• Applied Chemistry for Engineering
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• v.22 no.3
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• pp.296-300
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• 2011

In this work, various wood biomasses were used to determine the combustion characteristics for the fuel of cogeneration plant. Combustion characteristics of four types, i.e., (i) forest products, (ii) recycled wood, (iii) empty fruit bunch, and (iv) palm kernel shell, were examined via thermal gravimetric analyzer (TGA) in air atmosphere and coal was used as a comparison group. From the TGA results, the combustion of the wood biomass was occurred in the range of 280 to $420^{\circ}C$, which was lower than that of coal. Forest product showed the lowest activation energy (0.4 kJ/mol) compared to that of other wood biomasses (about 6 to 14 kJ/mol) and coal (64 kJ/mol). In addition, the reaction rate constant of the wood biomass was lower than that of coal. These results indicate the higher combustion initiation rate of wood biomass due to the high content of volatile matter, which had a low boiling point.

• Journal of the Korean Physical Society
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• v.73 no.9
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• pp.1340-1345
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• 2018

Mo-10 at.% Cu nanocomposite powders were fabricated by using planetary ball-milling (PBM), a mechanical alloying technique for preparing nanocomposite alloy powders of metals with mutual insolubility, and the variations in the physical and the chemical characteristics with the process conditions were investigated. We observed that Mo-10 at.% Cu was an appropriate composition to ensure a good alloying grade and minimal welding between particles. The influences of the temperature and the milling conditions on the mechanical alloying process and the phase change of Mo-10 at.% Cu composite powders were investigated, and the particle and the grain sizes of the powders after mechanical alloying were confirmed. The Mo-10 at.% Cu powders showed homogeneous elemental distributions and no phase changes up to $1200^{\circ}C$; their compositions were retained after the mechanical alloying process. The finest grain size obtained was about 5 nm for powders processed using optimum PBM processing conditions: ball-to-powder weight ratio of 5 : 1, ambient air atmosphere, a milling time of 20 h, a rotation speed of 200 rpm, and a stearic acid content of 4 wt.% produced superfine-grained Mo-10 at.% Cu nanocomposite powders with an average grain size of 5 nm (which is smaller than that of other similar materials reported in the literature). The analytical results confirmed that the PBM technique presented here is a promising method for preparing superfine-grained Mo-10 at.% Cu powders with improved properties.

• Journal of the Korean Geotechnical Society
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• v.37 no.1
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• pp.5-15
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• 2021

The areas consisting of frost susceptible soils in cold regions, such as the Arctic area, have problems of frost heave and thaw settlement due to the seasonal air temperature changes and internal temperature of installed structures. Ground stabilization methods for preventing frost heave and thaw settlement of frost susceptible soils include trenching, backfilling and thermo-syphon. The thermo-syphon is the method in which refrigerant can control the ground temperature by transferring the ground temperature to atmosphere in the from of two-phase flow through the heat circulation of the internal refrigerant. This numerical study applied the function of these thermo-syphon as the boundary condition through user-subroutine coding inside ABAQUS and compared and analyzed the temperature results of laboratory experiments.

• Atmosphere
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• v.30 no.4
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• pp.391-404
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• 2020

To understand the characteristics of the relationship between visibility and particulate matter (PM) in different meteorological conditions, we investigated the contributions of PM and relative humidity (RH) to visibility in Seoul, South Korea. For the period from 2001 to 2018, both PM and RH show descending trends, resulting in a visibility increase. PM has little impact on the hourly variation of visibility, which could be explained more by the RH variability. Meanwhile, the daily change of PM accounts for daily visibility variation. For the monthly variation of visibility, both PM and RH showed similar influence. The correlation coefficients of PM10, PM2.5, and RH with visibility was -0.486, -0.644, and -0.556, respectively, which became higher during the high PM seasons of spring and winter. The correlation coefficient between PM2.5 and visibility was -0.454 for RH higher than 80%, and -0.780 for RH between 40% and 60%. From 2017 to 2018, there were 10 cases of extreme visibility impairment, among which five cases were incurred by high PM pollution, and two cases were by high humidity. Further analysis with PM chemical composition measurements is required to better understand the characteristics of visibility in Seoul.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.34 no.5
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• pp.283-295
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• 2021

For the last decades, a research hotspot for the halide perovskites (HPs) is now showing great progress in terms of improving efficiency for numerous photovoltaic devices (PVDs). However, it still faces challenges in the case of long-term stability in the air atmosphere. Defect-free high-quality HP single crystals show their promising properties for the remarkable development of highly efficient and stable PVDs. Here, we summarize the growth processing routes for the stable HP single crystals as well as briefly discuss the pros and cons of those well-established synthesis routes. Furthermore, we briefly include the comparison note between the HP single crystals and polycrystalline perovskite films regarding their device applications. Based on the future progress, the review concludes subjective perspectives and current challenges for the development of HPs high-quality PVDs.

