• Membrane Journal
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• v.15 no.2
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• pp.147-156
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• 2005

It is well-known that polyethersulfone (PES) has high $CO_2$ selectivity over $N_2\;(or\;CH_4)$ and excellent pressure resistance of $CO_2$ plasticization among muy commercialized engineering plastics[1-4]. Asymmetric PES hollow fiber membranes for flue gas separation were developed by dry-wet spinning technique. The dope solution consists of PES, NMP and acetone. Water and water/NMP mixtures are used in outer and inner coagulants, respectively. Gas permeation rate (i.e., permeance) and $CO_2/N_2$ selectivity were measured with pure gas, respectively and the micro-structure of hollow fiber membranes was characterized by scanning electron microscopy. The effects of polymer concentration, ratio of NMP to acetone, length of air gap, evaporation condition and silicone coating were investigated on the $CO_2/N_2$ separation properties of the hollow fibers. Optimized PES hollow fiber membranes exhibited high permeance of $25\~50$ GPU and $CO_2/N_2$ selectivity of $30\~40$ at room temperature and have the apparent skin layer thickness of about $0.1\;{\mu}m$. The developed PES hollow fiber membranes, would be a good candidate suitable for the flue gas separation process.

• Journal of the Korean Ceramic Society
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• v.39 no.6
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• pp.582-588
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• 2002

IrO$_2$-RuO$_2$ films were deposited on plasma sprayed TiO$_2$ buffer layer above Ti metal by sol-gel and dip-coating method. Organic vehicle (ethyl cellulose and $\alpha$-terpineol) and glass frit were added to improve adherence of the coatings. Taguchi method and L$_{18}$ (2$^1$$\times$3$^{7}$ ) orthogonal arrays were evalvated in terms of current density to determine the optimal combination of levels of factors that best satisfy the bigger is better quality characteristic. The observed conditions were as fellows: ethyl cellulose (100 cp), drying temperature and time (17$0^{\circ}C$,20 min), heat treatment temperature and time (75$0^{\circ}C$,10 min), the weight ratio of IrO$_2$-RuO/powders to glass frit (99:5), final heat treatment time (120 min) and flow rate of air (5 sccm), respectively. ANOVA analysis suggested that the influence of the factors within $\alpha$= 0.1 was significant with a 90% confidence level.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.37 no.2
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• pp.5-12
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• 2000

Uncooled metallic thin-film thermopile infrared detectors have been fabricated, and the figures of merit for the detectors were examined. The hot junctions of a thermopile were prepared on a $Si_{3}N_{4}/SiO_{2}/Si_{3}N_{4}$-membrane which acts as a thermal isolation layer, the cold junctions on the membrane supported with the silicon rim which functions as a heat sink, and Au-black was used as an infrared absorber. Infrared absorbance of Au-black, which strongly depends on the chamber pressure during Au-evaporation and its mass per area, was found to be about 90 ％ in the wavelength range from 3${\mu}{\textrm}{m}$ to 14${\mu}{\textrm}{m}$. Voltage responsivity, noise equivalent power, and specific detectivity of Bi-Sb thermopile infrared detector at 5 Hz-chopping frequency were about 10.5V/W, 2.3 nW/Hz$^{1/2}$, 및 $1.9\times10^{7}$ cm.Hz$^{1/2}$/w at room temperature in air, respectively.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.3 no.3
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• pp.1-7
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• 1983

In spite of extensive knowledge of the surface chemistry and the transport mechanism in filtration systems, there is still insufficient understanding of the physical characteristics of suspensions and the system components. Because of this, no filtration mechanisms are mathematically generalized to the full extent. The purpose of this paper is to propose experimental equations for the filtration process. using the tracer study in filter layer. Some of results are as follows. (1) The Volume of the specific deposit (${\sigma}$) in filtration was directly measurable using the tracer study without interrupting the filtration. (2) It was also confirmed that the head loss in filtration was greatly in fluenced by the micro-air babbles. (3) The correction coefficient(f) was introduced into the Kozeny-Carman equation in order to apply it for the clogging filter media. The coefficient(f) was experimentally obtained. The total head loss of the filter media is given by next equation. $${\frac{h}{h_0}}={\frac{1}{L}}{\int}^{z=L}_{z=0}f({\sigma})g({\varepsilon}_0,{\sigma})dz$$ $$f=aexp(-b{\sigma})$$ The above equation was applicable without regard to the variation of the suspension concentration, the filter medium diameter, the filter depth, the filtration velocity, and the amount of aluminum in all continuous filtration experiments. (4) The total head loss was graphically generalized assuming mathematical filtration models I II (see fig. 7,8) (5) The total head loss was obtained from the filtration model in the field filtration conditions. (see fig. 9,10)

