• Title/Summary/Keyword: Adhesive property

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Preparation of Pressure Sensitive Adhesive Using Reactive Polyurethane Resin and the Effect of Interfacial Crosslinking on the Adhesion Property (반응성 폴리우레탄 레진을 이용한 Pressure Sensitive Adhesive 제조 및 계면 가교 반응이 점착 물성에 미치는 영향)

  • Shin, Jin Sup;Kim, Ji Heon;Cheong, In Woo;Kim, Jung Hyun
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.81-85
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    • 2005
  • Pressure sensitive adhesive (PSA) was prepared by semi-batch emulsion polymerization of acryl monomers in the presence of reactive and non-reactive carboxylated polyurethane resin (PUR). Effects of the PUR type, its content, and crosslinker feeding method on the adhesive properties of the PSA was investigated. In this experiment, the PSA prepared with the reactive PUR showed better adhesive property then the PSA with the non-reactive PUR. Especially, peel strength of the PSA, where acetoacetoxy ethyl methacrylate and 1,6-hexane diamine as crosslinkers were introduced, was dramatically enhanced in severe humidity condition due to the interfacial crosslinking.

A Study on Bonding Process for Improvement of Adhesion Properties Between CFRP-Metal Dual Materials (CFRP/금속간 접합력 강화를 위한 접합공정 연구)

  • Kwon, Dong-Jun;Park, Sung-Min;Park, Joung-Man;Kwon, Il-Jun
    • Composites Research
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    • v.30 no.6
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    • pp.416-421
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    • 2017
  • The structural adhesive have been manufactured for improvement of bonding process between CFRP and metal. The optimal condition for bonding process were investigated by evaluating the lap shear strength with amount of adhesive and curing time and the surface treatment of the CFRP. To confirm proper adhesion conditions, the fracture sections between CFRP and metal was observed using reflection microscope. Not only the improvement of the adhesion condition was important, but surface treatment on CFRP was also important. The optimal curing temperature was at $180^{\circ}C$ for 20 minutes. The improvement for adhesive property was confirmed After surface treatment on CFRP. The optimal amount of structural adhesive for bonding between CFRP and metal was $1.5{\times}10^{-3}g/mm^2$. Through the optimization of bonding process, the improvement of mechanical property over 10% is confirmed in comparison with existing adhesive.

Synthesis and Characterization of Catechol-Containing Biomimetic Mucoadhesive Polymers (카테콜 함유 생체모방 점막접착형 고분자의 합성 및 특성 연구)

  • Park, Dong Jin;Lee, Sang Jin;Lee, Sang Cheon
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.625-631
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    • 2013
  • Mucoadhesive property is the major function as an adhesive for medical devices, and therefore, these days many researches have conducted to develop polymers having this property. Recently, biomimetic technology has been used for developing mucoadhesive polymers. Among many technologies, mussel-inspired approaches have received noticeable attention because of its thread's strong adhesive characteristics. In this study, we synthesized mucoadhesive biomimetic polymers employing catechol structures which are abundant in mussel adhesive proteins, and their structures and molecular weights were characterized by using nuclear magnetic resonance spectroscopy and gel permeation chromatography. To evaluate in vitro mucoadhesive strength, the sheet type of the small intestinal porcine submucosa was prepared. Compared to commercial fibrin glue adhesives, catechol-containing mucoadhesive polymers showed enhanced adhesive strength. The study of adhesive strength with considering diverse factors, such as temperature, pressure, and oxidant amount indicated that mussel-inspired mucoadhesive polymer could be a promising candidate for an adhesive in various biomedical applications.

Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin - (III) The Effect of Wax and Filler - (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 - (III) 왁스와 충전제의 영향 -)

  • Chung, Kyung-Ho;Han, Kyung-A;Cho, Wook-Sang
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.827-833
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    • 2005
  • This study focused on the establishment of optimum formulation of polyamide based hot melt adhesive through adhesive synthesis, study of physical property, and adhesion study. In the previous study, the optimum formulation of base resins (CM831, 843P) and tackifying resin (terpene resin) was determined. The weight ratio of CM831, 843P, and terpene resin was 75, 25, and 10, respectively. Based on the optimum formulation, the effect of wax and filler addition was examined in this study. According to the results, the maximum adhesion strength with the steel could be obtained by the addition of 5 wt% of polyethylene wax although the melt viscosity of adhesive decreased continuously with the addition of wax. In the case of filler, the optimum adhesion property could be achieved by the addition of 10 wt% of talc. However, the addition of filler caused little increase of melt viscosity of adhesive.

A Study on Fabric Adhesive Interlining(3) (직물접착심지에 관한 연구(3))

  • Cho, Cha
    • Journal of the Korean Home Economics Association
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    • v.35 no.1
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    • pp.257-262
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    • 1997
  • In this thesis considering the problems shown in the usage of interlining of clothes and in the process of sewing the breaking away strength which is meant by adhesion is analysed by experimennt in which Polyamide content is dealed with at the 5 level to raise the adhesive strength by using the one-sided non woven adhesive interlining made in this country as the samples. After examing the optimum in the process of Cotton and polyester fabrics and adhered fabrics practical for blouse and jacket and analysing the breaking away strength the wanted property of matter and the change with the repeated laundry We reach at the following results. 1. The adhesive strength of the two adhered fabrics were strongly appeared in order of cotton>polyester. 2. The order of the breaking away strength by the interlinings of adhesive fabrics was A5> A4> A3> A2> A1. 3. The breaking away strength of the two adhered fabrics was weakened by the repeated laundry and the breaking away phenomena were fewer under the most suitable conditions than the various conditions.

