• Title/Summary/Keyword: Agitation

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Solvent Extraction of Organotin from Ship Wash Wastewater (선박 세척폐수에 함유된 유기주석화합물의 용매추출특성)

  • Song, Young-Chae;Woo, Jung-Hui;Kim, In-Soo;Park, Sang-Ho;Kim, Dong-Geun
    • Journal of Navigation and Port Research
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    • v.28 no.5
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    • pp.463-468
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    • 2004
  • A lab-scale fundamental study to develop the solvent extraction process of ship wash wastewater containing TBT was carried out. For various solvents, including diesels for car and ship, bunker B, thinner, toluene, and ether, the extraction efficiencies of TBT from synthetic ship wash wastewater were compared The effect of extraction conditions, such as solvent amount, time and intensity of agitation, and pH, on the extraction efficiency of TBT was evaluated Diesel for ship showed better extraction efficiency of TBT than those of other tested solvents, and the proper amount of the extraction solvent for 1L of the wastewater was l0mL. When the agitation intensity was increased from 50rpm to 250rpm, the TBT remained in the wastewater after the extraction was decreased from around 120ppb to 2.8ppb. The remaining TBT in the wastewater was sharply decreased from 1hr of the extraction time, but was slightly increased again after 5hrs of the extraction time. The efficiency of TBT extraction was good in the weak acid range of pH, but was not significant as much as the others.

Optimization of Bioreactor Operation by Mass Transfer Coefficient (물질전달계수를 이용한 생물 반응기 운전 최적화)

  • Kim, Hyung-Soon
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.3
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    • pp.243-251
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    • 2001
  • The effects of various operating parameters(agitation speed, impeller type, antiform agents, impeller spacing etc.) on air-liquid mass transfer was characterized by volumetric mass transfer coefficient($k_La$). Also, the dual-impeller agitated systems are compared with single-impeller agitated systems with a special focus on its applications for bioreactors, $k_La$ was take over a range of 200~450 rpm of agitation speed, and 0.5~2.5 vvm of air flow rates, for four single impeller and impeller combinations consisting of four impeller types, namely rushton, pitched blade, scaba, intermig were tested. The rushton impeller showed the best $k_La$ as compared with other single impellers. The dual impeller system are found to be superior as compared to single impeller in all aspects, The best combination of the dual impeller was a intermig of axial flow type as an upper impeller and a rushton of radial flow type as a lower part. Also, the control of the DO level with the variation of agitation speed was more efficient than that with an increase in air flow rate. The addition of antiform dropped the $k_La$ very large up to 1g/L regardless the type. PPG was less effect on $k_La$ than other antiforms. The impeller spacing and presence of solute are found very effective on $k_La$. When the $NaNO_3$is presented as solute, the $k_La$ increased approximately 50% then control.

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Optimization for the Fermentation Condition of Persimmon Vinegar using Response Surface Methodology (반응표면분석에 의한 감식초 제조조건의 최적화)

  • Jeong, Yong-Jin;Lee, Gee-Dong;Kim, Kwang-Soo
    • Korean Journal of Food Science and Technology
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    • v.30 no.5
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    • pp.1203-1208
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    • 1998
  • To utilize astringent persimmon (Diospyros kaki, T.) effectively, response surface methodology (RSM) was applied to optimize and monitor the vinegar fermentation conditions by two stage fermentation. In the first stage, the fermentation conditions for maximum alcohol content was $20.51\;^{\circ}brix$ in sugar concentration of astringent persimmon, 139.52 rpm in agitation rate, and 94.88 hr in fermentation time. When sugar concentration of astringent persimmon was $14\;^{\circ}brix$, maximum alcohol content predicted by response surface methodology was 7.1% at agitation rate of 40 rpm and fermentation time of 120 hr. In the second stage, the fermentation conditions for maximum acidity was 224.40 rpm in agitation rate, 176.07 hr in fermentation time. Alcohol content and acidity predicted at the optimum conditions were similar to experimental values.

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Synthesis of Succinic Acid from Hydrogenation of Maleic Anhydride (무수말레인산의 수소화 반응에 의한 호박산 합성)

  • Kim, Ji Sun;Baek, Jae Ho;Kim, Myung Hwan;Hong, Seong-Soo;Lee, Man Sig
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.650-655
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    • 2013
  • In this study, the synthesis of succinic acid from hydrogenation of maleic anhydride over Pd/C were performed in aqueous solution at various reaction conditions. We confirmed that the distribution of product was different according to process parameters. When increasing the reaction pressure and agitation speed, the by-product decreased and the purity of succinic acid increased. From the result, we may conclude that the reaction pressure and agitation speed are important factors for promoting the mass transfer rate of gas-liquid interface by increasing gas-liquid solubility in liquid hydrogenation. When the reaction pressure increased from 5 bar to 10 bar, the reaction rate increased 2.14 times. When the agitation speed increased from 300 rpm to 700 rpm, the reaction rate increased 2.75 times.

