• 한국입자에어로졸학회지
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• 제13권1호
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• pp.1-10
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• 2017

본 총설에서는 액체층을 통과하는 기포의 크기, 형상, 상승속도를 결정하기 위한 이론들을 살펴보았다. 액체의 물리적 특성과 기포의 유량으로부터 기포의 크기, 형상, 상승속도를 체계적으로 계산하는 여러 가지 이론식 및 모수식들을 살펴보고, 각각의 장단점을 정리하였다. 이 분야에서 발표된 초기 저작들에서는 주로 반복계산을 통해 기포의 형상과 상승속도를 결정하는 기법들이 사용되었으나, 최근에 발표된 논문들에서는 간단한 모수식을 통해 기포의 형상과 상승속도를 반복계산 없이 쉽게 구하는 기법들이 제시되고 있다. 이러한 기법들은 매우 다양한 물리적 특성을 가지는 실험결과들과의 비교에서도 우수성을 보여주고 있어, 관련 분야의 연구에 매우 유용한 도구로 사용할 수 있을 것으로 보인다.

• 한국입자에어로졸학회지
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• 제8권4호
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• pp.173-180
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• 2012

SiC particles, 8.3 ${\mu}m$ in volume average diameter, were chlorinated in an alumina tubular reactor, 2.4 cm in diameter and 32 cm in length, with reactor temperature varied from 100 to $1200^{\circ}C$. The flow rate of the gas admitted to the reactor was held constant at 300 cc/min, the mole fraction of chlorine in the gas at 0.1 and the reaction time at 4 h. The chlorination was negligibly small up to the temperature of $500^{\circ}C$. Thereafter, the degree of chlorination increased remarkably with increasing temperature until $900^{\circ}C$. As the temperature was increased further from 900 to $1200^{\circ}C$, the increments in chlorination degree were rather small. At $1200^{\circ}C$, the chlorination has nearly been completed. The surface area of the residual carbon varied with chlorination temperature in a manner similar to that with the variation of chlorination degree with temperature. The surface area at $1200^{\circ}C$ was 912 $m^{2}/g$. A simple model was developed to predict the conversion of a SiC under various conditions. A Langmuir-Hinshelwood type rate law with two rate constants was employed in the model. Assuming that the two rate constants, $k_{1}$ and $k_{2}$, can be expressed as $A_{1e}^{-E_{1}/RT}$ and $A_{2e}^{-E_{2}/RT}$, the four parameters, $A_{1}$, $E_{1}$, $A_{2}$, and $E_{2}$ were determined to be 32.0 m/min, 103,071 J/mol, 2.24 $m^{3}/mol$ and 39,526 J/mol, respectively, through regression to best fit experimental data.

• 한국대기환경학회지
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• 제18권5호
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• pp.419-426
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• 2002

The concentrations of three different fractions of particulate matters including PM2.5, PM10, and TSP were compared between the Asian Dust (AD) and non-AD (NAD) periods during the spring season of 2001. For the purpose of this comparative analysis, the data sets were obtained from four different observatory sites located within the city boundary of Seoul that concurrently measure those three fractions of PM at hourly intervals. According to our study, several conclusions can be drawn to describe relationships between the AD event and PM distribution characteristics. First of all, it is apparent that the concentrations of PM are distinctively distinguished between AD and NAD. If the extent of contribution to the AD events are assessed on the quantitative basis, it appears that their magnitude increases on the order of PM2.5, PM10, and TSP. As a result, the increase of PM observed during AD event is dominated by the coarse rather than fine fraction of PM. Moreover, when their relationships were assessed in terms of fractional ratios, it was found that TSP/PM10 ratios were almost constant, regardless of the occurrences of AD. On the other hand, the coarse/fine or TSP/PM2.5 ratios changed dramatically between AD and NAD periods. The results of our analysis cleary distinguishes quantitative role of each PM fraction between AD and NAD period, while suggesting indirectly the possible control of source processes on such relationships.

• 한국입자에어로졸학회지
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• 제10권3호
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• pp.119-130
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• 2014

Home is a major living environment of children. In urban area, indoor air at home could be severely influenced by combustion sources such as vehicle exhaust and cooking. In this work, the air quality of a high-rise apartment was investigated by monitoring combustion-related air pollutants at both indoor and outdoor in winter of 2014. From 48-h continuous monitoring data, large amount of $NO_x$ was observed at the balcony of the high-rise apartment during the morning traffic hours. It deteriorated indoor air quality of the apartment. During the cooking activity, high peak episodes of ultrafine particles were seen. It was concluded that effects of vehicle exhaust and cooking activity on the indoor air of the high-rise apartment could be easily checked by $NO_x$ and ultrafine particle indicators, respectively.

