• Journal of the Korean Chemical Society
• /
• v.22 no.4
• /
• pp.254-258
• /
• 1978

A simple and sensitive method of determining trace amounts of benzene hexachloride (BHC) in air has been investigated. The sample is passed through the n-hexane solution and the absorbance of it was measured at 245nm spectrophotometrically and the concentration of benzene hexachloride was calculated using a working curve obtained from the vaporized standard benzene hexachloride passed into n-hexane.

• Elastomers and Composites
• /
• v.47 no.2
• /
• pp.156-161
• /
• 2012

Difference in recovery behaviors from the circular deformation of natural rubber (NR) composites aged in air and distilled water, respectively were investigated. Recoveries of the samples aged in air were larger than those of the samples aged in distilled water. Recovery rates of the samples reinforced with filler were faster than those of the unreinforced ones. Recovery rates of the carbon black-filled samples were faster than those of the silica-filled ones. Difference in the recovery behaviors according to the aging media can be explained by the crosslinking density changes and the annealing effect.

• Applied Biological Chemistry
• /
• v.32 no.3
• /
• pp.265-269
• /
• 1989

Effects of air-tighteness of packing material and aluminum phosphide fumigation on mortality of rice weevil were studied during rice storage. Air-tight storage of rice in sealed bag of 0.1mm PE film or sealed glass bottle reduced the deterioration of rice quality and killed all rice weevils after 60 days storage, while paper bag, PP bag and straw bag storage kept them alive. One tablet of aluminum phosphide in one cubic meter heap of rice packed in PP bag was sufficient to kill all rice weevil in it, when the heap was covered by 0.15 mm PE film during fumigation.

• Journal of Photoscience
• /
• v.9 no.3
• /
• pp.57-63
• /
• 2002

A homopolymer containing anthracene groups, poly[6-(9-anthryloxy)hexyl methacrylate] (PAn) was prepared and the effect of oxygen on its photochemical reaction was studied by UV and IR absorption spectroscopy in order to understand its photochemical behavior. Photochemical reaction of the PAn in THF solution under an atmosphere of air resulted in the formation of endoperoxide at the beginning stage of reaction followed by photodimerization reaction after all the oxygen was consumed, whereas photodimerization and endoperoxide formation took place concomitantly in the film state. The photoreversible reaction of the anthracene photodimer groups in the polymer by photolysis with 254 nm UV light was not efficient. The IR absorption spectral changes of the PAn film upon irradiation indicate that various photooxidation products were produced in the atmosphere of air.

• Bulletin of the Korean Chemical Society
• /
• v.11 no.2
• /
• pp.118-123
• /
• 1990

X-ray photoelectron spectra have been obtained and comparisons have been made for 1-2-3 and 2-1-1 phases of YBaCuO compounds. The photoelectron binding energies of all the constituent elements are consistently larger for the 2-1-1 phase than for the 1-2-3 phase. The peak intensities reflect different stoichiometries of the two phases. For the superconducting 1-2-3 phase, its degradation in air and interaction with water and carbon dioxide were examined by taking core level spectra of all the elements. It appears that yttrium is the most affected by exposure to air, since it undergoes a rapid change to carbonate when water and subsequently carbon dioxide are introduced.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.31 no.2
• /
• pp.69-72
• /
• 2021

The reaction of ammonium ferric sulfate with sodium borohydride in laponite sol yields nanoiron colloidal solution. This solution in air forms transparent yellow brown solution. The resulting solution reacts with bidentate chelating ligands. The reaction products are characterized by UV-Vis absorption spectroscopy and X-ray diffraction. All compounds show metal to ligand charge transfer band in the region of 400~650 nm in UV-Vis absorption spectra. This indicates the formation of iron-ligand complex by air oxidation of nanoiron. Also, XRD patterns exhibit that the iron-ligand complex is intercalated in the interlayer of laponite.

• Bulletin of the Korean Chemical Society
• /
• v.12 no.2
• /
• pp.170-177
• /
• 1991

A lattice mean field theory is developed to investigate the conformational properties of monolayer amphiphiles at the air-water interface. By generalizing Dill and Cantor's method and by extending Whittington's recurrence equation, we derive the supermatrix recurrence equation which is applied to calculation of various segment density profiles and order parameter, etc. In deriving the equation, we incorporated the chain stiffness effect and the chain connectivity which are distinguished features of linear chain molecule. Our result shows that, as the surface coverage $\sigma$ increases the chain ordering process with respect to vertical axis of the lattice system becomes dominant.

• Prospectives of Industrial Chemistry
• /
• v.23 no.3
• /
• pp.32-41
• /
• 2020

사람들은 대부분의 시간을 실내에서 보내고 있으며, 실내에 존재하는 유해가스는 미량의 농도에도 불구하고 심각한 질환을 일으킬 수 있다. 금속산화물 반도체 가스센서는 감도가 우수하고, 구조가 간단하며, 초소형화가 가능한 장점이 있어 고가의 대형 장비를 사용하지 않고 실내 유해가스를 측정하는 데 효과적으로 이용될 수 있다. 본 기고문에서는 금속산화물 반도체를 이용한 가스 센서의 검지 원리를 고찰하고, 나노 구조 조절, 마이크로 리액터 및 이중층 구조를 이용한 가스 개질 등 실내 유해가스 측정을 위한 다양한 센서 설계방법을 소개하고자 한다.

• Prospectives of Industrial Chemistry
• /
• v.23 no.4
• /
• pp.20-29
• /
• 2020

최근 미세먼지가 사회적 이슈가 됨에 따라 지하철 시스템의 공기 질에도 많은 관심이 쏠리고 있다. 지하철 미세먼지는 지상과 달리 폐쇄적인 환경이라는 특징이 있는데, 이로 인해 발생 및 유입된 미세먼지는 지하철 시스템에 축적된다. 지하철 미세먼지의 대부분을 차지하는 미세마모입자들은 철 성분을 주축으로 다양한 중금속 성분을 포함하므로 인체에 해롭다. 본 기고문에서는 이러한 지하철 미세먼지 및 미세마모입자에 대한 기본 지식과 미세마모입자의 주된 발생원인 휠-레일 접촉 미세먼지발생 연구에 대해 소개하고자 한다. 연구 결과들은 지하철 공기 질 향상을 위해 미세마모입자 발생 저감에 기여할 것으로 기대된다.

• Prospectives of Industrial Chemistry
• /
• v.23 no.4
• /
• pp.30-36
• /
• 2020

실내공기질에 대한 중요성은 국민 생활수준 및 환경 현안에 대한 인식의 향상과 더불어 더욱 중요한 이슈가 되고 있다. 실내공기질은 시설의 유형, 실내 활동의 종류 등에 따라 차이가 크고, 상시 모니터링을 포함한 정부 및 각 지자체 차원의 관리 역시 어려운 실정으로 인해 종합적인 현황분석 및 관리방안 수립에 있어 많은 제약사항이 있는 것이 현실이다. 본 고에서는 그 간 국내 실내공기질의 관리와 개선을 위해 시행되어온 제도를 살펴보고 제시되어 왔던 문제점들을 다루고자 한다. 또한 미국, 일본 등 국외에서 시행 중인 실내공기질 관리 관련 제도 역시 함께 분석하여, 국내와의 차이점 및 개선안을 고찰하고자 하였다.