Effect of ultrasonic agitation on push-out bond strength and adaptation of root-end filling materials

  • Alcalde, Murilo Priori;Vivan, Rodrigo Ricci;Marciano, Marina Angelica;Duque, Jussaro Alves;Fernandes, Samuel Lucas;Rosseto, Mariana Bailo;Duarte, Marco Antonio Hungaro
    • Restorative Dentistry and Endodontics
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    • v.43 no.2
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    • pp.23.1-23.9
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    • 2018
  • Objectives: This study evaluated the effect of ultrasonic agitation of mineral trioxide aggregate (MTA), calcium silicate-based cement (CSC), and Sealer 26 (S26) on adaptation at the cement/dentin interface and push-out bond strength. Materials and Methods: Sixty maxillary canines were divided into 6 groups (n = 10): MTA, S26, and CSC, with or without ultrasonic activation (US). After obturation, the apical portions of the teeth were sectioned, and retrograde cavities were prepared and filled with cement by hand condensation. In the US groups, the cement was activated for 60 seconds: 30 seconds in the mesio-distal direction and 30 seconds in the buccal-lingual direction, using a mini Irrisonic insert coupled with the ultrasound transducer. After the materials set, 1.5-mm thick sections were obtained from the apexes. The presence of gaps and the bond between cement and dentin were analyzed using low-vacuum scanning electron microscopy. Push-out bond strength was measured using a universal testing machine. Results: Ultrasonic agitation increased the interfacial adaptation of the cements. The S26 US group showed a higher adaptation value than MTA (p < 0.05). US improved the push-out bond strength for all the cements (p < 0.05). Conclusions: The US of retrograde filling cements enhanced the bond to the dentin wall of the root-end filling materials tested.

The Recovery of Silver from Thiourea Leaching Solution by Cementation Technique (침전법을 이용한 Thiourea 용출용액으로부터 Silver 회수)

  • Kim, Bong-Ju;Cho, Kang-Hee;Choi, Nag-Choul;Park, Cheon-Young
    • Economic and Environmental Geology
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    • v.46 no.1
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    • pp.29-37
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    • 2013
  • In order to apply the silver cementation method using Fe powder from pregnant thiourea leaching solution. Parameters such as the amount of Fe powder addition, agitation speed, and temperature were investigated. The silver cementation rate was increased by the increasing of Fe powder addition, agitation speed, and temperature. The highest silver cementation rate was found when the addition of Fe powder was 50 g/L at the agitation speed of 500 rpm. The silver cementation rate increase with increasing temperature according to the Arrhenius equation and obeys $1^{st}$ order kinetics. The activation energy from the kinetics data was found to be between 13.73 KJ/mol and 17.02 KJ/mol. In the XRD analysis, goethite was detected in the precipitate of the thiourea leach solution. This indicates that an oxidation-reduction reaction had occurred in the thiourea solution due to the addition of the Fe powder.

Dismantling of Components from Waste Printed Circuit Boards Using Stannic Chloride Solution (염화주석용액을 이용한 폐인쇄회로기판으로부터 부품의 분리)

  • Park, Yujin;Yoo, Kyoungkeun
    • Resources Recycling
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    • v.30 no.2
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    • pp.24-30
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    • 2021
  • Dismantling tests were performed to separate components from waste printed circuit boards (PCBs) using HCl solution with Sn4+. Then, the effects of agitation speed, reaction temperature, initial Sn4+ concentration, and HCl concentration on the dismantling of components were investigated. No significant effect on the dismantling speed was observed upon changing the agitation speed from 100 to 300 rpm. However, the dismantling rate increased with increasing reaction temperature, Sn4+ concentration, and HCl concentration. In the all-component dismantling tests, when the dismantling ratio increased to 100%, no solder was observed on the boards, and the Sn4+ concentration was ~1,500 mg/L. The dismantling ratio of the components from the PCB increased to 100% within 2 h when 1 mol/L HCl solution with 10,000 mg/L Sn4+ was used at an agitation speed and temperature of 200 rpm and 90 ℃, respectively.