• 한국환경과학회지
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• 제12권2호
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• pp.217-225
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• 2003

Samples of size-fractionated PM10 (airborne particulate matter with aerodynamic diameter less than $10\mu\textrm{m}$) were collected at an urban site in Jeju city from May to September 2002. The mass concentration and chemical composition of the samples were measured. The data sets were then applied to the CMB receptor model to estimate the source contribution of PM10 in Jeju area. The average PM10 mass concentration was 28.80$\mu\textrm{g}/m^3$ ($24.6~33.49\mu\textrm{g}/m^3$), and the FP (fine particle with aerodynamic diameter less than $2.l\mu\textrm{m}$ fraction in PM10 was approximately 8% higher than the CP (coarse particle with aerodynamic diameter greater than $2.l\mu\textrm{m}$ and less than $10\mu\textrm{m}$ fraction in PM10. The CP composition was obviously different from the FP composition, that is, the most abundant water soluble species was nitrate ion in the FP, but sulfate ion in the CP. Also sulfur was the most dominant element in the FP, however, sodium was that in the CP. From CMB receptor model results, it was found that road dust was the largest contributor to the CP mass concentration (45% of the CP) and ammonium nitrate, domestic boiler, and marine aerosol were major sources to the CP mass. However, the secondary aerosol was the most significant contributor to the FP mass concentration (45% of the FP). In this study, it was suggested that the contributions of soil dust and gasoline vehicle became very low due to collinearity with road dust and diesel vehicle, respectively.

• 한국대기환경학회지
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• 제21권3호
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• pp.329-341
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• 2005

The purpose of this study is to study the $PM_{2.5}$ source characteristics affecting the Seoul area using a chemical mass balance (CMB) receptor model. This study was also to evaluate the $PM_{2.5}$ source profiles, which were directly measured and developed. Asian Dust Storm usually occurred in the spring, and very high $PM_{2.5}$ concentrations were observed in the fall among the sampling periods. So the ambient data collected in the spring and fall were evaluated. The CMB model results as well as the $PM_{2.5}$ source profiles were validated using the diagnostic categories, such as: source contribution estimate, t-statistic, R-square, Chi-square, and percent of total mass explained. In the spring months, the magnitude of $PM_{2.5}$ mass contributors was in the following order: Chinese aerosol $(31.7\%)>$ secondary aerosols ($22.3\%$: ammonium sulfate $13.4\%$ and ammonium nitrate $8.9\%)>$ vehicles ($16.1\%$: gasoline vehicle $1.4\%$ and diesel vehicles $14.7\%)>$biomass burning $(15.5\%)>$ geological material $(10.5\%)$. In the fall months, the general trend of the $PM_{2.5}$ mass contributors was the following: biomass burning $(31.1\%)>$ vehicles ($26.9\%$: gasoline vehicle $5.1\%$ and diesel vehicles $21.8\%)>$ secondary aerosols ($23.0\%$: ammonium sulfate $9.1\%$ and ammonium nitrate $13.9\%)>$ Chinese aerosol $(10.7\%)$. The results show that the $PM_{2.5}$ mass in the Seoul area was mainly affected by the Chinese area.

• Asian Journal of Atmospheric Environment
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• 제7권1호
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• pp.8-16
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• 2013

The fog water chemistry and deposition in northern Japan were investigated by fog water and throughfall measurements in 2010. Fog water was sampled weekly by an active-string fog sampler at Lake Mashu from May to November. Throughfall measurements were conducted using rain gauges under three deciduous trees along the somma of the lake from August to October. The mean fog deposition rate (flux) was calculated using throughfall data to estimate the total fog water deposition amount for the entire sampling period. $NH_4{^+}$ and $SO{_4}^{2-}$ were the most abundant cation and anion, respectively, in the fog water samples. A mean pH of 5.08 in the fog water, which is higher than those in rural areas in Japan, was observed. The [$NH_4{^+}$]/[$SO{_4}^{2-}$] equivalent ratio in fog water was larger than 1.0 throughout the study period, indicating that $NH_3$ gas was the primary neutralizing agent for fog water acidity. The mean rate and total amount of fog water deposition were estimated as 0.15 mm $h^{-1}$ and 164 mm, respectively. The amounts of nitrogen and sulfate deposition via fog water deposition were corresponded to those reported values of the annual deposition amounts via rainfall.