• Atmosphere
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• v.32 no.2
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• pp.149-162
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• 2022

This study investigated the prediction skill of the Asian dust seasonal forecasting model (GloSea5-ADAM) on the Asian dust and meteorological variables related to the dust generation for the period of 1991~2016. Additionally, we evaluated the prediction skill of those variables depending on the combination of the initial dates in the sub-seasonal scale for the dust source region affecting South Korea. The Asian dust and meteorological variables (10 m wind speed, 1.5 m relative humidity, and 1.5 m air temperature) from GloSea5-ADAM were compared to that from Synoptic observation and European Centre for medium range weather forecasts reanalysis v5, respectively, based on Mean Bias Error (MBE), Root Mean Square Error (RMSE), and Anomaly Correlation Coefficient (ACC) as evaluation criteria. In general, the Asian dust and meteorological variables in the source region showed high ACC in the prediction scale within one month. For all variables, the use of the initial dates closest to the prediction month led to the best performances based on MBE, RMSE, and ACC, and the performances could be improved by adjusting the number of ensembles considering the combination of the initial date. ACC was as high as 0.4 in Spring when using the closest two initial dates. In particular, the GloSea5-ADAM shows the best performance of Asian dust generation with an ACC of 0.60 in the occurrence frequency of Asian dust in March when using the closest initial dates for initial conditions.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.26 no.10
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• pp.1477-1482
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• 2022

Haze is a local weather phenomenon in which very small droplets float in the atmosphere, and the amount and characteristics of haze may vary depending on the region. In particular, these haze reduce visibility, which can cause air traffic interference and vehicle traffic accidents, and degrade the quality of security CCTVs and so on. Therefore, in the past 10 years, research on haze removal has been actively conducted to reduce damage caused by haze. In this study, local haze removal is performed by weight generation using a haziness degree evaluator to adaptively respond to haze-free, homogeneous haze, and non-homogeneous haze cases. And the proposed method improves the limitations of the existing static haze removal method, which assumes that there is haze in the input image and removes the haze. We also demonstrate the superiority of the proposed method through quantitative and qualitative performance evaluations with benchmark algorithms.

• Atmosphere
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• v.32 no.2
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• pp.119-133
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• 2022

From 2015 to 2021, high-concentration fine dust episodes with a daily average PM_2.5 concentration of 50 ㎍ m^-3 or higher were selected and classified into 3 types [long range transport (LRT), mixed (MIX) and Local emission and stagnant (LES)] using synoptic chart and backward trajectory analysis. And relationships between the fine particle data (PM_2.5 and PM₁₀ concentration and PM_2.5/PM₁₀ ratio) and meteorological data (PBLH, Ta, WS, U-wind, and Rainfall) were analyzed using hourly observation for the classification episodes on the Korean Peninsula and the Seoul metropolitan area (SMA). In LRT, relatively large particles such as dust are usually included, and in LES, fine particle is abundant. In the Korean peninsula, the rainfall was relatively increased centered on the middle and western coasts in MIX and LES. In the SMA, wind speed was rather strong in LRT and weak in LES. In LRT, rainfall was centered in Seoul, and in MIX and LES, rainfall appeared around Seoul. However, when the dust cases were excluded, the difference between the LRT and other types of air quality was decreased, but the meteorological variables (Ta, RH, Pa, PBLH, etc.) were further strengthened. In the case of the Korean Peninsula, it is difficult to find a clear relationship because regional influences (topographical elevation, cities and coasts, etc.) are complexly included in a rather wide area. In the SMA, it is analyzed that the effects of urbanization such as the urban heat island centered on Seoul coincide with the sea and land winds, resulting in a combination of high concentrations and meteorological phenomena.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.6
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• pp.120-127
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• 2022

Nitrogen oxide(NOx) is a major cause of air pollution, exists in the form of nitrogen monoxide and nitrogen dioxide, and is harmful to the human body. Recently, a number of studies to reduce NOx in the atmosphere have been conducted, and these efforts have been the same in the field of construction materials. It is known that NOx can be efficiently removed by using a photocatalytic reaction. In this study, the NOx removal performance of the foam composite using activated carbon(AC) and titanium dioxide(TiO₂) was investigated. AC was used to enhance the photocatalytic reaction of TiO₂ by increasing the internal specific surface area of the foam composite. In this study, foam composites were prepared using the substitution rate of AC as the main variable. The NOx removal performance of specimen was evaluated according to the test method presented in ISO-22197-1. The specific surface area of the foam composite showed a tendency to increase according to the AC content, but decreased at 15% or more. Also, when the AC substitution rate was 15%, the NOx removal efficiency was the highest.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.3
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• pp.259-268
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• 2022

Molten salt consisting primarily of eutectic LiCl-KCl is currently being used in electrorefiners in the Fuel Conditioning Facility at Idaho National Laboratory. Options are currently being evaluated for storing this salt outside of the argon atmosphere hot cell. The hygroscopic nature of eutectic LiCl-KCl makes is susceptible to deliquescence in air followed by extreme corrosion of metallic cannisters. In this study, the effect of occluding the salt into a zeolite on water sorption/desorption was tested. Two zeolites were investigated: Na-Y and zeolite 4A. Na-Y was ineffective at occluding a high percentage of the salt at either 10 or 20wt% loading. Zeolite-4A was effective at occluding the salt with high efficiency at both loading levels. Weight gain in salt occluded zeolite-4A (SOZ) from water sorption at 20% relative humidity and 40℃ was 17wt% for 10% SOZ and 10wt% for 20% SOZ. In both cases, neither deliquescence nor corrosion occurred over a period of 31 days. After hydration, most of the water could be driven off by heating the hydrated salt occluded zeolite to 530℃. However, some HCl forms during dehydration due to salt hydrolysis. Over a wide range of temperatures (320-700℃) and ramp rates (5, 10, and 20℃ min^-1), HCl formation was no more than 0.6% of the Cl^- in the original salt.