Enhanced Production of Gellan by Sphingomonas paucibilis NK-2000 with Shifts in Agitation Speed and Aeration Rate after Glucose Feeding into the Medium (Sphingomonas paucibilis NK-2000 균주가 생산하는 젤란의 생산 농도 향상을 위한 포도당 첨가 및 교반속도와 통기량 변화 방법의 최적화)

  • Lee, Nam-Kyu;Seo, Hyung-Phil;Cho, Young-Bai;Son, Chang-Woo;Gao, Wa;Lee, Jin-Woo
    • Journal of Life Science
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    • v.20 no.6
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    • pp.811-818
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    • 2010
  • Optimal agitation speed and aeration rate for the production of gellan by Sphingomnas paucibilis NK2000 in a 7 l bioreactor were found to be 400 rpm and 1.0 vvm. The best time for glucose feeding into the medium for enhanced production of gellan by S. paucibilis NK2000 was 36 hr after cultivation. The concentrations of gellan produced by S. paucibilis NK2000 from 1) 20.0 g/l glucose without additional feeding, 2) 20.0 g/l glucose with feeding of 200.0 g/l glucose at 36 hr, in which the final concentration in the medium was 10.0 g/l, 3) 20 g/l glucose with feeding of 200.0 g/l glucose and a shift in an agitation speed from 400 to 600 rpm, 4) 20.0 g/l glucose with feeding of 200.0 g/l glucose at 36 hr and shifts in an agitation speed from 400 to 600 rpm and an aeration rate from 1.0 to 1.5 vvm, 5) and 20.0 g/l glucose with feeding of 200.0 g/l glucose at 36 hr and shifts in an agitation speed from 400 to 600 rpm and an aeration rate from 1.0 to 2.0 vvm, were 5.19, 5.74, 6.73, 7.93, and 9.40 g/l, respectively, and their conversion rates from glucose were 26.0, 19.1, 22.4, 26.4, and 31.3%, respectively. Compared to those developed using a normal process, production of gellan by S. paucibilis NK2000 from 20.0 g/l glucose was 1.81 times higher, and and its conversion rate was 1.20 times higher when the optimized process developed in this study was used.

A Study on Aerobic Composting of Food Waste with Controlling Temperature by Air Flow Rate (온도를 공기량으로 제어한 음식물 쓰레기 호기성 퇴비화에 관한 연구)

  • Hwang, Seon-Hyeon;Sin, Chang-Ho;Sin, Bu-Yeong;Jo, Mu-Hwan
    • KSBB Journal
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    • v.14 no.5
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    • pp.621-627
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    • 1999
  • A food waste composting apparatus of 450 L was designed for and tested with changing conditions of inlet air flow rate, agitation and inoculation. Agitation was done twice per day for 5 min and inlet air flow rate was set as 22.7 L/min for RUN 1. For RUN 2 and RUN 3, agitation was continuous, and inlet air flow rate was changed frequently as 10 L/min, 15 L/min and 20 L/min in order to maintain temp. above 5$0^{\circ}C$, and the concentration of $O_2$over 7 mol%. The compost of RUN3 was inoculated with 10 wt% of accomplished compost, and it was compared with RUN 1 and 2 to show the effect of inoculation. The composting rates of RUN 2 and RUN 3 were faster than that of RUN 1, because agitation was continuous and temperature was controlled in RUN 2 and RUN 3. Inoculated RUN 3 was better than RUN 1 and RUN 2 in the concentrations of $CO_2$and reduction of volatile solids. while the effect of inoculation on C/N ratios, pH change and the numbers of microoragnisms was not clearly appeared.

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KINETIC STUDIES OF LACTIC ACID FERMENTATION(PART 1) EFFECT OF MECHANICAL AGITATION ON FERMENTATION (유산균 발효에 관한 동력학적 연구(제1보) 발효에 미치는 기계적 교반의 영향)

  • LEE Keun-Tai;HAN Bong-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.12 no.3
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    • pp.155-160
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    • 1979
  • Mechanical agitation in fermentation process enhances the fermentation activity of microbes by means of oxygen supply and frequent collision with substrate. However, the fermentation activity of microaerophilic bacteria is inhibited by the excess oxygen resulted from the mechanical agitation. On this account, a a strain of Lactobacillus bulgarius was cultured to know the inhibition effect of the mechanical agitation and determine the optimum conditions for tile process of lactic acid fermentation. The growth rate of L. bulgaricus and the consumption rate of tile substrate revealed an identical pattern in changes. The two rates were constant in the range of the modified Reynolds number of $1\times10^5\;to\;5\times10^5$ while they showed linear increase in the range of the modified Reynolds number of $1\times10^5\;to\;10\times10^5$. Under the conditions of the modified Reynolds number more than $10\times10^5$, the both rates decreased. At the modified Reynolds number of $10\times10^5$, the maximum specific growth rate and the saturation constant of L. bulgaricus were 0.58/hr and 6.74g/l, respectively.

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