• Journal of the Korea Concrete Institute
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• v.16 no.6 s.84
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• pp.805-811
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• 2004

In this paper, effects of mixture proportion and material condition on both fundamental properties, drying and autogenous shrinkage of high performance concrete are discussed. According to the results, for the effect of mixture proportion on the fundamental properties, decrease in W/B and unit water content results in reduction of fluidity, while air content has no variation. Compressive strength exhibits an decreasing tendency with an increase in W/B and unit water content do not remarkable affect the compressive strength. For the effect of materials on the fluidity, the fluidity of low heat portland cement(LPC) is smaller than that of ordinary portland cement(OPC). The use of Polycarbonic acid based superplasticizer(PS) has more favorable effect on enhancing fluidity than Naphtalene based superplasticlzer(NS) and Melamine based superplasticizer(MS). Air content of concrete using LPC is larger than that using OPC. The effects of superplasticizer type on the air content is larger in order of MS, PS and NS. The use of LPC exhibited lower strength development at early age than OPC, whereas after 91days, similar level of compressive strength is achieved regardless of cement type. Compressive strength of concrete is not affected by SP type. For the effect of mixture proportion and materials on drying and autogenous shrinkage, an increase in W/B results in reduction of drying shrinkage and an decrease in water content leads to reduce drying shrinkage. Autogenous shrinkage is not observed until 49 days with the concrete mixture with $35\%$ of W/B and $145 kg/m^3$ of water content. This is due to the combination effects of expansion admixture and shrinkage reducing admixture, which causes an offset of autogenous shrinkage. The use of LPC results in a reduction in autogenous shrinkage compared with OPC. SP type has little influence on the autogenous shrinkage. It is found from the results that mixture proportioning of high performance concrete incorporating fly ash, silica fume, expansion admixture and shrinkage reducing admixture is need to focus on the increase in W/B and the reduction in water content and the use of LPC and MS is also required to use to secure the stability against shrinkage properties.

• The korean journal of orthodontics
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• v.29 no.3 s.74
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• pp.383-397
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• 1999

Bone is a dynamic tissue which is constantly remodelled by subsequent cycles of bone resorption and formation. Glucocorticoid and vitamine $D_3$ are known as regulating substances in bone metabolism. In vitro experiments using bone tissue, it was suggested that glucocorticoid inhibits bone resorption, whereas the effect of glucocorticoid on bone formation are complex- increasing or decreasing effect. The active form of vitamin $D_3$, 1,25-dihydroxycholecalciferol[1.25-$(OH)_2D_3$], has been reported to stimulate osteoblastic activities including the production of ALP, type I collagen, and osteoclacin. The purpose of this study was to evaluate the effect of admixture of vitamin $D_3$ and dexamethasone, one of glucocorticoids, on osteoblastic cell line(MC3T3-E1). Alkaline phosphatase(ALP) and MTT assay were conducted in the cultivated cells with 1, 10, 100nM/ml of 1,25-$(OH)_2D_3$ and/or 10nM/ml, 100nM/ml, $1{\mu}M/ml$ of dexamethasone. The observed results were as follows. 1. The activity of osteoblastic cells with $1{\mu}M/ml$ of dexamethasone was significantly increased at 1-day cultivation with comparison to control group, but was decreased afterwards. But the activity of ALP was greatest in $1{\mu}M/ml$ of dexamethasone and increased with time lapsed. 2. The activity of osteoblastic cells with vitamin $D_3$ was significantly increased dose-dependently at 1-day cultivation, but was significantly decreased in l00nM/.ml at 2-day cultivation, and was a little increased again at 3-day cultivation. The activity of ALP was increased in 10nM/ml or 100nM/ml at 2-day or 3-day cultivation, and was greatest in 100nM/ml at 3-day cultivation. 3. In case of admixture of dexamethasone and vitamin $D_3$, the cellular activity was decreased in any concentration of vitamin $D_3$ at 2-day cultivation, but was increased again at 3-day cultivation, which was greater than that in control or dexamethasone only group. The activity of ALP was decreased at 1-day cultivation, but was increased in the admixture of 10nM/ml or 100nM/ml of dexamethasone with 100nM/ml of vitamin $D_3$ at 2-day cultivation, and was again decreased at 3-day cultivation.

