• Title/Summary/Keyword: Air Layer

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PVDF/h-BN hybrid membranes and their application in desalination through AGMD

  • Moradi, Rasoul;Shariaty-Niassar, Mojtaba;Pourkhalili, Nazila;Mehrizadeh, Masoud;Niknafs, Hassan
    • Membrane and Water Treatment
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    • v.9 no.4
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    • pp.221-231
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    • 2018
  • A new procedure to produce poly(vinylidene fluoride)/boron nitride hybrid membrane is presented for application in membrane distillation (MD) process. The influence of hexagonal boron nitride (h-BN) incorporation on the performance of the polymeric membranes is studied through the present investigation. For this aim, h-BN nanopowders were successfully synthesized using the simple chemical vapor deposition (CVD) route and subsequent solvent treatments. The resulting h-BN nanosheets were blended with poly(vinylidene fluoride) (PVDF) solution. Then, the prepared composite solution was subjected to phase inversion process to obtain PVDF/h-BN hybrid membranes. Various examinations such as scanning electron microscopy (SEM), wettability, permeation flux, mechanical strength and liquid entry pressure (LEP) measurements are performed to evaluate the prepared membrane. Moreover, Air gap membrane distillation (AGMD) experiments were carried out to investigate the salt rejection performance and the durability of membranes. The results show that our hybrid PVDF/h-BN membrane presents higher water permeation flux (${\sim}18kg/m^2h$) compared to pristine PVDF membrane. In addition, the experimental data confirms that the prepared nanocomposite membrane is hydrophobic (water contact angle: ${\sim}103^{\circ}$), has a porous skin layer (>85%), as well competitive fouling resistance and operational durability. Furthermore, the total salt rejection efficiency was obtained for PVDF/h-BN membrane. The results prove that the novel PVDF/h-BN membrane can be easily synthesized and applied in MD process for salt rejection purposes.

Studies on the Evaporative Heat Transfer Characteristics and Pressure Drop of CO2 Flowing Upward in Inclined (45°) Smooth and Micro-fin Tubes (경사평활관 및 마이크로핀관에서의 이산화탄소의 증발열전달 특성과 압력강하에 관한 실험적 연구)

  • Kim, Yong-Jin;Cho, Jin-Min;Kim, Min-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.8
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    • pp.612-620
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    • 2008
  • New alternative refrigerants have been developed due to the ozone layer depletion and global warming. For this reason, carbon dioxide is believed to be a promising refrigerant for use in air conditioners and heat pumps. Evaporative heat transfer characteristics and pressure drop of $CO_2$ with outer diameter of 5 mm in inclined ($45^{\circ}$) smooth and micro-fin tubes have been investigated by the experiments with respect to several test conditions such as mass fluxes, heat fluxes, evaporation temperatures in this study. The inclined ($45^{\circ}$) smooth and micro-fin tubes with length of 1.44 m were installed to measure the evaporative heat transfer coefficients of $CO_2$ and heat was supplied to the refrigerant by direct heating method where the test tube was uniformly heated by electricity. The tests were conducted at mass fluxes from 212 to $656\;kg/m^2s$, heat fluxes from 15 to $60\;kW/m^2$ and evaporation temperatures from -10 to $20^{\circ}C$. The heat transfer coefficients of $CO_2$ are slightly increased with increasing mass flux, and the heat transfer characteristics in the inclined ($45^{\circ}$) tubes are enhanced about $5{\sim}10%$ compared with those in horizontal or vertical tubes.

An experimental study on the performance improvement of dead-end type PEMFC with pulsating effect (맥동 효과를 이용한 dead-end type 연료전지의 성능향상에 대한 실험적 연구)

  • Choi, Jong-Won;Seo, Jeong-Hoon;Hwang, Yong-Sheen;Lee, Dae-Heung;Cha, Suk-Won;Kim, Min-Soo
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.567-571
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    • 2008
  • PEM Fuel Cell operation mode can be classified into dead-end mode or open mode by whether the outlet port is blocked or not. Generally, dead-end type fuel cell has some merits on the pressure drop and system efficiency because it can generate more power than the open type fuel cell due to high operating pressure condition. However, the periodic purging process should be done for removing water which is formed as product of a reaction in the gas diffusion layer. In this study, cathode side dead-end type operation has been conducted. Moreover, pulsating flow generator at the outlet of cathode side has been suggested for increasing the period to purge the formed water because the pulsating flow can make formed water scattered uniformly over the whole channel. As a result, the purging period with pulsation increased by 1.5-2 times longer than that without pulsating.