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Adhesive Membrane of Oocyte in Korean Cobitid Species (Pisces, Cobitidae) (한국산 기름종개속 어류의 난모세포의 부착막)

  • 김익수;박종영
    • The Korean Journal of Zoology
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    • v.38 no.2
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    • pp.212-219
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    • 1995
  • Through the histolosical observation of ovary in the nine species of the genus Cobitis, we found that specific adhesive membranes were attached to the outer zone radials during the vitellosenesis. These adhesive membranes could be classified into four forms as follows: 1) granular form of Colitis lutheri, C. striate, and C. sinensis, 2) villous form of C. longicorpus, C. konensis koreensis, C. k. pumilus, and C. granoei, 3) saw-like form of C. rotundicaudata, and 4) filamentous form of C. chou. The various forms of adhesive membrane of egg in the cobitid fishes are showed a species specificitv with reference to their habitats and spawning property.

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Treatment and Characterization of Polyethylene Terephthalate Fibers with Silicone Rubber Adhesive for Heat-Resistant Adhesion (실리콘 고무와 내열접착 향상을 위한 Polyethylene Terephthalate 섬유 접착층의 제조 및 특성)

  • Kim, Jihyo;Lee, Sangoh;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.31 no.2
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    • pp.107-117
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    • 2019
  • In case of pure rubber materials, the initial quality of the rubber materials would be excellent, however, the durability against external impact might be poor. In order to overcome the relatively low durability, textile cord could be employed with silicone rubber. We have studied the improvement of heat-resistant adhesion properties of silicone adhesives between silicone rubber and PET fibers by applying various conditions including dip solution recipe. The silicone rubber used was a platinum catalyst curing type and platinum catalyst type silicone adhesive was used as an adhesive to obtain an optimum adhesive force. Furthermore, the bonding mechanism between silicone and PET fiber was established.

Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin - (II) The Effects of Terpene Resin - (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능향상 - (II) 테르펜수지의 영향 -)

  • Chung, Kyung-Ho;Hong, Young-Keun;Chun, Young-Sik
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.226-231
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    • 1998
  • Hot melt adhesive which is solventless type has been widely used due to the possibility of automated adhesion process. The main purpose of this study is the development of polyamide based hot melt adhesive to improve the property of conventional ethylene-vinyl acetate hot melt adhesive, which has an inherent problem against heat resistance. In this study, it was found that the terpolymers of nylon 6, nylon 66, and nylon 12(CM831, 843P types) instead of nylon homopolymer were suitable base resins for hot melt adhesive, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. According to the results, the optimum adhesion property could be obtained by the using 75/25~50/50 weight radio of CM831/843P resin as a base resin. Terpene resin was used as tackifier to improve adhesion and wetting properties. The best result can be obtained with the 10 wt.% addition of terpene resin. The terpene resin acted as proper tackifier in this system which decreased the melt temperature and viscosity, but increased the mechanical strength of adhesive itself. Also, the rheological property of the adhesive changed from typical non-Newtonian behavior to Newtonian behavior as terpene resin was added.

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Property and Polymerization of Hi-solid PSA's using Seeded Polymerization (Seed 중합을 이용한 고고형분 수용성 점착제의 합성과 물성)

  • Jung, Young Sik;Min, Seong-Kee;Seul, Soo Duk
    • Journal of Adhesion and Interface
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    • v.10 no.4
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    • pp.174-181
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    • 2009
  • The viscosity for hi-solid pressure sensitive adhesive to improve water soluble low viscosity pressure sensitive adhesive polymerized using seeded polymerization. While seed binder polymerizing it produces an optimum polymerization condition, and acrylic acid and seed binder concentration changed were measurement of viscosity variation and adhesive power at the substrate (SUS420J) as flowing results. In adhesive polymerization, seed binder concentration 7 wt%/monomer was recovered 60% of solid content, 2,100 cps of low viscosity and clear adhesive film. When acrylic acid content was 4 wt%/monomer, it was turned excellent adhesive power and holding power.

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Adhesive and Removable Characteristics of UV Curable Adhesive (자외선 경화형 점착제의 접착 및 재박리 특성)

  • Kim, In Beom;Lee, Myung Cheon
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.76-81
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    • 2008
  • UV curable pressure sensitive adhesive (PSA) was made by blending the di-functional or hexa-functional urethane-acrylate oligomer with synthesized acrylic PSA. The change of adhesive property and removability were investigated at various oligomer contents under each oligomer. As the content of oligomer increased, the peel strength was increased before UV irradiation, but it was decreased after UV irradiation. Also, it was observed that the peel strength increased with decrease of storage modulus (G'), and that loss factor (tan ${\delta}$) of the adhesive material affected the adhesive properties and removability.