• Magazine of the Korean Society of Agricultural Engineers
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• v.14 no.2
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• pp.2622-2633
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• 1972

This study was attempted in order to search for phyosical properties on various mix designs of concrete as ne of studies relating top revention against corrosion by action of sea water in the West Sea. In this study, as concerete mix design, fly ash, pozzolith and vinsolresin were used as admixtures for normal portland cement respectively, and pozzolan cement and normal cement were also used for each plain concrete. Concrete specimens were made and cured in accordance with the Korean Standard Specifications for concrete. In thetest, compressive strengths of the specimens were measured at the following ages; 7-day, 28-days and 3-months. Absorption test was made by immersing the specimens in water kept at boiling temperature for 5 hours. The results obtained from the tests are summarized as follows; 1. The use of fly ash as an admixture in mix design of concrete, has an effect on compressive strength at each age. But it is actually not effective on absorption by concrete, as the result of the fly ash concrete is almost the same at that of ordinary plain concrete. 2. The use of pozzolith as an admixture in mix design of concrete, has an effect on both of compressive strength at each age and absorption rate. The pozzolith is more effective than vinsol resin, relating to improvement for physical proreties of concrete. 3. The use of vinsol resin as an admixture in mix design of concrete, has also an effect on both of compressive strength at each age and absorption rate. As the above fact, effectiveness of the vinsol resin is some what lower than pozzolith, as far as physical properties of the concrete are concerned. 4. Plain concrete used pozzolan cement only is the most effective on both of strength at each age and absorption rate in this study. The pozzolan cement is characteristic of higher strenth as the age is later. 5. Relationship between compreessive strengths and absorption rates of the concrete is shown by a different regression line dependingon ages. The gradient of the regression line is steeper as the age is later. 6. Throught physical test, it may be expected that the use of pozzolith and vinsol resinas asan admixture respectively will be better resistant than fly ash or ordinary plain concrete and that plain pozzolan concrete will also be the best resistant to action of sea water due to improvement of theirphysical properties.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.117-124
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• 2009

The purpose of the study was to improve quality of high volume fly ash concrete. The study evaluated on the possibility of early quality improvement of high volume fly ash concrete with early strength gain admixture ('GA' below) developed by the preceding research. The study regarded applying naphthalene admixture ('NA' below) to mix proportion substituting FA 15 % to be plain. In the event of substituting FA 20, 25 and 30 %, the study compared engineering properties of concrete with plain by applying GA. Because of features of fresh concrete, fluidity falls down when GA is applied. Therefore, its use amount shall be increased. Only, in W/B 60 %, it was beneficial since slump loss was reduced about 35~70 mm than plain. The study could see that AE use should be increased proportionally since air content was reduced by coming from AE absorption operation of unburned coal content included in FA according to an increase in the amount of FA use. Reduction effect of bleeding could be anticipated since the amount of bleeding appeared at least in FA 20 %. Because of hardened concrete, time of setting appeared in the same level as plain when GA was applied. Therefore, it is judged that delay of setting can be reduced. In compressive strength, the study could check the same strength development as plain when GA was applied, having nothing to do with W/B and curing temperature. However, it is thought that we shall pay attention to GA use in the event of FA 30 % substitution. Freezing and melting resistance had less early value than plain. However, it is judged that there will be no problem of frost resistance since there is no a large difference between freezing and melting resistance and plain in overall. In accelerated neutralization, it was analyzed that a problem of weakening in neutralization appointed as a demerit when FA was applied in mass in proportion with GA use could be settled to some extent.

• Korean Journal of Agricultural Science
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• v.12 no.1
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• pp.75-85
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• 1985