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Numerical Simulation of Wave Breaking Near Ship Bow

  • Lee, Young-Gill;Kim, Nam-Chul;Yu, Jin-Won;Choi, Si-Young
    • Journal of Ship and Ocean Technology
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    • v.12 no.1
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    • pp.16-27
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    • 2008
  • The interaction between advancing ships and the waves generated by them plays important roles in wave resistances and ship motions. Wave breaking phenomena near the ship bow at different speeds are investigated both numerically and experimentally. Numerical simulations of free surface profiles near the fore bodies of ships are performed and visualized to grasp the general trend or the mechanism of wave breaking phenomena from moderate waves rather than concentrating on local chaotic irregularities as ship speeds increase. Navier-Stokes equations are differentiated based on the finite difference method. The Marker and Cell (MAC) Method and Marker-Density Method are employed, and they are compared for the description of free surface conditions associated with the governing equations. Extra effort has been directed toward the realization of extremely complex free surface conditions at wave breaking. For this purpose, the air-water interface is treated with marker density, which is used for two layer flows of fluids with different properties. Adaptation schemes and refinement of the numerical grid system are also used at local complex flows to improve the accuracy of the solutions. In addition to numerical simulations, various model tests are performed in a ship model towing tank. The results are compared with numerical calculations for verification and for realizing better, more efficient research performance. It is expected that the present research results regarding wave breaking and the geometry of the fore body of ship will facilitate better hull form design productivity at the preliminary ship design stage, especially in the case of small and fast ship design. Also, the obtained knowledge on the impact due to the interaction of breaking waves and an advancing hull surface is expected to be applicable to investigation of the ship bow slamming problem as a specific application.

THE STUDY OF PATIENT EXPOSURE AND PROTECTION FROM DENTAL RADIOGRAPHY (치과 X선 촬영에 있어서 환자에 대한 피폭과 방어에 관한 연구)

  • Park T. W.
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.9 no.1
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    • pp.25-31
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    • 1979
  • The utilization of x-ray for diagnosis and examination is increasing by about 5-15% every year, therefore, it would be mandatory to protect the patients from exposures and so, studies in this field are performed even now. In dental field, the area of irradiation is limited any to the head and neck area, but the irradiated angle is varied following the objected tooth, so the adjacent structures lens and thyroid gland would be fragile to radiation. And the scattered radiation is one of the complicated problems in the protection because of specificity of dental x-ray and its object structures. The author, by using TLD (Thermo luminescent Dosimeter; Teledyne Isotopes-Model 7300, Element; TLD 200(CaF₂:Dy) and Capintec(Capintec Model 192, PM-30 Diagnostic chamber 28㎖ active volume), tried a measurement of air dose distribution of the scattered radiation and the irradiated dose of lens and thyroid gland under the condition of taking the film on the left maxillary molar. The results were as follows: 1. The half value layer of adapted dental x-ray machine was measured, and is 1.44㎜ Al. 2. The time of irradiation on the left maxillary molar in the Alderson Rando Phantom, the measured doses of left and right lens, and thyroid gland were 8,9mR, 1,2mR and 2,8mR. Under the same conditions, the scattered radiation at the distance of 1 meter from the phantom were 84 μR at the front side, 11μR at the back side, 18μR at the right side and 72μR at the left side. 3. Under the same conditions, the dose showed higher value by about 5% in the presence of object(phantom) than in the case of absence.

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Analysis of A New Crossbar Embedded Structure for Improved Attenuation Characteristics on the Various Lossy Media (다양한 손실매질내의 손실특성 개선을 위한 새로운 크로스바 구조의 해석)

  • Kim, Yoon-Suk
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.12 s.354
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    • pp.83-88
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    • 2006
  • In this paper, we propose a new cross bar embedded structure for improvement of attenuation characteristics along the different lossy media. A general characterization procedure based on the extraction of the characteristic impedance and propagation constant for analyzing a single MIS(Metal-Insulator-Semiconductor) transmission line used and an analysis for a new substrate shielding MIS structure consisting of grounded crossbars at the interface between Si and Sio2 layer using the Finite-Difference Time-Domain(FDTD) technique is used. In order to reduce the substrate effects on the transmission line characteristics, a shielding structure consisting of grounded cross bar lines over time-domain signal has been examined. The extracted, distributed frequency-dependent transmission line parameters as well as the line voltages and currents, and also corresponding equivalent circuit parameters have been examined as function of frequency. It is shown that the quality factor of the transmission line can be improved without significant changes in the characteristic impedance and effective dielectric constant.