• KSCE Journal of Civil and Environmental Engineering Research
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• v.3 no.3
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• pp.107-116
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• 1983

This paper is concerned with the permeability through a decomposed granite soil layer which is influnced by change of grain sizes and crushed soils made by varied compaction energy. The change in the content of crushed soils can be described in terms of the ratio of surface area ($S_w{^{\prime}}/S_w $). The experiments were carried out to obtain the relationships of the coefficient of permeability(K) versus the optimum moisture content($w_{opt}$) by the variable head permeability test with the samples that were preapared by compaction test. The results are found as follows; (1) By the change in compaction energy, the crush ratio increased whereas the void ratio decreased with a larger maximum dry density running in parallel with the zero air void curve. (2) The ratio of surface area was $0.33(P)^{0.96}$ in $S_w{^{\prime}}/S_w $ with no relation to the compaction energy. (3) The grain size which produced the largest crush of soil particles ranged from 0.5 to 1 millimetre (4) The relationship of K versus $e^3$/1+e appeared as a straight line on the full-log-scale paper under the optimum moisture state. (5) As the compaction energy was larger, the passing percentage of #200-sieve grains increased linearly. The increment in the surface area ratio was deemed to have been caused by the decreased in the permeability.

• Composites Research
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• v.32 no.6
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• pp.301-306
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• 2019

Triboelectric nanogenerator (TENG) is one of the energy harvesting methods in spotlight that can convert mechanical energy into electricity. As TENGs produce high electrical output, previous studies have shown TENGs that can power small electronics independently. However, recent studies have reported limitations of TENG due to air breakdown and field emission. In this study, we developed a triboelectric nanogenerator that utilizes the metal-to-metal surface contact to induce ion-enhanced field emission and electron avalanche for electrons to flow directly between two electrodes. The average peak open-circuit voltage of this TENG was measured as 340 V, and average peak closed-circuit current was measured as 10 mA. The electrical output of this TENG has shown different value depending on the surface charge of surface charge generation layer. The TENG developed in this study have produced RMS power of 0.9 mW, which is 2.4 times higher compared to conventional TENGs. The TENG developed in this study can be utilized in charging batteries and capacitors to power portable electronics and sensors independently.

• Journal of environmental and Sanitary engineering
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• v.7 no.2
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• pp.1-10
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• 1992

Since 1960's along with industrialization and urbanization, economic growth has been . achieved, however, at the same time, environmental condition has been seriously deteriorated. . Currently, volume of wastewater has been increasing at annual rate of 7% in sewage and 20% in industrial wastewater. However, the nation's sewage treatment serves only 33% of the municipal wastewater as of 1991. Major portion of air pollutants comes from combustion of oil and coal which comprise 81% of total energy use and emission gases from motor vehicles increasing at an accelerated rate. It is known that Korea generates the highest amount of waste per capta. Nevertheless, it is not sufficient to reduce the volume of waste by means of resources recovery and recycling. Recognizing the importance of global environmental problems such as ozone layer depletion, global warming and acid rain, international society has been making various efforts since the 1972 Stockholm conference. In particular, it is expected that the Rio conference which has adopted the Rio declaration and Agenda 21 will form a crucial turning point of the emerging new world order after the Cold War confrontation. To cope with such issues as domestic pollution and global environmental problems, the fundamental national policy aims at harmonizing "environmental protection and sustainable development". The Ministry of Environment has recently set up a mid-term comprehensive plan which includes annual targets for environmental protection. According to the government plan, gradual improvement of various environmental conditions and specific measures to achieve them is planned in time frame. Additional sewage treatment plants will be constructed in urban areas with the target to treat 65% of the nation's municipal sewage by 1996. Supply of clean fuels such as LNG will also be expanded starting from large cities as a cleaner substitute energy for coal and oil. In parallel with expansion of LNG, emphasis will be placed on installation of stack monitoring system. Due to the relatively limited land, government's basic policy for solid waste treatment is to develop large scale landfill facilities rather than small sized ones. Thirty three regional areas have been designated for the purpose of waste management. For each of these regions, big scale landfill site is going to be developed. To increase the rate of waste recycling the government is planning to reinforce separate collection system and to provide industries with economic incentives. As a part of meeting the changing situation on global environmental problems after UNCED, and accommodation regulatory measures stipulated in the global environmental conventions and protocols, national policy will try to alter industrial and economic structure so as to mitigate the increasing trends of energy consumption, by encouraging energy conservation and efficiency. In this regard, more attention will be given to the policy on the development of the cleaner technology. Ultimately, these policies and programs will contribute greatly to improving the current state of national public health.

