintaining constant the platinum and ionomer loads. Polarization curves and electrochemical active area measurements have been carried out. The polarization curves are analyzed in terms of a model for a flooded passive air breathing cathode. The analysis shows that $L_{CL}$ affects to electrochemical kinetics and mass transport processes inside the electrode, as reflected by two parameters of the polarization curves: the Tafel slope and the internal resistance. The observed decrease in Tafel slope with decreasing $L_{CL}$ shows improvements in the oxygen reduction kinetics which we attribute to changes in the catalyst layer structure. A decrease in the internal resistance with $L_{CL}$ is attributed to lower protonic resistance of thinner catalyst layers, although the observed decrease is lower than expected probably because the electronic conduction starts to be hindered by more hydrophilic character and thicker ionomer film.

kW급 SOFC 시스템용 개질기 최적화 (A Study on Optimization of Reformer for kW Class SOFC System)

  • 이용;박세진;김민수;신장식;신석재
    • 한국수소및신에너지학회논문집
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    • 제29권4호
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    • pp.317-323
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    • 2018
  • Solid oxide fuel cell (SOFC) operates at high temperature, therefor has the advantage of higher power generation and using exhaust heat than other fuel cells. In particular, the reforming reaction can be performed inside the SOFC stack to reduce the cooling of the stack and the burden on the reformer reactor. In this study, the reformer structure, operating characteristics, and thermal efficiency were evaluated for the optimization design of a heat exchanger type reformer of a 1 kW SOFC system.

수치시뮬레이션에 의한 공기부양선 주위의 유동장해석과 조파저항계산 (Numerical Analysis on Flow Fields and the Calculation of Wave Making Resistance about Air Supported Ships)

  • 나영인;이영길
    • 한국전산유체공학회지
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    • 제1권1호
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    • pp.55-63
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    • 1996
  • Numerical computations are carried out to analyze the characteristics of flow fields around Air Supported Ships. The computations are performed in a rectangular grid system based on MAC(Marker And Cell) method. The governing equations are represented in finite difference forms by forward differencing in time and centered differencing in space except for its convection terms. For the certification of this numerical analysis method, the computations of flow fields around a Catamaran, an ACV(Air Cushion Vehicle) modeled with pressure distribution on free surface and two SES(Surface Effect Ship)'s are carried out, The results of the present computations are compared with the previously presented computational and experimental results in the same condition.

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구조 해석과 유동 해석을 통한 연료전지 공기판 설계 (Structural and Flow Analysis for Designing Air Plate of a Fuel Cell)

  • 박정선;양지혜;이원용
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.585-590
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    • 2003
  • The distributions of mass flow rate and pressure are major factors to deside the performance of a proton exchange membrane fuel cell (PEMFC). These factors are affected by channel configuration of air plate. In this paper. structural analysis is performed to investigate deformation of porous media. Two kind of models are suggest for flow analyses. Deformed porous media and undeformed porous media are considered for air plate model. The Numerical flow analysis results with deformed porous media and undeformed porous media had some discrepancy in pressure distribution. The pressure and velocity in a working condition are numerically calculated to predict the performance of the air plates. Distributions of the parameters in the PEMFC are analyzed numerically under steady-state conditions.

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Zn/Air Fuel Cell의 전기화학적 성능에 미치는 인자연구 (Factors Affecting on Electrochemical Performances for Zn/Air Fuel Cell)

  • 이창우;엄승욱;김현수;문성인;윤문수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 B
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    • pp.1717-1718
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    • 2005
  • Zn/Air 전지는 방전하는 동안에 최종 방전 cut-off 전압에 이르기까지 평탄한 voltage profile의 전기화학적 특성을 보여준다. Air cathode 전극의 경우, 전극의 porosity에 따라 특성변화에 큰 영향을 가지는 것으로 보이며 이의 비교연구를 위해 사용되어지는 활성탄의 종류를 달리함으로써 이러한 인자의 영향을 이해하고자 하였다. 이러한 인자연구는 discharge voltage, specific capacity, 및 energy 등의 연구결과를 바탕으로 고찰되어졌으며 결과적으로 공기 유로를 통한 산소의 원활한 공급 여부가 주요 원인인 것으로 여겨진다.

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