Nitrogen Monoxide Gas Sensing Properties of CuO Nanorods Synthesized by a Hydrothermal Method (수열합성법으로 합성된 산화구리 나노막대의 일산화질소 가스 감지 특성)

  • Park, Soo-Jeong;Kim, Hyojin;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.24 no.1
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    • pp.19-24
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    • 2014
  • We report the nitrogen monoxide (NO) gas sensing properties of p-type CuO-nanorod-based gas sensors. We synthesized the p-type CuO nanorods with breadth of about 30 nm and length of about 330 nm by a hydrothermal method using an as-deposited CuO seed layer prepared on a $Si/SiO_2$ substrate by the sputtering method. We fabricated polycrystalline CuO nanorod arrays at $80^{\circ}C$ under the hydrothermal condition of 1:1 morality ratio between copper nitrate trihydrate [$Cu(NO_2)_2{\cdot}3H_2O$] and hexamethylenetetramine ($C_6H_{12}N_4$). Structural characterizations revealed that we prepared the pure CuO nanorod array of a monoclinic crystalline structure without any obvious formation of secondary phase. It was found from the gas sensing measurements that the p-type CuO nanorod gas sensors exhibited a maximum sensitivity to NO gas in dry air at an operating temperature as low as $200^{\circ}C$. We also found that these CuO nanorod gas sensors showed reversible and reliable electrical response to NO gas at a range of operating temperatures. These results would indicate some potential applications of the p-type semiconductor CuO nanorods as promising sensing materials for gas sensors, including various types of p-n junction gas sensors.

Thermal Conductivity of Thermally Conductive Ceramic Composites and Silicon Carbide/Epoxy Composites through Wetting Process (세라믹 방열 복합체의 열전도도 분석 및 Wetting Process를 이용한 SiC/에폭시 복합체)

  • Hwang, Yongseon;Kim, Jooheon;Cho, WonChul
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.782-786
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    • 2014
  • Various kinds of thermal conductive ceramic/polymer composites (aluminum nitride, aluminum oxide, boron nitride, and silicon carbide/epoxy) were prepared by a casting method and their optical images were observed by FE-SEM. Among these, SiC/epoxy composite shows inhomogeneous dispersion features of SiC and air voids in the epoxy matrix layer, resulting in undesirable thermal conductive properties. To enhance the thermal conductivities of SiC/epoxy composites, the epoxy wetting method which can directly infiltrate the epoxy droplet onto filtrated SiC cake was employed to fabricate the homogeneously dispersed SiC/epoxy composite for ideal thermal conductive behavior, with maximum thermal conductivity of 3.85W/mK at 70 wt% of SiC filler contents.

Preparation of Aminosiloxane-grafted Poly(imidesiloxane) Copolymer and its Morphology and Adhesive Properties in Film (아미노실록산이 그래프팅된 폴리(이미드실록산) 공중합체 제조와 필름 모폴로지 및 점착 특성 연구)

  • Lee, Ji Mok;Kwon, Eunjin;Lee, Sunyoung;Jung, Hyun Min
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.547-552
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    • 2013
  • Polyimide (PI) containing carboxyl functional group was prepared and reacted with diaminosiloxane during high temperature film casting. The morphology of resulting film was observed by using transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX), which revealed that globular 100 nm-sized PI domains and continuous polysiloxane phase were formed. X-ray photoelectron spectroscopy (XPS) study indicated that air-film interface mainly consisted of polysiloxane blocks. Poly(imidesiloxane) thin layer was thermostable until $400^{\circ}C$ and its pressure- sensitive adhesive property was retained up to $300^{\circ}C$. The comparative experiments revealed that grafting between carboxyl groups of polyimide and aminosiloxane was crucial for formation of microdomain structure and pressure-sensitive adhesive property.

A Scheme for Computing Primary Fields in Modeling of Marine Controlled-Source Electromagnetic Surveys (해양전자탐사 모델링을 위한 1차장 계산법)

  • Kim, Hee-Joon
    • Geophysics and Geophysical Exploration
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    • v.14 no.3
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    • pp.185-190
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    • 2011
  • In marine controlled-source electromagnetic (CSEM) modeling, it may be difficult to evaluate primary fields accurately using conventional linear filters because they decay very rapidly with distance. However, since there exists a closed-form solution to the Hankel transform in TM mode for a homogeneous half space, we can assess the accuracy of linear filters for evaluating the Hankel transform. As a result, only nine out of 36 source-receiver pairs show that EM fields decrease linearly in semi-log scale with an increase of source-receiver distance, while EM fields are either 0 or not reduced significantly due to an effect of the air layer. There also exist closed-form solutions for the nine pairs, and the others can be evaluated accurately with a relatively short filter. This paper proposes a method which uses closed-form solutions for TM-mode Hankel transforms and a filter with 61 coefficients for TE-mode ones.