• Journal of Korea Soil Environment Society
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• v.2 no.2
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• pp.25-33
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• 1997

To investigate the effects of cow manure compost(CMC) on soil and water environment as non-point source, the elution patterns of anions were determined in muti-layered soil columns which were consisted of one top and one bottom in combination. The top soil columns were uniformly packed with Ap horizon soils amended with air-dried CMC at different ratios(0, 2, 4, 6%, wt/wt), the bottom ones were packed with of B horizon soils of 15, 30, and 45cm in length. After saturating the each soil column, the leachate were collected from the bottom of the column while the double-ionized water was applied from the surface of the column by constant head method. From the hydraulic conductivity and anion eluted were measured in the leachate. Each saturated hydraulic conductivities for top and the bottom soils were 3$\times$$10^{-4}$sec and 1.6$\times$$10^{-3}$cm/sec. Most of water soluble chloride and sulfate, having non-specific adsorption characteristics onto the soil particles, were eluted within 1 PV, showing that there was no apparent retardation of anion movement with increasing CMC contents in the top soils. The effect of soil depths on anion movement were similar to the results of CMC contents. Sulfate of having both of non-specific and specific adsorption characteristics was also recovered in the effluent within 1 PV, while the elution curves were slightly skewed to the right showing that the CMC affected the movement of sulfate. Phosphate of specific adsorption characteristics was hardly eluted within 5 PV.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.17 no.2
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• pp.143-150
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• 1984

A field survey and experiment on aquaculture in Costa Rica including Nicoya Gulf was carried out for a month, December $2{\sim}28$, 1981. 1) Air temperature was $27{\sim}32^{\circ}C$, water temperature, $28{\sim}29.5^{\circ}C$ and salinity, $20{\sim}28.5\%$ both in the surface and 5 m layer on December 22, 1981. 2) Dissolved oxygen plentiful, $7.3{\sim}9.95\;ml/l$. 3) Mean precipitation for the past ten years in Nicoya Gulf area was $1298.6{\sim}2196.3$ mm near Puntarenas area and rainy days a year was 137.7, Most rainfalls was concentrated from May to November, the rainy season. 4) Precipitation in main oyster farms near Chungmu, Korea was 1836.0mm a year and it was similar to that of Costa Rica. 5) Diatoms were 16 species belonged to 13 genera and dinoflagellates, 3 species belonged to 2 genera. Standing crops was $639{\sim}130,211\;cells/l$ and dominant species were Chaeteocros curvisetus, Chaetoceros decipiens, Nitzschia serata. Thalassiothrix mediterranca, a tropical esturary species, was found. 6) Nicoya Gulf has the good environmental factors in the water temperature, salinity, dissolved oxygen and planktons, and it is desirable to experiment and culture the oyster (Crassostrea rhrizophorae).

• Journal of Conservation Science
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• v.29 no.2
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• pp.187-196
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• 2013

This study is on the corrosion of iron objects caused by sulfides in undersea environment. The corrosion state of objects in seawater and their damage state after underwater and left in highly humid air were studied. The samples of this study were four iron objects which had been taken out from undersea mud layer located in Taean Mado, Chungcheongnamdo. SEM-EDS and XRD analyse on the objects to check whether they have sulfides or not. The result of analysis suggested that the major component of corrosion product generated in undersea deposit soil is sulfur(S) and iron sulfide(FeS) is formed as sulfide. However, there was no clear corrosion on the surface of objects which was exposed to sea water because of the impact of concretion which covered the surface. In order to check the damage status of iron objects after they had been taken out of sea water, exposure tests in high humidity environment and dehumidified environment were done on the corrosion products. The result of the test suggested that the oxidization of iron sulfide corrosion product makes iron sulfate ($FeSO_4$) and sulfuric acid ($H_2SO_4$) and they can cause secondary corrosion of iron objects. Therefore, it is believed that the iron sulfide corrosion product of iron objects taken out from underwater environment should be removed by all means and the keeping environment of the iron objects should also maintain dehumidified state.