• 한국농림기상학회지
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• 제11권4호
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• pp.185-191
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• 2009

여름을 제외한 다른 계절의 온난화 혹은 일 최저기온에 대한 온실효과와 도시열섬효과에 관한 연구가 활발히 수행되었던 것에 비하면 여름철의 기온상승, 특히 일 최고기온의 상승에 대한 연구는 미흡하다. 최근 25년간 전국 18개 지점에서 관측된 우리나라의 여름철(6-8월) 일 최고기온 변화를 조사하고 그 변화에 미친 일사량의 영향을 분석한 결과, 평년(1971-2000)에 비해 하루 평균 일사량은 $0.61MJ\;m^{-2}$ 증가하였으며 같은 기간 일 최고기온은 $0.1^{\circ}C$ 상승한 것으로 확인된다. 이 기간 중 일사량의 연차변이는 여름 최고기온 연차변이의 65%를 설명할 수 있었다. 일사량의 증가는 대기투과율의 증가에 기인하며 대기투과율의 증가는 에어로졸 농도 특히 아황산가스 농도 감소 때문인 것으로 판단된다. 1999년부터 2007년까지 여름철 아황산가스 농도가 계속 감소해왔는데 이와 같은 경향이 앞으로도 지속된다면 대기투과율 증가 및 이에 따른 일사량 증가와 증가된 일사량으로 인한 최고기온 상승을 예상할 수 있다.

• 대한원격탐사학회지
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• 제37권6_2호
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• pp.1891-1900
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• 2021

직경 2.5 ㎛ 이하인 초미세먼지는 급격한 도시화와 인구 증가로 인해 대도시에서 많이 발생하며, 유아 및 청소년기는 성인에 비해 초미세먼지에 취약하고 만성 질환으로 이어질 가능성이 높다. 특히 대부분의 청소년들은 학교에서 가장 많은 시간을 보내고 있으며, 다양한 이유에 의해 실외에서 발생한 초미세먼지가 실내로 유입된다. 본 연구는 외부 요인에 의해 발생하는 학교 초미세먼지를 예측하고 학교별 초미세먼지 범주화를 수행하였다. 10-fold cross validation과 grid-search method를 적용한 random forest (RF) 모델에 화학과 기상 인자, 위성 기반의 aerosol optical depth (AOD)를 입력 자료로 하여 학교 초미세먼지를 예측하고 정확도 평가를 위해 4가지 통계 지표를 이용하였다. 학교 미세먼지 범주화를 위해 6가지 유형을 가진 느슨한 기준과 엄격한 기준을 정의하였으며, 범주화 결과 느슨한 기준의 경우 유형 2와 3에, 엄격한 기준의 경우 유형 3과 4에 가장 많은 학교가 포함되었다.

• 한국기후변화학회지
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• 제7권4호
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• pp.433-442
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• 2016

In this study, we examine future changes in surface radiation associated with cloud amount and aerosol emission over East Asia. Data in this study is HadGEM2-CC (Hadley Centre Global Environmental Model version 2, Carbon Cycle) simulations of the Representative Concentration Pathways (RCPs) 2.6/4.5/8.5. Results show that temperature and precipitation increase with rising of the atmosphere $CO_2$. At the end of $21^{st}$ century (2070~2099) relative to the end of $20^{st}$ century (1981~2005), changes in temperature and precipitation rate are expected to increase by $+1.85^{\circ}C/+6.6%$ for RCP2.6, $+3.09^{\circ}C/+8.5%$ for RCP4.5, $+5.49^{\circ}C/10%$ for RCP8.5. The warming results from increasing Net Down Surface Long Wave Radiation Flux (LW) and Net Down Surface Short Wave Radiation Flux (SW) as well. SW change increases mainly from reduced total Aerosol Optical Depth (AOD) and low-level cloud amount. LW change is associated with increasing of atmospheric $CO_2$ and total cloud amount, since increasing cloud amounts are related to absorb LW radiation and remit the energy toward the surface. The enhancement of precipitation is attributed by increasing of high-level cloud amount. Such climate conditions are favorable for vegetation growth and extension. Expansion of C3 grass and shrub is distinct over East Asia, inducing large latent heat flux increment.