This study is intended to find out the influence of Lignosulfonic Acid Type Admixture on compressive, tensile, flexural strength and dispersing action of mortar, and fixation of by-product of pulp industry. 1. The more Pozzolith-84 is added, the larger flow value is. The admixture of lignosulfonic acid type adhere to cement particles and the surface potential of particles is generated. On account of the repulsion among the cement particles, they are dispersed and the mortar get workable, so the production cost of precast product is curtailed and the amount of cement is reduced in a certain workability of mortar. 2. The strength of mortar is greater than plain mortar when P/C added is 0.2 and 0.4%. As time passed the potential energy is reduced and the distance of particles which lignosulfonic acid adhered to get near according as the amount of adhesion is increased. The setting and hardening reaction of morter is occurred in close state, so the strength of mortar is increased a little. The strength of mortar is less than plain mortar when amount P/C added is 0.8%. Pozzolith-84 is mainly composed of lignosulfonic acid and lignin does not influence the hardening of mortar, therefore the remained $SO_3$, $SO_3H$ are the reason of decrease of strength. 3. There is high significance between specific gravity and compressive strength. The larger specific gravity is, the more compressive strength is increased. There is high significance between 7 day's strength and 28 day's strength. The larger compressive strength is, the more tensile and flexural strength are increased. 4. Since Pozzolith-84 is a by-product of pulp industry, by using the Pozzolith-84 admixture the concreate quality is improved. The water pollusion is reduced according to fix by-products in concrete structure.

• The Korean Journal of Ceramics
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• v.6 no.2
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• pp.103-106
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• 2000

The effects of replacement level, curing method and chemical admixtures were investigated in the cement-fly ash paste. The strength of cement-fly ash paste is lower than that of controlled cement paste only and the differences increase with replacement level. However, in steam curing, strength of cement-fly ash pastes is improved, especially, at early ages. In order to improve early strength, the use of $Na_2SO_4$in cement-fly ash paste increases the quality of concrete. In addition, improvement of strength of concrete including 30% of fly ash can be obtained and achieves the highest strength compared to other concrete mixtures.

• Journal of the Korea Institute of Building Construction
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• v.1 no.2
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• pp.179-184
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• 2001

The most recent building trend is going large, high rise, high strength as overlarge project is developing in domestic construction business. Belite cement has properties like low heat, excellent long term strength, and durability without admixture(fly ash, silica fume). so, Beilte cement is suitable for mass structure which is needed high strength, high fluidity and low heat property. This study is to examine the possibility if site adoption microwave-use early strength estimation method. Based on the existed study related the portland cement, the interrelation between Belite cement and microwave-use early strength estimation method is required. In this study, interrelation between mortar and Evaluating strength estimation method is investigated before the concrete experiment.

• Journal of Ocean Engineering and Technology
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• v.12 no.1
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• pp.153-161
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• 1998

This paper is to investigate the Fluidity of Antiwashout Underwater Concrete containing Fly Ash. The results of study are concluded as follows: the increase in Slump Flow value did not happen in the plain concrete which was replaced cement by Fly Ash; however, the maximum value could reach in the replacement of 30% of Fly Ash by weight of cement in the Fly Ash replaced concrete. On the condition of Fly Ash-Antiwashout Underwater Concrete in expecting 50 cm of the Slump Flow, it was necessary that the usage amount of Superplasticizer be around 1% of unit Binder, and 1.5% in 60 cm of the Slump Flow, respoectively.

• Computers and Concrete
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• v.8 no.2
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• pp.229-241
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• 2011

In this work, cement paste samples with 1% (by cement mass) of a conductive carbon fiber admixture have been studied under uniaxial compression. Three different arrangements were used to measure the resistivity of the samples. According to the results obtained, the resistance should be measured using the four wire method in order to obtain good sensitivity and repeatability. The effect of the load value and the load rate on the fractional change of the volume resistivity has been determined. It has been observed that the gage factor (fractional change in resistance respect to strain) increases when the maximum load is increased, and the loading rate does not affect significantly this parameter. The effect of the sample ambient humidity on the material piezoresistivity has also been studied, showing that the response of the composite is highly affected by this parameter.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.431-436
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• 2002

In this paper, to seek a solution of reducing autogenous shrinkage three types of bar restricted concrete specimens which have similar compressive strength were tested. The three type of concrete were plain concrete-P25 type, $10^{\circ}C$ fly-ash replaced concrete-F10 type, and $1^{\circ}C$ expansion admixture replaced concrete-SP1 type, and with the test result an experimental study was conducted to gain the tensile stress of concrete. From the result of P25, SP1, F10 tests, it was found that by the age of 14 the ratios of tensile stress to tensile strength of three specimens are $75^{\circ}C$, $47^{\circ}C$, $52^{\circ}C$ respectively. so we came to a conclusion that the SP1-type concrete has better capacity to reduce autogenous shrinkage than F10-type concrete at similar compressive strength condition.